Construction of the adsorption isotherm

A number of potential sources of error must be taken into account. In the volumetric method the following items need attention (a) constancy of the level of liquid nitrogen (b) depth of immersion of the sample bulb ( S cm) (c) temperature of sample (monitoring with vapour pressure thermometer close to sample bulb) (d) purity of adsorptive (preferably 99-9 per cent) (e) temperature of gas volumes (doser, dead space), controlled to 01 C. 

With gravimetric methods, the magnitude of the buoyancy correction should be assessed. Particular attention must be paid to the adsorbent temperature because of the unavoidable gap between the sample and the balance case (cf. Section 6.2). 

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