Alkanes aldehydes

In reaction (52), the organic can be any species with abstractable hydrogen atoms, including alkanes, aldehydes, etc. 

Small alkylperoxy and alkoxy radicals can decompose uni-molecularly, though their rate constants are often in the second-order region. They abstract hydrogen atoms from alkanes, aldehydes, esters, and acids, add to olefins, and may react with 02. Furthermore, interactions with other radicals can lead to disproportionation or combination. These reactions are reviewed, and particular attention is given to CH 02 and CH30 a number of rate constants are estimated. 

Methyl benzoate (aryl ester) 3-Methylbutanal (alkane aldehyde)... 

Atomic Charges—Methodology and Application to Alkanes, Aldehydes, Ketones, and Amides. 

Dinur U and A T Hagler 1995. Geometry-Dependent Atomic Cliarges Methodology and Application to Alkanes, Aldehydes, Ketones and Amides Journal of Computational Chemistry 16 154-170. 

One important consideration in any catalytic oxidation process at conditions of interest herein is the possible formation of hazardous incomplete oxidation products. One simple example is the formation of CI2 observed in the catalytic oxidation of methyl chloride over a-CrjOj/AljOj. Products that are even more toxic are of course possible. For all alcohols, aromatics, alkanes, aldehydes, naphthenes, ketones, and esters, the products of complete oxidation would of course be CO, and H,0. Although many VOCs are from these chemical classes, other associated compounds may lead to other products ... 

Alkynes give alkenes and alkanes. Aldehydes give primary alcohols. Ketones give secondary alcohols. 4.46 a. +2CH3CH2OH... 

Food irradiation may now be used in over 40 countries. The short chapter by Morsel describes the need to find markers which indicate that food has been irradiated (Chapter 7). The lipids which have been examined as potential markers include hydroperoxides, alkenes, alkanes, aldehydes and cyclo-butanones. Derivative formation with cyclobutanones can increase the sensitivity of detection of butanones in irradiated food. 

C.-J. Lee, Y.-J. Jang, Z.-Z. Wu, W. Lin, Org. Lett. 2012, 14, 1906-1909. Preparation of functional phosphorus zwitterions from activated alkanes, aldehydes, and tributylphos-phine synthesis of polysubstituted furo[3,2-c]coumarins. 

Cobalt-catalyzed hydroformylation is a typical example of how the nature of the ligand and the reaction conditions may lead either to alkanes, aldehydes, or... 

The reactions of atomic oxygen with alkanes, aldehydes, alcohols, and alkyl halides have been reported to proceed mostly as follows... 

Indirect oxidation of propylene is an important route for propylene oxide production that proceeds in two reaction steps. The first step is the formation of a peroxide from alkanes, aldehydes, or adds by oxidation with air or oxygen. The second reaction step is the epoxidation of propylene to PO by oxygen transfer from the peroxide with formation of water, alcohol, or acid. The catalytic oxidation of propylene with organic hydroperoxides is nowadays a successful commercial production route (51% of world capacity). Two organic hydroperoxides dominate the processes (i) a process using isobutane (peroxide tert-butyl hydroperoxide, co-product tert-butyl alcohol), which accounts for 15% of the world capacity and (ii) a process using ethylbenzene (peroxide ethylbenzene hydroperoxide, co-product styrene) that accounts for 33% of the world capacity. The process via isobutane is presented by ... 

This reactivity makes it possible to synthesize a wide variety of compounds from alkenes. For example, we will see that alkyl halides, alcohols, ethers, epoxides, alkanes, aldehydes, and ketones can all be synthesized from alkenes by electrophilic addition reactions. The particular product obtained depends only on the electrophile and the nucleophile used in the addition reaction. 

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