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Alkyl hypobromite preparation

Alkyl hypobromites can be prepared by the reaction of alcohols with either aqueous hypobromous acid or silver oxide-bromine or mercuric oxide-bromine in an appropriate solvent. The proposed reaction sequence for hypobromite formation is shown in Scheme 9. Bromine oxide as the intermediate has been isolated and characterized. - ... [Pg.2232]

Methylsuccinic acid has been prepared by the pyrolysis of tartaric acid from 1,2-dibromopropane or allyl halides by the action of potassium cyanide followed by hydrolysis by reduction of itaconic, citraconic, and mesaconic acids by hydrolysis of ketovalerolactonecarboxylic acid by decarboxylation of 1,1,2-propane tricarboxylic acid by oxidation of /3-methylcyclo-hexanone by fusion of gamboge with alkali by hydrog. nation and condensation of sodium lactate over nickel oxide from acetoacetic ester by successive alkylation with a methyl halide and a monohaloacetic ester by hydrolysis of oi-methyl-o -oxalosuccinic ester or a-methyl-a -acetosuccinic ester by action of hot, concentrated potassium hydroxide upon methyl-succinaldehyde dioxime from the ammonium salt of a-methyl-butyric acid by oxidation with. hydrogen peroxide from /9-methyllevulinic acid by oxidation with dilute nitric acid or hypobromite from /J-methyladipic acid and from the decomposition products of glyceric acid and pyruvic acid. The method described above is a modification of that of Higginbotham and Lapworth. ... [Pg.56]

Many of the iV-alkyl and iV-aryl derivatives of urazine have been synthesized and characterized, but the parent substance is not well known. In the past, urazine has been prepared by thermal deammonation of carbohydrazide-iV-carboxamide [eq. (I)],1 fusion of hydrazidicarbamide with hydrazinium hydrogen sulfate [eq. (2)],2 fusion of earbohy-drazide with urea [eq. (3)],3 action of sodium hypobromite on semicarbazide [eq. (4)],4 reaction of dichlorourea with concentrated ammonia [eq. (5)],5 and the reaction between 1,2 hydrazine carboxylic ester and hydrazine hydrate... [Pg.29]

Sodium hypobromite, NaOBr, is prepared in situ from bromine and aqueous sodium hydroxide under cooling. Its almost exclusive application is the degradation of methyl ketones to acids with one less carbon [635, 735, 736, 737]. Such degradation is achieved not only with methyl ketones but also with other alkyl ketones [103, 160], Other oxidations, such as the conversion of hydroxylamines into nitroso compounds, are rare [738]. [Pg.29]

Alkyl hypochlorites and hypobromites are relatively stable molecules alkyl hypoiodites can only be prepared in situ, usually by the reaction of alcohols with metal acetates or oxides and iodine or by the reaction of alcohols with a hypervalent iodine compound and iodine.1319 Alkyl hypochlorites and hypoiodites can be utilized in reactions that parallel those of the organic nitrites (Barton reaction Section 6.4.2). For example, the photochemistry of the steroidal hypoiodite 497, prepared by the reaction of the corresponding alcohol with iodine oxide (I2O) generated from mercury(II) oxide and molecular iodine in situ, affords a new five-membered ring via an O I bond fission, 1,5-hydrogen abstraction and substitution (Scheme 6.244).1353... [Pg.403]

Although alkyl hypochlorites and hypobromites are isolable species, alkyl hypoiodites are not isolable. They can only be prepared in situ, either by the reaction of alcohols with metal acetates or oxide and iodine in solution, or by the reaction of alcohols with a hypervalent iodine compound and iodine in... [Pg.2232]


See other pages where Alkyl hypobromite preparation is mentioned: [Pg.2229]    [Pg.2232]    [Pg.261]    [Pg.261]    [Pg.150]    [Pg.2234]   


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