Acrylic rubber ACM

Ta b I e 5.62 Upper and lower temperature limits for elastomeric materials (R C backbone with unsaturated units, M C backbone with only saturated units, 0 both C and 0 in the backbone, U C, N and 0 in the backbone, T C and S in the backbone, Q siloxane backbone NR natural rubber, IR isoprene rubber, BR butadiene rubber, CR chloroprene rubber, SBR styrene butadiene rubber, NBR nitrile rubber, HR butyl rubber, EPDM ethylene propylene ter-rubber, EAM ethylene vinyl acetate rubber, FKM fiuoro rubber, ACM acrylate rubber, CSM chlorosulfonated polyethylene, CM chlorinated polyethylene, ECO epichlorohydrin rubber (epichlorohydrin, ethylene oxide), AU polyurethane rubber (did), EU polyurethane rubber (diisocyanate), VMQ silicone rubber) specialties [229]... 

Acrylic rubbers, as is the case for most specialty elastomers, are characterized by higher price and smaller consumption compared to general-purpose mbbers. The total mbber consumption ia 1991 was forecast (55) at 15.7 million t worldwide with a 66% share for synthetic elastomers (10.4 x 10 t). Acryhc elastomers consumption, as a minor amount of the total synthetic mbbers consumption, can hardly be estimated. As a first approximation, the ACM consumption is estimated to be 7000 t distributed among the United States, Western Europe, and Japan/Far East, where automotive production is significantly present. 

FIGURE 3.3 (a) Transmission electron microscopic (TEM) image of acrylic rubber (ACM)-siUca hybrid nanocomposite synthesized from 10 wt% of tetraethoxysilane (TEOS). (From Bandyopadhyay, A., Bhowmick, A.K., and De Sarkar, M., J. Appl. Polym. Sci., 93, 2579, 2004. Courtesy of Wiley Interscience.) Transmission electron microscopic (TEM) photographs of acrylic rubber (ACM)-silica hybrid nanocomposites prepared from (b) 30 wt% and (c) 50 wt% tetraethoxysilane (TEOS) concentrations. (From Bandyopadhyay, A., Bhowmick, A.K., and De Sarkar, M., J. Appl. Polym. Sci., 93, 2579, 2004. Courtesy of Wiley InterScience.)... 

FIGURE 3.16 Morphology and visual appearance of acrylic rubber (ACM)-silica and epoxidized natural rubber (ENR)-silica hybrid composites prepared from different pH ranges (a) transmission electron microscopic (TEM) picture of ACM-siUca in pH 1.0-2.0, (b) scanning electron microscopic (SEM) picture of ACM-siUca in pH 5.0-6.0, (c) SEM image of ACM-siUca in pH 9.0-10.0, (d) TEM picture of ENR-silica in pH... 

FIGURE 3.17 Tensile stress-strain plots for uncross-linked acrylic rubber (ACM)-siUca and epoxidized natural rubber (ENR)-silica hybrid composites synthesized from various pH. Letter p in the legends indicates pH and the numbers following the letter are indicative of the pH ranges e.g., 1 means pH range of 1.0-2.0, similarly 3 means 3.0-4.0. (From Bandyopadhyay, A., De Sarkar, M., and Bhowmick, A.K., J. Mater. Sci., 41, 5981, 2006. Courtesy of Springer.)... 

TPEs prepared from rubber-plastic blends usually show poor high-temperature properties. This problem could be solved by using high-melting plastics like polyamides and polyesters. But, often they impart processing problems to the blends. Jha and Bhowmick [49] and Jha et al. [50] have reported the development and properties of novel heat and oil-resistant TPEs from reactive blends of nylon-6 and acrylate rubber (ACM). The properties of various thermoplastic compositions are shown in Table 5.4. In this kind of blend, the plastic phase forms the continuous phase, whereas... 

FIGURE 5.16 Viscosity-shear stress relationships for various compositions of nylon-6-acrylate rubber (ACM) blends at 240°C. 

The effect of polymer-filler interaction on solvent swelling and dynamic mechanical properties of the sol-gel-derived acrylic rubber (ACM)/silica, epoxi-dized natural rubber (ENR)/silica, and polyvinyl alcohol (PVA)/silica hybrid nanocomposites was described by Bandyopadhyay et al. [27]. Theoretical delineation of the reinforcing mechanism of polymer-layered silicate nanocomposites has been attempted by some authors while studying the micromechanics of the intercalated or exfoliated PNCs [28-31]. Wu et al. [32] verified the modulus reinforcement of rubber/clay nanocomposites using composite theories based on Guth, Halpin-Tsai, and the modified Halpin-Tsai equations. On introduction of a modulus reduction factor (MRF) for the platelet-like fillers, the predicted moduli were found to be closer to the experimental measurements. 

ID IQ 2D 2D-NMR 2h2o 2Q 3Q 9BEN A1 ABS AC ACM ACN AFM Al-CSM ALMA-i5 Al-m-EPDM AN AO APT ASTM ATR ATR-IR B/S BABA Two-dimensional Single-quantum One-dimensional Deuteron solid-state NMR Deuterated water Double-quantum Triple-quantum 9 borobicyclo [3, 3, 1] nonane Amide 1 Acrylonitrile-butadiene-styrene terpolymer Accelerator Acrylate rubber Acrylonitrile Atomic Force Microscopy Aluminium salt of chlorosulfonate polyethylene Allyl-rf5 methacrylate Aluminium salt of maleated EPDM Acrylonitrile 1-Allyl oxyoctane Attached Proton Test American Standards for Testing and Materials Attenuated total reflectance spectroscopy Attenuated total reflectance-IR spectroscopy Butadiene/styrene Back-to-back... 

AAAS American Association of the Advance- ACM acrylic acid ester rubber... 

Acrylic Rubbers (ACMs). Polar elastomers are obtained by the copolymerization of acrylate esters with monomers, which contain reactive sites for cross-hnking reactions to take place during vulcanizations. The general chemical structure for ACM rubbers is as follows ... 

Properties of Acrylic Rubbers. The ultimate tensile properties of ACM vulcanizates are not as good as those of NR or NBR, but the tensile properties are sufficient for their applications. ACM grades can be used under certain conditions for 1000 hr at 160 to 170°C. ACM vulcanizates can withstand exposures of 1000 hr in oil at 150°C. In addition, ACM vulcanizates are very resistant to degradation by the action of ozone. 

Uses of Acrylic Rubbers. The main uses of ACM are in automotive and engineered products. Applications include seals and O-rings (for crankshafts, automatic and differential transmissions, valves, and so on) and oil hose. ACM vulcanizates are also used for roll coverings, tank linings, and fabric covering. 

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