Anilines, incompatibilities with

The reduction of these compounds would give mole of labelled aniline, H moles of ordinary aniline, i mole of labelled ammonia and mole of ordinary ammonia, which is incompatible with the experimental results actually obtained. 

Note Copper columns often cause adsorption problems incompatible with amines, anilines, acetylenes, terpenes, steroids, and strong bases. 

SAFETY PROFILE A poison by inhalation. A corrosive and severe irritant to skin, eyes, and mucous membranes. Reacts with water or steam to produce heat, toxic and corrosive fumes. Violent reaction with aniline or phosphine. Incompatible with hexafluorisopropylidene amino lithium, NO2, grease, organic matter, O2. When heated to decomposition it emits toxic fumes of Cl". See also BORON COMPOUNDS and HYDROCHLORIC ACID. 

Of the highly functionalized 5,10,15,20-tetraphenylporphins, there is 5,10,15,20-tetrakis (o-aminophenyl)porphin. Summing the enthalpy of formation of the solid of 474 17 kJ mol-1 with the enthalpy of sublimation of 332 kJmol 1 from Reference 71 results in a gas phase enthalpy of formation of this species of 806 kJmol-1. Should we assume the applicability of equation 2 as for simpler, lower molecular weight, less hindered anilines, these enthalpy values are incompatible with the values, likewise obtained from Reference 71, of 621.3 6.3 and 865 kJmol-1 for the enthalpies of formation of solid and gaseous 5,10,15,20-tetraphenylporphin. The enthalpy of formation of solid 5,10,15,20-tetrakis(p-(A,A-dimethylamino)phenyl)porphin72 of —434.8 kJmol-1 is also incompatible with those of both porphyrins cited above. 

ANILINE, 2,6-DIETHYL (579-66-8) C10H15N Combustible liquid (flash point 254°F/123°C cc Fire Rating 1). Vigorous reaction with strong oxidizers. A weak base incompatible with strong acids, mineral acids, organic anhydrides, isocyanates, aldehydes. On small fires, use dry chemical powder (such as Purple-K-Powder), alcohol-resistant foam, or CO2 extinguishers. ANILINE HYDROCHLORIDE (142-04-... 

CHLOROMETHYL OXIRANE (106-89-8) C3H5CIO Highly flammable, polymerizable liquid. Forms explosive mixture with air [explosion limits in air (vol %) 3.8 to 21.0 flash point 69°F/21°C 88°F/31 °C autoignition temp 772 F/411 °C Fire Rating 3]. Reacts violently with water. Contact with elevated temperatures, contamination, strong acids, strong bases, metallic halides, aluminum, aluminum chloride iron(III) chloride and other chlorides of iron or zinc can cause explosive polymerization. Violent reaction with aniline, hypochlorite, isopropylamine, potassium ieri-butoxide (ignition), sulfuric acid. Mixtures with trichloroethylene forms explosive dichloroacetylene. Incompatible with aliphatic amines, alkaline earths, alkali... 

---