Chemistry alcohols

The hydroxyl groups on glycols undergo the usual alcohol chemistry giving a wide variety of possible derivatives. Hydroxyls can be converted to aldehydes, alkyl hahdes, amides, amines, a2ides, carboxyUc acids, ethers, mercaptans, nitrate esters, nitriles, nitrite esters, organic esters, peroxides, phosphate esters, and sulfate esters (6,7). 

Chemical properties of isopropyl alcohol are determined by its functional hydroxyl group in the secondary position. Except for the production of acetone, most isopropyl alcohol chemistry involves the introduction of the isopropyl or isopropoxy group into other organic molecules by the breaking of the C—OH or the O—H bond in the isopropyl alcohol molecule. 

Chen DA, Friend CM (1996) Alcohol chemistry as a probe of mixed-metal phases reactions of 2-propanol on cobalt-covered Mo(110). J Phys Chem 100 17640-17647... 

Klomp, D., Maschmeyer, T., Hanefeld, U., Peters Jeep, A. Mechanism of homogeneously and heterogeneously catalysed meerwein-ponndorf-verley-oppenauer reactions for the racemisation of secondary alcohols. Chemistry (Weinheim an der Bergstrasse, Germany)... 

This section concludes the coverage of alcohol chemistry for now. A summary chart concerning the various conditions for substitution and elimination reactions follows. 

Indeed, any of five bonds may be involved in alcohol chemistry, and if we treat substitution and elimination separately, a total of four types of reactions are possible, as shown. A related class of compounds—ethers—is also presented. Bccau.se the.se lack an oxygen-hydrogen bonu, the two reactions of alconols that involve the 0-H bond are not available to ethers. In fact, only substitution reactions turn out to be important in the chemistry of ethers, and those occur only under certain. sets of conditions, depending on the nature of the ether. By and large, ethers, in contrast with alcohols, have been found to be very unreactive molecules, a property that results in their usefulness as solvents for a wide variety of reactions in organic chemistry. 

Table 12. Trends Within Phthalate Ester Plasticizers as a Function of Alcohol Chemistry ...

Based on the concept of simplification and alcohol chemistry, disconnections C, D, and E are reasonable. Interestingly, disconnections A and B are quite reasonable if the tertiary alcohol is further disconnected to give a secondary alcohol and an ethyl fragment. The purpose of this section is not to analyze 71 in depth, but rather to point out that understanding the various reactions of the functional groups is essential to planning a disconnection. 

Matsumoto, T., Ueno, M., Wang, N., et al. (2008). Recent Advances in Immobilized Metal Catalysts for Environmentally Benign Oxidation of Alcohols, Chemistry-An Asian Journal, 3, pp. 196-214. 

Boggan, W. (2005). Alcohol, Chemistry, and You. Chemcases.com. Kennesaw State... 

The goal is the selection of catalysts for reactions involving the formation of higher alcohols, following the alcohol chemistry route. This study aims to apply the theory and thus provide the selection of catalysts for the process. 

The work reported here stems from a program to develop a non-ionic superabsorbent polymer based on poly(vinyl alcohol) chemistry. The products were compared to conventional (ionic) acrylate super absorbents in baby diapers. 

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