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Xylene-benzene-aluminum chloride system

Styrene. Styrene is the largest benzene derivative with annual consumption about 11.5 billion lb in the United States. It is produced mainly by catalytic dehydrogenation of high-purity ethylbenzene (EB) in the vapor phase. The manufacture process for EB is based on ethylene alkylation with excess benzene. This can be done in a homogeneous system with aluminum chloride catalyst or a heterogeneous solid acid catalyst in either gas or liquid-phase reaction. In the past decade, the liquid-phase alkylation with zeolite catalyst has won acceptance. Those processes have advantages of easier product separation, reducing waste stream, and less corrosion. In addition, it produces less xylene due to lower... [Pg.392]

Kinetic studies of acylation reactions are somewhat limited by the insolubility of the acyl halide-Lewis acid complexes in many of the solvent systems that are used. However, useful results have been obtained and, as far as we are concerned, relative rates of reactions are of greater importance than absolute values. In any case it is not possible to distinguish between the two mechanistic extremes on the basis of the observed kinetics." Friedel-Crafts acylations are generally characterized by high substrate selectivity and frequently by high positional selectivity. Relative rate data show, as expected, that toluene is more reactive than benzene and that /n-xylene is the most reactive of the dimethylbenzenes. Values, relative to benzene, for benzoylation catalyzed by aluminum chloride were r-butylbenzene (72), toluene (1.1 X 10 ), p-xylene (1.4 x 10 ), o-xylene (1.12 x 10 ), and m-xylene (3.94 x 10- ). Competition data for the trifluoroacetylation of a number of heterocycles using trifluoroacetic anhydride at 75 "C gave the relative rates thiophene (1.0), furan (1.4 x lO ), 2-methylfuran (1.2 x 10 ) and pyrrole (5.3 x 10 ). ... [Pg.735]


See other pages where Xylene-benzene-aluminum chloride system is mentioned: [Pg.48]    [Pg.100]    [Pg.760]    [Pg.735]    [Pg.760]    [Pg.760]   
See also in sourсe #XX -- [ Pg.286 ]




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Aluminum chloride

Benzene chloride

Benzene system

System xylene

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