Adsorbent, glass powder

The adsorbent—a powder generally, but it could be a metal or oxide film— is placed in a glass tube (the adsorption cell C in Fig. 15) which is connected to the volumetric and vacuum lines. The bottom part of the tube, which contains the adsorbent and is located in the calorimeter cell, is made of thin-walled (0.2-0.3 mm) blown tubing (A in Fig. 18). In order to avoid the slow diffusion of gases through a thick layer of adsorbent (see Section VII.A), the sample is often placed in the annular space between the inner wall of the adsorption cell and the outer wall of a cylinder made of glass,... 

The glass powder, which served as the adsorbent, was obtained from the Arthur S. Lapine Company in the form of spherical beads approximately 40 fL in diameter. The beads were washed with a large quantity of distilled water and dried in an oven at 120 °C. before use in the adsorption experiments. 

Open tubular columns are simply capillary tubes in which the inside of the column wall is used as the support for the liquid phase. These wall-coated open tubular columns (WCOT) have the stationary phase distributed in the form of a thin film on the inside surface of the open capillary tube, the walls thus serving as the support. In order to reduce the thickness of the liquid phase film, a porous layer may be formed on the inside wall of the capillary tubing and then coated with the liquid phase to produce a support-coated open tubular column (SCOT). Porous-layer open tubular colunms (PLOT) are similar to SCOT colunms, the difference being that in the former, the stationary phase is deposited on fine crystalline particles or glass powder which is adsorbed onto the walls of the tube. In both cases, the available surface area of the wall is increased, and allows an increased amount of liquid phase to be accommodated in the same length and diameter of tubing. The whisker-walled (WW) colunm consists of whiskers chemically etched on the surface of the wall, which also result in a significant increase in the available surface area. Wall-coated, porous-layer, and support-coated capillary columns are all available as whisker-walled, i.e., WWCOT, WWPLOT, and WWSCOT, respectively. 

We wish to report some work on the adsorption of acid and alkali-precursor gelatins, the water-soluble products of collagen. The study of both types allowed us to determine whether the differences exhibited by the two kinds in solution are reflected in the adsorbed state, and offers some insight into the state of flexible molecules at interfaces. The use of two dissimilar adsorbents, glass and stainless steel powders, should yield information on segment-surface interactions during the adsorption process. Some effects of added calcium ions were also studied since the Ca-ions of hydroxyapatite in bone and teeth are intimately related to collagen. 

Vitrification of the iodine-adsorbed magnesium compound was tested as follows (Scheme 1) To the prepared MgO-P20s glass powder, 5-15mass% of the iodine-adsorbed compound was added, and then, the resultant mixture was melted at 1300°C for 20 Glass samples were obtained after the same... 

Classed under this heading are media made from metal powder and fibres, ceramic powder and mineral wools, glass powder and carbon fibres (used for their mechanical separation ability, not as adsorbent). 

The Karl Fischer procedure was applied to the determination of water present in hydrated salts or adsorbed on the surface of solids. The procedure, where applicable, was more rapid and direct than the commonly used drying process. A sample of the finely powdered solid, containing 5-10 millimoles (90-180 mg) of water, was dissolved or suspended in 25 mL of dry methanol in a 250-mL glass-stoppered graduated flask. The mixture was titrated with standard Karl Fischer reagent to the usual electrometric end point. A blank titration was also carried out on a 25 mL sample of the methanol used to determine what correction (if any) needed to be applied to the titre obtained with the salt. 

Kanan, S.M., Tze, W.T.Y., and Tripp, C.P. (2002) Method to double the surface concentration and control the orientation of adsorbed (3-aminopropyl)dimethylethoxysilane on silica powders and glass slides. Langmuir 18(17), 6623-6627. 

Gas chromatography makes use, as the stationary phase, a glass or metal column fdled either with a powdered adsorbent or a non-volatile liquid coated on a non-adsorbent powder. The mobile-phase consists of an inert-gas loaded with the vapourised mixture of solutes flowing through the stationary phase at a suitable temperature. In the course of the passage of the vapour of the sample through the column, separation of the components of the sample occurs in two ways, namely ... 

A TLC system comprises three elements. As its name implies, one of the elements is thin layer coated mostly on a glass or plastic plate, which acts as a stationary phase. Such a plate is termed chromatoplate . The most popular materials (adsorbent) used to form the thin layer are silica gel and alumina powder. The other elements are a sample, and a solvent or solvent mixture (developer) which acts as a mobile phase to develop (elute) the sample. A stock solution of sample is prepared in advance of the TLC experiment and applied to the thin layer to form a spot. After removal of solvent contained in the spot, the sample is eluted with an appropriate... 

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