Harmonic wave

Fourier analysis The breaking down of a periodic function into its component cosine and sine waves (harmonics) with different amplitudes and frequencies. 

Up to now we have considered only harmonic generation by a plane wave. Harmonic generation by a focused laser beam was treated by Kleinman et al (1966), Ward and New (1969) and applied for THG in liquids and in air (environmental effects) by Meredith et al (1983b), Kajzar and Messier... 

Consider the reflection of a normally incident time-harmonic electromagnetic wave from an inhomogeneous layered medium of unknown refractive index n(x). The complex reflection coefficient r(k,x) satisfies the Riccati nonlinear differential equation [2] ... 

Marquardt R and Quack M 1989 Infrared-multlphoton excitation and wave packet motion of the harmonic and anharmonic oscillators exact solutions and quasiresonant approximation J. Chem. Phys. 90 6320-7... 

Boyd G T, Shen Y R and Hansch T W 1986 Continuous-wave second-harmonic generation as a surface microprobe Opt. Lett. 11 97-9... 

The vibrational part of the molecular wave function may be expanded in the basis consisting of products of the eigenfunctions of two 2D harmonic oscillators with the Hamiltonians ffj = 7 -I- 1 /2/coiPa atid 7/p = 7p - - 1 /2fcppp,... 

The coordinates of interest to us in the following discussion are Qx and Qy, which describe the distortion of the molecular triangle from Dy, symmetry. In the harmonic-oscillator approximation, the factor in the vibrational wave... 

These new wave functions are eigenfunctions of the z component of the angular momentum iij = —with eigenvalues = +2,0, —2 in units of h. Thus, Eqs. (D.l 1)-(D.13) represent states in which the vibrational angular momentum of the nuclei about the molecular axis has a definite value. When beating the vibrations as harmonic, there is no reason to prefer them to any other linear combinations that can be obtained from the original basis functions in... 

The problem is heated in elementary physical chemishy books (e.g., Atkins, 1998) and leads to a set of eigenvalues (energies) and eigenfunctions (wave functions) as depicted in Fig. 6-1. It is solved by much the same methods as the hamionic oscillator in Chapter 4, and the solutions are sine, cosine, and exponential solutions just as those of the harmonic oscillator are. This gives the wave function in Fig. 6-1 its sinusoidal fonn. 

The functions are known as the angular wave functions or, because they describe the distribution of p over the surface of a sphere of radius r, spherical harmonics. The quantum number n = l,2,3,...,oo and is the same as in the Bohr theory, is the azimuthal quantum number associated with the discrete orbital angular momentum values, and is... 

Figure 1.13 Plot of potential energy, V(r), against bond length, r, for the harmonic oscillator model for vibration is the equilibrium bond length. A few energy levels (for v = 0, 1, 2, 3 and 28) and the corresponding wave functions are shown A and B are the classical turning points on the wave function for w = 28...

Figure 1.13 shows the potential function, vibrational wave functions and energy levels for a harmonic oscillator. Just as for rotation it is convenient to use term values instead of energy levels. Vibrational term values G(v) invariably have dimensions of wavenumber, so we have, from Equation (1.69),... 

Just as the electrical behaviour of a real diatomic molecule is not accurately harmonic, neither is its mechanical behaviour. The potential function, vibrational energy levels and wave functions shown in Figure f.i3 were derived by assuming that vibrational motion obeys Hooke s law, as expressed by Equation (1.63), but this assumption is reasonable only... 

However, unlike electrical anharmonicity, mechanical anharmonicity modifies the vibrational term values and wave functions. The harmonic oscillator term values of Equation (6.3) are modified to a power series in (u + ) ... 

Owing to the effects of mechanical anharmonicity - to which we shall refer in future simply as anharmonicity since we encounter electrical anharmonicity much less frequently -the vibrational wave functions are also modified compared wifh fhose of a harmonic oscillator. Figure 6.6 shows some wave functions and probabilify densify functions (iA A ) for an anharmonic oscillator. The asymmefry in and (iA A ) 5 compared wifh fhe harmonic oscillator wave functions in Figure f.i3, increases fheir magnitude on the shallow side of the potential curve compared with the steep side. 

The remaining ISM allocations above 433.92 MHz are not harmonically related. This is unfortunate in terms of the problem of minimizing radio-frequency interference (REI), except for the harmonic relation in the millimeter wave range. 

In EIS, a potential is applied across a corroding metal in solution, causing current to flow The amount of current depends upon the corrosion reaction on the metal surface and the flow of ions in solution. If the potential is apphed as a sine wave, it will cause harmonics of the current output. The relationship between the apphed potential and current output is the impedance, which is analogous to resistance in a DC circiiit. 

The second component is caused by the different harmonic quantities present in the system when the supply voltage is non-linear or the load is nonlinear or both. This adds to the fundamental current, /,- and raises it to Since the active power component remains the same, it reduces the p.f of the system and raises the line losses. The factor /f/Zh is termed the distortion factor. In other words, it defines the purity of the sinusoidal wave shape. 

The basic principle of this relay is the sensing of the phase displacement between the fundamental waveforms of the voltage and current waves of a power circuit. Harmonic quantities are filtered out when present in the... 

The protection current produced by the usual full-wave rectifier has a 100-Hz alternating component of 48%. There are receivers with selective transmission filters for 100 Hz, which corresponds to the first harmonic of the cathodic protection currents [45]. With such a low-frequency test current, an inductive coupling with neighboring pipelines and cables is avoided, which leads to more exact defect location. 

Potential control rectifiers can also be constructed using thyristors. However, these produce strong high-frequency harmonic waves that can be transmitted to... 

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