Acetic diphenyl

Phosphites. The phosphates, second only to phthalates in production volume, are favored for flame resistance and low volatility. Tricresyl phosphate (mixed meta and para isomers) is the most popular it is used in polyvinyl chloride and in nitrocellulose lacquers. Resins plasticized with tricresyl phosphate are deficient in low-temperature flexibility. Diphenyl cresyl phosphate and triphenyl phosphate are other examples, the former for polyvinyl chloride, the latter for cellulose acetate. Diphenyl-2-ethylhexylphosphate is preferred to tricresyl phosphate in polyvinyl chloride where its low toxicity and improved low-temperature flexibility are required. Tn(2-elliylliexyl)-phosphale is outstanding among phosphates used in polyvinyl chloride with respect to low-temperature flexibility in flame- and oil resistance, however, it is inferior to tricresyl phosphate. Tri(butoxvethyl)phosphate finds some use in synthetic rubber. 

Purines Mercuric acetate-diphenyl carbazone Shadows on violet background (circle after appearance not stable)... 

Diethylene glycol monobutyl ether acetate Diphenyl 2-ethylhexyl phosphate Ethyl n-butyrate... 

Diphenyl. Reflux a mixture of 1 g, of diphenyl, 2 ml. of glacial acetic acid and 0 -5 ml. of fuming nitric acid for 10 minutes. Pour into 20 ml. of cold water, filter oflF the precipitate, wash it with cold water imtil free from acid, and recrystallise from alcohol. The product is 4-nitrodiphenyl, m.p. 114°,... 

Diphenic acid. Phenanthrene upon oxidation in acetic acid solution at 85° with 30 per cent, hydrogen peroxide gives diphenic acid (diphenyl-2 2 -di-carboxyHc acid) no phenanthraquinone is formed under these experimental conditions. The reaction is essentially an oxidation of phenanthrene with peracetic acid. (For another method of preparation, see Section I V,74.)... 

Place 125 ml. of glacial acetic acid, 7 -5 g. of purifled red phosphorus (Section II,50,d) and 2 5 g. of iodine in a 500 ml, round-bottomed flask fitted with a reflux condenser. Allow the mixture to stand for 15-20 minutes with occasional shaking until aU the iodine has reacted, then add 2 5 ml. of water and 50 g, of benzilic acid (Section IV,127). Boil the mixture under reflux for 3 hours, and filter the hot mixture at the pump through a sintered glass funnel to remove the excess of red phosphorus. Pour the hot filtrate into a cold, weU-stirred solution of 12 g. of sodium bisulphite in 500 ml, of water the latter should be acid to litmus, pro duced, if necessary, by passing sulphur dioxide through the solution. This procedure removes the excess of iodine and precipitates the diphenyl-acetic acid as a fine white or pale yellow powder. Filter the solid with suction and dry in the air upon filter paper. The yield is 45 g., m.p. 

The preparation of these [4-hydroxy-THISs, (1), X = O] by cydization of a-carboxy-N-arylthiobenzimides (5) by treatment with acetic anhydride and triethylamine has been investigated in detail, and the structure has been revised for the compound previously described as 2.3-diphenyl-4-hydroxythiazolium hydroxide inner salt (1, X = 0, R = R = Ph, R = H) (Scheme 5) (3, 10). 4-Hydroxy-THlSs also arise by condensation of gem-dicyanoepoxides with thioamides (Scheme 6) (8). 

PyraZolines. l,3-Diphenyl-2-pyia2olines (7) (Table 2) aie obtainable from appiopiiately substituted phenyUiydiazines by the Knoii reaction with either P-chloro- or P-dimethylaminopropiophenones (30,31). They are employed for brightening synthetic fibers such as polyamides, cellulose acetates, and polyacrylonitriles. 

An analogue of the transesterification process has also been demonstrated, in which the diacetate of BPA is transesterified with dimethyl carbonate, producing polycarbonate and methyl acetate (33). Removal of the methyl acetate from the equihbrium drives the reaction to completion. Methanol carbonylation, transesterification using phenol to diphenyl carbonate, and polymerization using BPA is commercially viable. The GE plant is the first to produce polycarbonate via a solventiess and phosgene-free process. 

The present preparation illustrates a general and convenient irethod for ring contraction of cyclic ketones. The first step is the usual procedure for the preparation of enamines. The second step involves 1,3-dipolar cycloaddition of diphenyl phosphorazidate to an enamine followed by ring contraction with evolution of nitrogen. Ethyl acetate and tetrahydrofuran can be used as a solvent in place of toluene. Pyrrolidine enamines from various cyclic ketones smoothly undergo the reaction under similar reaction conditions. Diphenyl (cycloalkyl-1-pyrrolidinylmethylene)phosphoramidates with 5,6,7, and 15 members in the ring have been prepared in yields of 68-76%. 

S,S -Dipropyl Acetals and Ketals RR C(SC3H7)2 S,S -Dibutyl Acetals and Ketals RR C(SC4H9)2 S,S -Dipentyl Acetals and Ketals RR C(SC5H i, )2 S,S -Diphenyl Acetals and Ketals RR C(SC6H )2 S,S -Dibenzyl Acetals and Ketals RR C(SCH2C6H5)2... 

The spectra and halochromism of thiophene analogs of triphenyl and diphenyl carbinol, " the spectra of anilides of 2- and 3-thenoyl-acetic acid, " and the fluorescence of some thiophene compounds have been investigated. 

The cyclization of 1,3,5-triketones to pyrones will not be discussed here, although this is a related reaction, because pyrones are not true pyrylium salts. Mention will be made, however, of the formation of 2,6-diphenyl-4-pyrone from 1,3-dibenzoylallene this ketone adds secondary amines leading to 3-dialkylamino-l,5-diphenyl-4-penten-l,5-diones, which arc cyclized by hydrogen chloride in acetic acid to 2,6-diphenyl-4-dialkylaminopyrylium chlorides (R = Me and/or Ph) (see Scheme. 5). 

Balaban, Mateescu, and Nenitzescu, diacylatcd 1,3-diphenyl-2-propanone (213, R =Ph) to 3,5-diphcnyl-4-pyrones (215), the former with acetic and polyphosphorio acids, the latter with acetyl chloride and aluminum chloride. This leaction follows the usual course of ketone acylation, and has been studied in detail several... 

Tlie smallest compounds among the azafulvalenes described to date are the azacalicenes, which are formed by combining a cyclopropenylidene moiety with a nitrogen-containing cyclopentadienylidene. Tlius, heating di-or triphenylpyrroles with diphenyl-methylsulfanyl-cyclopropenylium perchlorate in acetic acid gives the aza-triafulvalenium salts 33 and 34... 

Using different mono- and diketones in acetic acid (at room temperature) afforded the following products from benzophenone, 2,2-diphenyl-2//-imid-azo[4,5-/]quinoline from dibenzylketone, the 2-benzyl-imidazo[4,5-/]quino-line and from 2,4-pentanedione, 2-methyl-imidazo[4,5-/]quinoline. Cyclohexanone under reflux gave 2-n-pentyl-, whereas at room temperature it afforded the. s pira[cyclohexane-l,2 ]-(2//)-imidazo[4,5-/]quinoline 108 (R R =(CFl2)5) (86UC527). 

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