Amine alkane

Amines are named m two mam ways m the lUPAC system either as alkylamines or as alkanamines When primary amines are named as alkylamines the ending amine IS added to the name of the alkyl group that bears the nitrogen When named as alkan amines the alkyl group is named as an alkane and the e ending replaced by amine... 

The acidity probes discussed above are the most commonly used. However, the use of many different probes has been reported in the literature. This list includes nitriles, alkanes, amines, water, di-hydrogen, deuterium, isotopically labeled molecules, benzene, etc. Probe molecules can also be used to measure basicity on zeohtes. In this case, weakly acidic molecules such as CO2, pyrrole, acetic acid and halogenated light paraffins have been used. Space does not permit discussion of these in any detail, but information about these probes and their applications can be found in the following references [87, 127-130]. 

The first chapter concerns the chemistry of the oxidation catalysts, some 250 of these, arranged in decreasing order of the metal oxidation state (VIII) to (0). Preparations, structural and spectroscopic characteristics are briefly described, followed by a summary of their catalytic oxidation properties for organic substrates, with a brief appendix on practical matters with four important oxidants. The subsequent four chapters concentrate on oxidations of specific organic groups, first for alcohols, then alkenes, arenes, alkynes, alkanes, amines and other substrates with hetero atoms. Frequent cross-references between the five chapters are provided. 

One type of organic compound can be determined quantitatively in the presence of a different type, such as the percentage of alcohols in alkanes, amines in alcohols, aromatics and aliphatics in petroleum, olefins in hydrocarbon mixtures, organic halides and organo-metallic compounds in other organic compounds, or the number of side chains in a hydrocarbon. The method is not limited in the number of components that can be identified as long as there is at least one peak in the spectrum that is unique to each component. 

The reaction of MBFI adduct with alkane-amines also provided an effective protocol to synthesize pyrrolidin-2-one derivatives via nucleophilic reaction and subsequent cyclization processes. Ayed et al. first reported the direct condensation of MBH adduct with primary amines in methanol to afford 3-hydroxyl pyrrolidin-2-ones 410 in good to excellent yields (Scheme 4.130). The reaction of (5)-phenylethylamine with MBH adduct 411 was reported to generate an equimolar mixture of the 4,5-ci5-disubstituted pyrrolidin-2-ones 412 and 413 (Scheme 4.131). Interestingly, pyrrolidin-2-one 413 could be further used to synthesize the glycosidase inhibitor 414. ... 

RuClH(PPh3)3] 1-Alkenes, nitroalkanes, aldehydes Alkanes, amines, alcohols ) H2 0.1 MPa, 298 K... 

Table 11.2 A Comparison of Alkane, Amine, and Alcohol Boiling Points ...

The kinetics of ligand substitution on Cr(CO)5(heptane) was studied by Yang et al. and the rate constants vary by 20 for different entering groups. As noted above, the AH for CO and H2O substitution on Cr(CO)5(CgH,2) is smaller than the Cr—(CjH,2> bond strength. These observations seem most consistent with associative activation. On the other hand, van Eldik and co-workers have done several studies in mixed alkane/amine solvents and interpret the observed values of AV in terms of dissociative activation. 

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