Fluidization, adsorbent

Fluidized-bed adsorbers have several disadvantages. The continuous handling and transport of solids is expensive from an equipment standpoint fluidized-bed systems must be large to be economical. Solids handling also presents a potential for mechanical problems. Careful control is required to keep the adsorbent fluidized, while minimizing adsorbent loss with the gas-phase attrition of the adsorbent can be high, requiring substantial makeup. 

Loch-Bonazzi et al. [33] evaluated the quality of mushrooms dried by various processes such as hot air, vacuum, freeze-drying in an adsorbent fluidized bed and vacuum freeze-drying. Results of their study indicated that vacuum freeze-dried products were of superior quality in... 

Wolff E, Gibert H. Freeze-drying under vacuum and in an adsorbing fluidized bed influence of operation pressure on drying kinetics. In Mujumdar AS, Filkova I, eds. Drying 91. Amsterdam Elsevier Science Publishers, 1991, pp 237-240. 

Loch-Bonazzi et al. [33] evaluated the quality of mushrooms dried by various processes such as hot air, vacuum, freeze-drying in an adsorbent fluidized bed and vacuum freeze-drying. Results of their study indicated that vacuum freeze-dried produets were of superior quality in terms of density, rehydration eap-acity, and color. They also reported that most flavor compounds disappear during preparation and freezing steps. Microwave vacuum drying of mushroom has been explored by Pappas et al. [34]. Their experimental results indicated that microwave-vacuum drying exhibits superior drying performance as well as improved rehydration characteristics. 

The commercialization by Kureha Chemical Co. of Japan of a new, highly attrition-resistant, activated-carbon adsorbent as Beaded Activated Carbon (BAC) allowed development of a process employing fluidized-bed adsorption and moving-bed desorption for removal of volatile organic carbon compounds from air. The process has been marketed as GASTAK in Japan and as PURASIV HR (91) in the United States, and is now marketed as SOLD ACS by Daikin Industries, Ltd. 

Pressure Drop. The prediction of pressure drop in fixed beds of adsorbent particles is important. When the pressure loss is too high, cosdy compression may be increased, adsorbent may be fluidized and subject to attrition, or the excessive force may cmsh the particles. As discussed previously, RPSA rehes on pressure drop for separation. Because of the cychc nature of adsorption processes, pressure drop must be calculated for each of the steps of the cycle. The most commonly used pressure drop equations for fixed beds of adsorbent are those of Ergun (143), Leva (144), and Brownell and co-workers (145). Each of these correlations uses a particle Reynolds number (Re = G///) and friction factor (f) to calculate the pressure drop (AP) per... 

Seal legs are frequently used in conjunction with solids-flow-control valves to equ ize pressures and to strip trapped or adsorbed gases from the sohds. The operation of a seal leg is shown schemati-caUy in Fig. 17-19. The sohds settle by gravity from the fluidized bed into the seal leg or standpipe. Seal and/or stripping gas is introduced near the bottom of the leg. This gas flows both upward and downward. Pressures indicated in the ihustratiou have no absolute value but are only relative. The legs are designed for either fluidized or settled solids. 

In fluidized-bed adsorbers, the combination of high gas rate and small adsorbent particle size results in suspension of the adsorbent, giving it many of the characteristics of a fluid. Fluidized bed adsorbers, therefore, lend themselves to truly continuous, countercurrent, multistage operation. Adsorbent inventory is minimized. 

Carbon should be prewetted prior to being placed in the test columns. Backwashing the carbon at low rates (2.5 m/hr) does not remove the air. Rates that would expand the bed 50 percent or 15-30 m/hr, are required. The liquid used for prewetting can either be water, if it is compatible with the liquid to be treated, or a batch of the liquid to be treated which has been purified previously. There are three types of carbon systems (1) fixed beds, (2) pulse beds, and (3) fluidized beds, and these can be used singly, in parallel, or in combination. The majority of systems are either fixed or pulse beds. The two basic types of adsorbers which can be designed to operate under pressure or at atmospheric pressure are the moving or pulse bed and the fixed bed. Either can be operated as packed or expanded beds. 

The adsorption process is normally performed in a column. The column is run as either a packed- or fluidized-bed operation. The adsorbent, after it has reached the end of its useful life, can either be discarded or regenerated. For further information, the reader is directed to the literature. ... 

Equation (15) is derived under the assumption that the amount of adsorbed component transferred by flow or diffusion of the solid phase may be neglected. This assumption is clearly justified in cases of fixed-bed operation, and it is believed to be permissible in many cases of slurries or fluidized beds, since the absolute amount of adsorbed component will probably be quite low due to its low diffusivity in the interior of the catalyst pellet. The assumption can, however, be waived by including in Eq. (15) the appropriate diffusive and convective terms. 

As mentioned in Section 11.3, fluidized-bed reactors are difficult to scale. One approach is to build a cold-flow model of the process. This is a unit in which the solids are fluidized to simulate the proposed plant, but at ambient temperature and with plain air as the fluidizing gas. The objective is to determine the gas and solid flow patterns. Experiments using both adsorbed and nonadsorbed tracers can be used in this determination. The nonadsorbed tracer determines the gas-phase residence time using the methods of Chapter 15. The adsorbed tracer also measures time spent on the solid surface, from which the contact time distribution can be estimated. See Section 15.4.2. 

Metallocenes are homogeneous catalysts that are often soluble in organic solvents. Therefore, polymerization can occur via a solution process with a non-polar diluent dissolving the propylene gas, the catalyst, and the co-catalyst system. They can also be adsorbed onto an inert substrate which acts as part of the fluidized bed for gas phase polymerization processes. 

Using three-dimensionally structured adsorbent with a large number of uniform gas channels, the limitations of mass transfer kinetics and fluidization of the conventional beaded sorbents may be removed. Such structured adsorbents have been described in... 

DAP-Mn Also called the Manganese Dioxide Process. A flue-gas desulfurization process using a fluidized bed of manganese dioxide, which becomes converted to manganous sulfate. The adsorbent is regenerated with ammonia. 

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