Benzyl nitrate

Isoquinoline, 3 -benzoyltetrahydro-synthesis, 2, 413 Isoquinoline, 1-benzyl-nitration, 2, 335 Isoquinoline, 4-benzyl-nitration, 2, 335 synthesis... [Pg.679]

Schneider M, O Luxenhofer, A Deissler, K Ballschmiter (1998) Cj-C, alkyl nitrates, benzyl nitrate and bifunctional nitrates measurements in California and South Atlantic air and global comparsion using C2Cj4 and CHBrj as marker molecules. Environ Sci Technol 32 3055-3062. [Pg.46]

Chemical/Physical. Products identified from the reaction of toluene with nitric oxide and OH radicals include benzaldehyde, benzyl alcohol, 3-nitrotoluene, p-methylbenzoquinone, and o, m, and p-cresol (Kenley et ah, 1978). Gaseous toluene reacted with nitrate radicals in purified air forming the following products benzaldehyde, benzyl alcohol, benzyl nitrate, and 2-, 3-, and 4-nitro-toluene (Chiodini et al., 1993). Under atmospheric conditions, the gas-phase reaction with OH radicals and nitrogen oxides resulted in the formation of benzaldehyde, benzyl nitrate, 3-nitrotoluene, and o-, m-, and p-cresol (Finlayson-Pitts and Pitts, 1986 Atkinson, 1990). [Pg.1059]

Benzol hjthiophene, see Naphthalene 1,2,3-Benzotriazin-4 (3/J -one, see Azinnhos-methyl Benzotriazole, see Tetrachloroethylene Benzyl alcohol, see Benzo[a]anthracene, Benzyl butyl phthalate. Benzyl chloride, Permethrin. o-Xylene, m-Xylene, p-Xylene. Toluene 0-Benzyl alcohol, see o-Xylene m-Benzyl alcohol, see m-Xylene p-Benzyl alcohol, see p-Xylene 10-Benzyl-10-hydroanthracen-9-one, see Benzo [ a] anthracene Benzyl hydroperoxide, see Toluene Benzyl nitrate, see Toluene Benzylsuccinic acid, see Toluene... [Pg.1519]

The decomposition rates of several glycol nitrates and glyceryl trinitrate are greatly enhanced by the presence of transition metal oxides or chelates. 2-tranv-l-Azido-l,2-dihydroacenaphthyl nitrate, 3466 Benzyl nitrate, 2765... [Pg.26]

FIGURE 6.12 Mechanism of formation of benzyl nitrate and benzaldehyde from reaction from the methyl side group of toluene. [Pg.208]

Schneider, M., O. Luxenhofer, A. Deissler, and K. Ballschmiter, C,-C 5 Alkyl Nitrates, Benzyl Nitrate, and Bifunctional Nitrates Measurements in California and South Atlantic Air and Global Comparison Using C2C14 and CHBr3 as Marker Molecules, Enriron. Sci. Technol., 32, 3055-3062 (1998). [Pg.261]

Benzyl alcohol and derivs 2 B91— B92 benzyl nitrate 2 B91 benzyl nitrite 2 B91 dinitrobenzyl alcohol 2 B91 dinitrobenzyl nitrate 2 B92 mononitrobenzyl alcohol 2 B91 mononitrosobenzyl alcohol 2 B91 nitrobenzyl dinitrate 2 B91-B92 nitrobenzyl nitrate 2 B91 trinitrobenzyl alcohol 2 B92... [Pg.489]

In experiments with benzyl nitrate the same workers have established that during the hydrolysis of this ester a certain quantity of benzaldehyde is obtained together with benzyl alcohol ... [Pg.8]

Baker [52], who investigated the influence of nucleophilic reagents on benzyl nitrate in anhydrous alcohol, has established that two parallel reactions proceed simultaneously (Y is a hydrolysing agent) ... [Pg.15]

N 14.14%. The following isomers are known 2-Nifro-, solid, mp 28°, prepd by refluxing 2-nitrobenzyl chloride with finely powdered Ag nitrate for 7 days(Ref 4) 3-Nitro-, pale-yel crysts mp 42.5-43°, prepd as above from 3 nitrobenzyl chloride(Ref 4) and 4 Nitro-, yel crysts, mp 71° (Ref 1), 52°(Ref2) and 68.2° (Ref 3) can be prepd by nitration of p-nitrobenzyl alcohol(Refs 1 3) by gradual introduction of benzyl nitrate into an excess of 95% nitric acid cooled to -10°(Ref 2)... [Pg.91]

The isomer 2,4 Dinitro-, crysts, d 1.55 at 25°, mp 38.8°, expl ca 180°(in 5 mins). It was prepd prior to 1944 by the DuPont Co through the following steps Benzyl chlorides 2,4-dinitrobenzyl chloride- 2,4-dinitrobenzyl alcohol- 2,4-dinitro benzyl nitrate... [Pg.92]

SC = Solventless Cordite instead of solvendess, carbamite TNBAc instead of TNBA for Trinitrobenzoic Acid TNBzN = Trinitrobenzoyl Nitrate instead of Trinitro-benzyl Nitrate... [Pg.636]

The ozone-mediated reaction of bicumene and some derivatives (11) with nitrogen dioxide in dichloromethane (kyodai nitration) at low temperatures results in the cleavage of the central C—C bond to yield the benzyl nitrate and products therefrom, in... [Pg.263]

Barium /V- pe rc h I o r y I b e n z y I a m i d e, 3642 Benzyl alcohol, 2802 Benzyl azide, 2775 Benzyl bromide, 2731 Benzyl chloride, 2734 Benzyl fluoride, 2742 Benzyl nitrate, 2761 1 -Benzyl-3-(4-tolyl)triazene, 3650 Benzylamine, 2808 Benzyldimethylamine, 3162 Benzyloxyacetylene, 3127... [Pg.2260]

The benzyl radical formed in channel (a) behaves like an alkyl radical and in air adds O2 rapidly (within a xs) to give a benzyl peroxy radical which either reacts with HO2 radicals to give a hydroperoxide, with NO2 to give a thermally unstable peroxy nitrate, or with NO to give a 10-12% yield of benzyl nitrate and 88-90% yield of an alkoxy radical which then reacts with O2 to produce benzaldehyde [15,66]. [Pg.141]

Acridine, halogenation, 59, 295 Acridine A-oxide, halogenation, 59, 295 Acridine, 9-benzyl-, nitration, 58, 251 Acridine, 9-phenyl-, nitration, 58, 251 Acridin-9(10//)-ones, see Acridones Acridizinium ion, see... [Pg.354]

In summary, the main products derived from these photochemical reactions are O3, peroxides (e.g., PAN, PBN, and H202), hydroperoxides, aldehydes, ketones, alcohols, nitro compounds (alkyl and benzyl nitrates and nitrites), and acids such as sulfuric, nitric, and nitrous acid. [Pg.177]

Toluene o-Cresol m-Cresol p-Cresol m-Nitrotoluene o-Nitrotoluene p-Nitrotoluene Benzaldehyde 2-Methyl-p-benzoquinone Benzyl alcohol Benzyl nitrate Glyoxal Methyl glyoxal Methylbutenedial Hydroxymethylbutenedial Oxoheptadienal Methylhydroperoxide Formaldehyde Hexadienyl Hydroxyoxoheptadienyl Maleic anhydride... [Pg.300]

Benzyltrimethylsilanes, on the other hand, give products of C-Si cleavage, i.e. benzyl nitrate and acetate, on treatment with cerium(IV) ammonium nitrate in AcOH based on ring substituent effects, a one-electron transfer mechanisms seems to be in operation. [Pg.649]

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