Ammonia KRES process

KAAP [Kellogg advanced ammonia process] The first high-pressure process developed for synthesizing ammonia from its elements which does not use an iron-containing catalyst. The reformer gas for this process is provided by the KRES process. The catalyst was developed by BP it contains ruthenium supported on carbon. Developed by MW Kellogg Company in 1990 and first installed by the Ocelot Ammonia Company (now Pacific Ammonia) at Kitimat, British Columbia, from 1991 to 1992. Another plant was installed at Ampro Fertilizers in Donaldsonville, LA, in 1996. 

Breakthroughs in small-scale capacity processes are the Kellogg (KRES system) and ICI Leading Concept-Ammonia (LCA) process. The capacity of the referenced installation is 457 tpd, and the total energy consumption is estimated at 7.22 Gcal/tonne of ammonia, h-stallation also produces carbon dioxide that has more than 99% purity. The processes are described in Chapter 6. 

Description The key steps in the KAAP plus process are reforming using the KBR reforming exchanger system (KRES), cryogenic purification of the synthesis gas and low-pressure ammonia synthesis using KAAP catalyst. 

Kellogg Brown Root Ammonia, advanced Hydrocarbons/natural gas naphtha Catalytic-steam reforming process uses pressure-based Kellogg Reforming Exchange System (KRES) NA NA... 

Desulfurized feed is reacted with steam in the primary reformer (1) with an exit temperature of about 700°C. Primary reformer effluent is reacted with excess air in the secondary reformer (2) with an exit temperature of about 900°C. The air compressor is normally a gas-driven turbine (3). Turbine exhaust is fed to the primary reformer and used as preheated combustion air. An alternative to the above described conventional reforming is to use KBR s reforming exchanger system (KRES), as described in KBR s Purifierp/us ammonia process. 

Another key feature of this new process is the patented KBR Reforming Exchanger System (KRES), which eliminates the need for the directly fired primary reformer furnace (fig. 6.11). This reduces capital costs by 5-8%, and emissions of NO and CO2 by 70-75%. The first KAAP process was installed for the Ocelot Ammonia Company s (now Pacific Ammonia Inc.) retrofit of its plant in Kitimat, British Columbia, in 1992 and when the first two new KAAP plants (for Farmland Misschem and PCS Nitrogen) were completed at Point Lisas, Trinidad, in July 1998, they became the world s largest ammonia facilities (each at 1,850 t/day) to date. ... 

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