Actual phase current

For single-component systems, the theoretical solutions obtained are easy to compare to experimental profiles. They differ only by the smoothing effect due to axial dispersion and to the finite kinetics of mass transfers in actual columns. In many cases, because of the qualities of the stationary phases currently available, these effects appear to be secondary compared to the major role of thermodynamics in controlling the band proffles in overloaded elution. Admittedly, the influence of the finite coliunn efficiency on the band profiles prevents a successful quantitative comparison between theoretical and experimental band profiles. However, these profiles are similar enough at high concentrations and the solutions of the ideal model indicate which are the trends to be expected. 

In the previous section we gave a physical explanation of how various current components on finite arrays came about. Furthermore, we used the SPLAT program in conjunction with a Fourier analysis to determine the actual element currents on a finite array. We decomposed these according to their phase velocities and found one strong component at Tcx = = 0.707 for 45° angle of... 

To ensure proper sensing of the incoming current and its phase displacement by the relay it i.s es.senlial that the CTs ratio and their VA burden chosen for the required duty are close to the actual requirement as noted in Table I. S.8.. Sometimes this fact is overlooked and CTs with a much higher VA burden or ratio or both are chosen while the secondary circuit may not be adequately loaded. In this case the CTs may not accurately transform the primary parameters to the secondary and. in turn, the relay may not send accurate signals. Moreover, the relay itself may operate only at minimum 19c or more of its rated current (I or 5 A), depending upon its design and type (lEC 60051-1). 

We have considered each phase composed of lour bus sections to calculate F, to be on the sale side. In fact the current of each phase is split into two circuits in this arrangement similar to the arrangement of interleaving and hence the actual F will also be only half that considered above. 

The use of kinetic inhibitors and/or anti-agglomcrators in actual fieid operations is a new and evolving technology. These are various formulations of chemicals that can be used in a mixture of one or more kinetic inhibitors and/or anti-agglomerators. At the current time, to get an optimum mixture for a specific application it is necessary to set up a controlled bench test using the actual fluids to be inhibited and determine the resulting equilibrium phase line. As the mixture of chemicals is changed, a family of equilibrium phase lines will develop. This will result m an initial determination of a near optimum mixture of chemicals. 

The power factor is the factor by which the apparent kva power is multiplied to obtain the actual power, kw, in an alternating current system. It is the ratio of the in-phase component of the line current to the total current. ... 

This value does not express the actual result since side and/or parallel reactions (e.g., H+ or 02 reduction) are not considered, but it does demonstrate the completeness of the cementation process and the effectiveness of this liquid-liquid extraction. During this extraction no external current flows through the phase boundary Hg (amalgam)/solution thereby establishing a potentiometric condition. The question of the potential difference at the phase boundary can be answered by constructing the experimentally accessible current-voltage curves for the reactions ... 

Under conditions of nonlimiting interfacial kinetics the normalized steady-state current is governed primarily by the value of K y, which is the relative permeability of the solute in phase 2 compared to phase 1, rather than the actual value of or y. In contrast, the current time characteristics are found to be highly dependent on the individual K. and y values. Figure 16 illustrates the chronoamperometric behavior for K = 10, log(L) = —0.8 and for a fixed value of Kf.y = 2. It can be seen clearly from this plot that whereas the current-time behavior is sensitive to the value of Kg and y, in all cases the curves tend to be the same steady-state current in the long-time limit. This difference between the steady-state and chronoamperometric characteristics could, in principle, be exploited in determining the concentration and diffusion coefficient of a solute in a phase that is not in direct contact with the UME probe. 

We shall consider the voltammetric behavior of a base at the 0/W interface. In the discussion stated above it is assumed that the transfer process of drugs at the 0/W interface is of reversible nature (see the assumptions 1-6 above). With increasing pH of the W phase, particularly in basic solutions, however, the rate of protonation in the W phase, that is, B(W) - - H+(W) = BH+(W) should rapidly decrease, resulting in decreasing of the current associated with the transfer of BH+ ion across the O/W interface. This has actually... 

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