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Starch aldehydes

Aldehyde starches are prepared by treatment with periodic acid/periodate ions, which selectively oxidize the adjacent hydroxyl groups on carbon atoms 2 and 3 to aldehyde groups. Dialdehyde starch can react with cellulose by forming covalent hemiacetal and acetal bonds.40 It is primarily used as a wet strength agent in the production of tissue and other sanitary grades. [Pg.665]

In addition, they are used in combination with casein solutions and synthetic resin emulsions. Whereas starch ethers and esters and also aldehyde starches are used to only a limited extent in the adhesives field, the thermal degradation products of starches, the water-soluble dextrins, are still important in quantitative terms as raw materials for adhesives. They are used on their own in aqueous form or as mixtures with synthetic resin emulsions. [Pg.10]

Molisch s Test. Dissolve about 01 g. of the carbohydrate in z ml. of water (for starch use 2 ml. of starch solution ), add 2-3 drops of a 1 % alcoholic solution of i-naphthol (ignoring traces of the latter precipitated by the water) and then carefully pour 2 ml. of cone. H2SO4 down the side of the test-tube so that it forms a heavy layer at the bottom. A deep violet coloration is produced where the liquids meet. This coloration is due apparently to the formation of an unstable condensation product of i-naphthol with furfural (an aldehyde produced by the dehydration of the carbohydrate). [Pg.367]

Almost insoluble in cold water. Higher alcohols (including benzyl alcohol), higher phenols (e.g., naphthols), metaformaldehyde, paraldehyde, aromatic aldehydes, higher ketones (including acetophenone), aromatic acids, most esters, ethers, oxamide and domatic amides, sulphonamides, aromatic imides, aromatic nitriles, aromatic acid anhydrides, aromatic acid chlorides, sulphonyl chlorides, starch, aromatic amines, anilides, tyrosine, cystine, nitrocompounds, uric acid, halogeno-hydrocarbons, hydrocarbons. [Pg.404]

Brown resinous product formed. Aliphatic aldehydes (except formaldehyde) carbohydrates and soluble starch (sucrose and ordinary starch only faintly coloured). [Pg.407]

Carbohydrates may be divided into monosaccharides, disaccharides and polysaccharides. The monosaccharides under certain conditions react as polyhydroxy-aldehydes or polyhydroxy-ketones two important representatives are glucose CjHjjO (an aldose) and fructose (laevulose) CgHuO, (a ketose). Upon hydrolysis di- and polysaccharides 3deld ultimately monosaccharides. Common disaccharides are sucrose, lactose and maltose (all of molecular formula C,2H2. 0,), whilst starch, dextrin and cellulose, (CjHjoOj), in which n > 4, are typical polysaccharides. [Pg.449]

Yeast (qv) metabolize maltose and glucose sugars via the Embden-Meyerhof pathway to pymvate, and via acetaldehyde to ethanol. AH distiUers yeast strains can be expected to produce 6% (v/v) ethanol from a mash containing 11% (w/v) starch. Ethanol concentration up to 18% can be tolerated by some yeasts. Secondary products (congeners) arise during fermentation and are retained in the distiUation of whiskey. These include aldehydes, esters, and higher alcohols (fusel oHs). NaturaHy occurring lactic acid bacteria may simultaneously ferment within the mash and contribute to the whiskey flavor profile. [Pg.84]

Alcohol to acetic acid Aldehydes to alcohols (e.g., acetaldehyde to ethyl alcohol) Starch to glucose Hexose phosphate from hexose and phosphoric acid... [Pg.855]

Tannins comprise various polyhydroxyphenols and polysaccharides (polysaccharoses), which are complex carbohydrates (polyhydroxy aldehydes or ketones) and include starches and cellulose, and their... [Pg.405]

Carbohydrates include sugars, starches, and cellulose. Glucose is an alcohol and an aldehyde that polymerizes to form starch and cellulose. [Pg.894]

Figure 30.3 C NMR spectrum of oxidized starch. (Signals at 171.6 and 180.5 ppm are attributed to carboxyl and aldehyde groups, respectively). Figure 30.3 C NMR spectrum of oxidized starch. (Signals at 171.6 and 180.5 ppm are attributed to carboxyl and aldehyde groups, respectively).
We have developed an efficient and practical method for clean oxidation of starch (21-23) resulting in the oxidation of primary alcohol function in Ce position and the cleavage of vicinal diols in C2 and C3 position (Figure 30.2). We used small amounts of cheap iron tetrasulfophthalocyanine catalyst, pure water as reaction medium and H2O2 as clean oxidant to achieve a one-pot conversion of starch resulting in the introduction of aldehyde and carboxyl functions in polymer chains. The iron content... [Pg.266]

Although the pyrolysis of some classes of polysaccharide materials has been studied quite extensively in the food, petrol and tobacco industry, very little has been published specifically on polysaccharide binders (arabic gum, tragacanth gum, fruit tree gum, honey and starch). The pyrolysis of glucane based polymers, especially cellulose, has been studied in detail [6,55], highlighting how anhydrosugars and furan derivatives are the main pyrolysis products, together with one-, two- and three-carbon aldehydes and acids. [Pg.314]

Its toxicity is discussed by Curme Johnston (Ref 4, p 317). In skin absorption it is about l/l0th as toxic as formaldehyde The industrial utilization of glyoxal is largely based on the advantage which may be taken of its two aldehyde groups, its lack of volatility from aqueous solns, and its inoffensive color. Among its uses may be cited in-solubilizing of proteins, polyvinyl, alcohol, starch, etc (Ref 4, p 127) (See also Ref 5). [Pg.760]


See other pages where Starch aldehydes is mentioned: [Pg.16]    [Pg.20]    [Pg.20]    [Pg.257]    [Pg.16]    [Pg.20]    [Pg.20]    [Pg.257]    [Pg.1069]    [Pg.27]    [Pg.518]    [Pg.10]    [Pg.19]    [Pg.342]    [Pg.96]    [Pg.342]    [Pg.543]    [Pg.893]    [Pg.169]    [Pg.1069]    [Pg.265]    [Pg.267]    [Pg.177]    [Pg.499]    [Pg.103]    [Pg.186]    [Pg.188]    [Pg.62]    [Pg.145]    [Pg.28]    [Pg.502]    [Pg.107]    [Pg.194]    [Pg.195]    [Pg.279]    [Pg.154]    [Pg.633]    [Pg.245]    [Pg.210]   
See also in sourсe #XX -- [ Pg.665 ]




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