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With chromium trioxide-pyridine complex

D. Oxidation with Chromium Trioxide-Pyridine Complex General Procedure... [Pg.5]

Oxidation, of primary alcohols to aldehydes, 52, 5 of terminal olefins with chromyl chloride, 51, 6 of 2,4,4-trimethyl-1-pentene with chromyl chloride, 51, 4 with chromium trioxide-pyridine complex, 52, 5... [Pg.62]

Conjugated acetylenic ketones can be prepared in about 40% yield by oxidation of alkynes with chromium trioxide-pyridine complex ... [Pg.96]

A - -Steroid. Dauben and Fullerton chose the following route for conversion of A -androstenc-.3)S,17 -diol diacetate (1) into A - -androstadiene-3, 17 -diol diacetatc (4). The starting material was converted into the 7-ketonc (2) by oxidation with chromium trioxide-pyridine complex in methylene chloride (2, 74 75). The ketone OAc... [Pg.304]

OXIDATION WITH CHROMIUM TRIOXIDE-PYRIDINE COMPLEX... [Pg.283]

OXIDATION WITH THE CHROMIUM TRIOXIDE-PYRIDINE COMPLEX PREPARED in situ ... [Pg.84]

CHROMIUM TRIOXIDE-PYRIDINE COMPLEX, preparation in situ, 55, 84 Chrysene, 58,15, 16 fzans-Cinnamaldehyde, 57, 85 Cinnamaldehyde dimethylacetal, 57, 84 Cinnamyl alcohol, 56,105 58, 9 2-Cinnamylthio-2-thiazoline, 56, 82 Citric acid, 58,43 Citronellal, 58, 107, 112 Cleavage of methyl ethers with iodotri-methylsilane, 59, 35 Cobalt(II) acetylacetonate, 57, 13 Conjugate addition of aryl aldehydes, 59, 53 Copper (I) bromide, 58, 52, 54, 56 59,123 COPPER CATALYZED ARYLATION OF /3-DlCARBONYL COMPOUNDS, 58, 52 Copper (I) chloride, 57, 34 Copper (II) chloride, 56, 10 Copper(I) iodide, 55, 105, 123, 124 Copper(I) oxide, 59, 206 Copper(ll) oxide, 56, 10 Copper salts of carboxylic acids, 59, 127 Copper(l) thiophenoxide, 55, 123 59, 210 Copper(l) trifluoromethanesulfonate, 59, 202... [Pg.114]

The above discussion has concentrated upon the reagents used, but it is equally of value to comment on the substrate, particularly in reactions for which other oxidation methods have been reported to fail. A good example is the oxidation of the iron-carbonyl complex (31) to the ketone (32 equation 14). The use of dimethyl sulfoxide activated with sulfur trioxide-pyridine complex gave a 70% yield of the product, in contrast to the use of the Pfitzner-Moffatt procedure (dimethyl sulfoxide-DCC) or the chromium... [Pg.299]

An attempted allylic oxidation of (68 equation 29) was found by Paquette to be difficult to achieve using a range of reagents due to problems with polymerization and rearrangement. The chromium trioxide-pyridine complex was the only reagent combination found to be successful, albeit in low yield. [Pg.102]

P. J. Garegg and B. Samuelsson, Oxidation of primary and secondary alcohols in partially protected sugars with the chromium trioxide-pyridine complex in the presence of acetic anhydride, Carbohydr. Res., 67 (1978) 267-270. [Pg.125]

Alternatively, treatment of the aporphine glaucine with a large excess of chromium trioxide-pyridine complex in dichloromethane led in a low yield to a mixture of dehydroglaucine, 1,2,9,10-tetramethoxy-oxoaporphine (6), corunnine (16), and pontevedrine (17) 51). [Pg.250]


See other pages where With chromium trioxide-pyridine complex is mentioned: [Pg.178]    [Pg.197]    [Pg.177]    [Pg.122]    [Pg.178]    [Pg.197]    [Pg.177]    [Pg.122]    [Pg.230]    [Pg.230]    [Pg.231]    [Pg.496]    [Pg.182]    [Pg.65]    [Pg.158]    [Pg.1065]    [Pg.201]    [Pg.177]    [Pg.5]    [Pg.124]    [Pg.124]    [Pg.257]    [Pg.387]    [Pg.21]    [Pg.22]    [Pg.314]    [Pg.533]    [Pg.90]   
See also in sourсe #XX -- [ Pg.5 , Pg.52 ]




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Chromium complex with

Chromium pyridine

Chromium trioxide

Chromium trioxide complex

Chromium trioxide-pyridine

Complexes pyridine

Complexes trioxide

Pyridine with

Pyridines complexation

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