Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Dimensional analysis general

Dimensional Analysis. Dimensional analysis can be helpful in analyzing reactor performance and developing scale-up criteria. Seven dimensionless groups used in generalized rate equations for continuous flow reaction systems are Hsted in Table 4. Other dimensionless groups apply in specific situations (58—61). Compromising assumptions are often necessary, and their vaHdation must be estabHshed experimentally or by analogy to previously studied systems. [Pg.517]

It should be emphasized that the specific relationship between the variables or groups that is implied in the foregoing discussion is not determined by dimensional analysis. It must be determined from theoretical or experimental analysis. Dimensional analysis gives only an appropriate set of dimensionless groups that can be used as generalized variables in these relationships. However, because of the universal generality of the dimensionless groups, any functional relationship between them that is valid in any system must also be valid in any other similar system. [Pg.29]

An approximate yet accurate analysis of general multi-dimensional overlap integrals is undoubtedly very complicated. A purely classical approach as outlined in Chapter 5 becomes rather uncertain because the... [Pg.318]

The three-dimensional linear-elastic finite-element formulation permits the analysis of general three-dimensional structures of arbitrary geometry. [Pg.163]

Even if the polymer melt is assumed to be purely viscous, the analysis will generally be quite complicated because many dies have flow channels of complex shape. As a result, accurate analysis of flow In extrusion dies generally requires three-dimensional flow analysis. This presents quite a challenge for simple Newtonian fluids. Three-dimensional flow analysis of viscoelastic non-Newtonian fluids is beyond the capabilities of most (if not all) die designers. Not surprisingly, die designers often take an empirical approach to die design. [Pg.419]

The answer to this question is the subject oiscaling and dimensional analysis. In general, scaling involves the nondimensionalization of the conservation equations where the characteristic variables used for nondimensionalization are selected as their maximum values, e.g., the maximum values of velocity, temperature, length, and the like, in a particular problem. Let s see specifically how this method works and why it can often lead to a simplification of partial differential equations. [Pg.144]

A multi-dimensional generalization of the Stefan problem which includes surface tension is studied as a mathematical model for growth in a metastable medium. Planar solutions are shown to exist for all time only if the data is sufficiently small, otherwise the velocity of the front becomes infinite in finite time. Planar fronts which exist for all time are shown to be morphologically unstable without surface tension and to be stable with respect to perturbations of short wavelength when surface tension is included. Above a critical value of the surface tension, planar fronts are completely stable. The mathematical techniques used are a combination of soft analysis based on the maximum principle and functional analytic/integral equation type hard estimates. [Pg.247]

One-dimensional nonlinear total-stress site response analysis is generally cmiducted using... [Pg.3288]

For one-dimensional analysis, the general Reynolds equation for rough svirfaces is... [Pg.762]

Segmentation method based on the analysis by Co-Occurrence Matrix is developed. We try to increase the quality of the obtained results by means of the application of two dimensional (2D) processing. We use Co-Occurrence Matrix for ultrasonic image segmentation. This tool, introduced by Haralick (1), was selected for the present study as several general considerations were favourable ... [Pg.231]

Dimensional analysis (qv) shows that is generally a function of the particle Reynolds number ... [Pg.316]

Scale- Up of Electrochemical Reactors. The intermediate scale of the pilot plant is frequendy used in the scale-up of an electrochemical reactor or process to full scale. Dimensional analysis (qv) has been used in chemical engineering scale-up to simplify and generalize a multivariant system, and may be appHed to electrochemical systems, but has shown limitations. It is best used in conjunction with mathematical models. Scale-up often involves seeking a few critical parameters. Eor electrochemical cells, these parameters are generally current distribution and cell resistance. The characteristics of electrolytic process scale-up have been described (63—65). [Pg.90]

In general, two related techniques may be used principal component analysis (PCA) and principal coordinate analysis (PCoorA). Both methods start from the n X m data matrix M, which holds the m coordinates defining n conformations in an m-dimensional space. That is, each matrix element Mg is equal to q, the jth coordinate of the /th conformation. From this starting point PCA and PCoorA follow different routes. [Pg.87]

Damkdhler (1936) studied the above subjects with the help of dimensional analysis. He concluded from the differential equations, describing chemical reactions in a flow system, that four dimensionless numbers can be derived as criteria for similarity. These four and the Reynolds number are needed to characterize reacting flow systems. He realized that scale-up on this basis can only be achieved by giving up complete similarity. The recognition that these basic dimensionless numbers have general and wider applicability came only in the 1960s. The Damkdhler numbers will be used for the basis of discussion of the subject presented here as follows ... [Pg.278]

A general theory of dimensional change in graphite due to Simmons [62] has been extended by Brocklehurst and Kelly [17]. A detailed account of the treatment of dimensional changes in graphite can be found in Kelly and Burchell s analysis of H-451 graphite irradiation behavior [63]. [Pg.462]

The modeling of a groundwater chemical pollution problem may be one-, two-, or tlu-cc-dimcnsional. The proper approach is dependent on the problem context. For c.xamplc, tlie vertical migration of a chemical from a surface source to the water table is generally treated as a one-dimensional problem. Within an aquifer, this type of analysis may be valid if the chemical nipidly penetrates the aquifer so that concentrations are uniform vertically and laterally. This is likely to be the case when the vertical and latcrtil dimensions of the aquifer arc small relative to the longitudinal scale of the problem or when the source fully penetrates the aquifer and forms a strip source. [Pg.363]


See other pages where Dimensional analysis general is mentioned: [Pg.66]    [Pg.363]    [Pg.230]    [Pg.1569]    [Pg.150]    [Pg.714]    [Pg.273]    [Pg.123]    [Pg.140]    [Pg.259]    [Pg.113]    [Pg.371]    [Pg.598]    [Pg.59]    [Pg.1733]    [Pg.528]    [Pg.17]    [Pg.54]    [Pg.87]    [Pg.102]    [Pg.106]    [Pg.548]    [Pg.333]    [Pg.418]    [Pg.103]    [Pg.103]    [Pg.1388]    [Pg.1905]    [Pg.436]    [Pg.290]    [Pg.566]    [Pg.11]    [Pg.58]    [Pg.68]   
See also in sourсe #XX -- [ Pg.298 , Pg.299 ]




SEARCH



Dimensional analysis

© 2024 chempedia.info