Weeds, residues from control

Residues from Control of Submersed Weeds. Recommendations for use of herbicides to control submersed aquatic weeds usually specify treatment concentrations in terms of ppm. Granular formulations of herbicides such as 2,4-D, 2,6-dichlorobenzonitrile (dichlobenil), and 2,3,6-trichlorophenylacetic acid (fenac) are applied at pound-per-acre rates. The herbicides most commonly used to control submersed aquatic weeds are listed in Table I with normal rates of application. The initial residue levels represent the concentrations effective on submersed vegetation. For comparison, treatment rates given in pounds per acre are also shown as ppm in an arbitrarily selected water depth of 4 feet. 

Carbamates and substituted ureas are a numerous group of pesticides widely used to control weeds, pests, and diseases in fruit trees, vegetables, and cereals. Carbamate residues in foods are commonly extracted with water-miscible solvents and determined by using a liquid chromatograph equipped with a sensitive detector, frequently a UV detector. In addition, to obtain adequate detection selectivity, the postcolumn fluorimetric labeling technique is used for methyl carbamates. Substituted ureas are normally extracted from foods with organic solvents, and they can be determined directly by HPLC-UV or after postcolumn derivatization by fluorescence determination of their derivatives. 

The benefits of the triazines in multiple cropping systems range from their application flexibility, effective weed control, soil residual activity, and crop selectivity to their important role in resistance management and conservation tillage. The triazines also have made a major impact on agricultural sustainability and crop yields, as evidenced by the use of atrazine, especially in com. 

Research had confirmed that no parent simazine residues were found in treated com plants, and additional data on the dissipation pathway of simazine needed to be developed. Research also indicated that triazines interfered with the photosynthetic process on susceptible growing weeds, as evidenced by the appearance of chlorotic leaves. Steps were undertaken to elucidate simazine s dissipation pathway and herbicidal mode of action. In Basel, Dr. Gast (1958) showed that the accumulation of starch by common coleus (Coleus blumei Benth.) plants was inhibited from treatment with 2-chloro-4,6-bis-(alkyl-amino)-triazines due to the inhibition of sugar synthesis. At the same time, Moreland et al. (1958) found weed control activity could be reduced by supplying carbohydrates to the plants through their leaves and that simazine was a strong inhibitor of the Hill reaction in photosynthesis. Exer (1958) found that triazines inhibited the Hill reaction as strongly as urea of the CMU (monuron) type. 

During the late 1950s and early 1960s, most soil-applied herbicides typically did not receive mechanical incorporation, and when rain was insufficient, lacked reliability in controlling weeds. The reason for the slow adoption of mechanical incorporation techniques was probably three-fold (a) banded applications were preferred from a cost standpoint (b) the advantages of soil incorporation were not universally recognized and (c) the equipment and techniques for adequate incorporation were not available. Poor soil incorporation not only resulted in poor weed control, but in some cases resulted in crop injury. Simazine, in spite of its good weed control spectrum in corn, was never widely used in the Central Plains. Its lack of acceptance was attributed to its soil residual with the potential to injure... 

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