Alkyl nitrite peroxide

In addition to CuCfi, some other compounds such as Cu(OAc)2, Cu(N03)2-FeCl.i, dichromate, HNO3, potassium peroxodisulfate, and Mn02 are used as oxidants of Pd(0). Also heteropoly acid salts comtaining P, Mo, V, Si, and Ge are used with PdS04 as the redox system[2]. Organic oxidants such as benzo-quinone (BQ), hydrogen peroxide and some organic peroxides are used for oxidation. Alkyl nitrites are unique oxidants which are used in some industrial... 

Thermal or photo-induced decompositions of dialkyl peroxides in the presence of suitable substrates yield various products. For example, with nitric oxides, alkyl nitrites or nitrates are formed and, with carbon monoxide, Z fZ-alkyl esters are obtained (44) ... 

The thiazolyl radicals are, in comparison to the phenyl radical, electrophilic as shown by isomer ratios obtained in reaction with different aromatic and heteroaromatic compounds. Sources of thiazolyl radicals are few the corresponding peroxide and 2-thiazolylhydrazine (202, 209, 210) (see Table III-34) are convenient reagents, and it is the reaction of an alkyl nitrite (isoamyl) on the corresponding (2-, 4-, or 5-) amine that is most commonly used to produce thiazolyl radicals (203-206). The yields of substituted thiazole are around 40%. These results are summarized in Tables III-35 and ni-36. 

Herm and Herschbach [104] and Wilson [142] have studied the reactions of alkali metals with NO2, N2O, CH3NO2, several alkyl nitrites, nitrates and nitro compounds and dialkyl peroxides. Differential surface ionization could not be used as the Pt—8% W filament was in the... 

The photodecomposition of the various oxidation products of the alkanes, alkenes, and the aromatic hydrocarbons play important roles in the chemistry of the urban, mral, and remote atmospheres. These processes provide radical and other reachve products that help drive the chemistry that leads to ozone generation and other important chemistty in the troposphere. In this chapter, we have reviewed the evidence for the nature of the primary processes that occur in the aldehydes, ketones, alkyl nitrites, nittoalkanes, alkyl nitrates, peroxyacyl nitrates, alkyl peroxides, and some representative, ttopospheric, sunlight-absorbing aromatic compounds. Where sufficient data exist, estimates have been made of the rate of the photolytic processes that occur in these molecules by calculation of the photolysis frequencies ory-values. These rate coefficients allow estimation of the photochemical lifetimes of the various compounds in the atmosphere as well as the rates at which various reactive products are formed through photolysis. 

The hydroxyl groups on glycols undergo the usual alcohol chemistry giving a wide variety of possible derivatives. Hydroxyls can be converted to aldehydes, alkyl hahdes, amides, amines, a2ides, carboxyUc acids, ethers, mercaptans, nitrate esters, nitriles, nitrite esters, organic esters, peroxides, phosphate esters, and sulfate esters (6,7). 

Acetylenedimagnesium bromide, 66, 84, 137 Acyl-alkyl diradical disproportionations, 299 Acyl-alkyl diradical recombination, 296 Alkaline hydrogen peroxide, 10, 12, 20 Alkylation of formyl ketones, 93 Alkylation via enolate anions, 86 17a-Alkynyl steroids from 17-ketones, 67 2 -Allyl-17jS-hydroxy-5a-androstan-3 -one, 9 5 Allylic acetoxylation, 242 Allylmagnesium bromide, 64 17 /3-Ami noandrost-5-en-3/3-ol, 145 17 a- Aminomethy 1-5 a-androstane-3 /3,17/3-diol, 387 Amyl nitrite, 154... 

Many compounds have been tested as ignition quality improvers—additives which shorten the ignition delay to a desirable duration. An extensive review in 1944 (6, 43) listed 303 references, 92 dealing with alkyl nitrates and nitrites 61 with aldehydes, ketones, esters, and ethers 49 with peroxides 42 with aromatic nitro compounds 29, with metal derivatives 28 with oxidation and oxidation products 22 with polysulfides 16 with aromatic hydrocarbons nine with nitration and four with oximes and nitroso compounds. In 1950, tests at the U. S. Naval Engineering Experiment Station (48) showed that a concentration of 1.5% of certain peroxides, alkyl nitrates, nitroaikanes, and nitrocarbamates increased cetane number 20 or more units. 

In summary, the main products derived from these photochemical reactions are O3, peroxides (e.g., PAN, PBN, and H202), hydroperoxides, aldehydes, ketones, alcohols, nitro compounds (alkyl and benzyl nitrates and nitrites), and acids such as sulfuric, nitric, and nitrous acid. 

The 2-amino group of 4-oxo-4//-pyrido[l,2-(/]pyrimidines can be transformed to a hydroxy group by sodium nitrite in concentrated sulfuric acid at 0 The 2-hydroxy group can be formed from the 2-mercapto group by treatment with 3" hydrogen peroxide in I N potassium hydroxide. The hydrazino group of 2-hydrazino-4-oxo-4H-pyrido[l,2-a]pyrimidine was alkylated at N-2 with 6-chloronebularine, formylated at N-2 by heating in formic acid, and transformed to a Schiff s base by reaction with benzaldehyde. " ... 

Naked cyanide has been demonstrated to be a synthetically useful reagent in a wide variety of substitution, elimination and addition processes [119]. The reaction of naked nitrite with primary alkyl halides yields nitro compounds as major products, with nitrite esters as the principal byproducts [140]. The use of crown ethers also permits the transformation of organic alkyl halides into the corresponding dialkyl peroxides [141] through the generation of naked peroxide from KO2 or Na02. 

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