Comets water

Figure 11.26 shows a component removed from an air-conditioning compressor. Pinhole perforations in this component had allowed cooling water to leak into the freon. Many failures of this type had occurred previously. Examinations of the internal surfaces of both the canister and the tubes entering it revealed evidence of metal loss. Tiny perforations at the bases of deep grooves were noted in the tubes. Deep, general, smooth metal loss surrounded irregular islands of intact surface (Fig. 11.27). The canister walls displayed a similar metal loss and comet-tail-shaped depressions (Fig. 11.2).

Water and carbon play critical roles in many of the Earth s chemical and physical cycles and yet their origin on the Earth is somewhat mysterious. Carbon and water could easily form solid compounds in the outer regions of the solar nebula, and accordingly the outer planets and many of their satellites contain abundant water and carbon. The type I carbonaceous chondrites, meteorites that presumably formed in the asteroid belt between the terrestrial and outer planets, contain up to 5% (m/m) carbon and up to 20% (m/m) water of hydration. Comets may contain up to 50% water ice and 25% carbon. The terrestrial planets are comparatively depleted in carbon and water by orders of magnitude. The concentration of water for the whole Earth is less that 0.1 wt% and carbon is less than 500 ppm. Actually, it is remarkable that the Earth contains any of these compounds at all. As an example of how depleted in carbon and water the Earth could have been, consider the moon, where indigenous carbon and water are undetectable. Looking at Fig. 2-4 it can be seen that no water- or carbon-bearing solids should have condensed by equilibrium processes at the temperatures and pressures that probably were typical in the zone of fhe solar... 

As evidenced by their low abundances, carbon compounds, water, and other volatiles such as nitrogen compounds were probably not significantly abundant constituents of the bulk of the solids that formed near the Earth. Many of the carriers of these volatiles condensed in cooler, more distant regions and were then scattered into the region where the Earth was forming. Eragments of comets and asteroids formed in the outer solar system still fall to Earth at a rate of 1 x 10 kg/yr and early in the... 

Aqueous chemistry is one of the oldest forces of change in the solar system. It started less than 20 million years after the gases of the solar nebula began to coalesce into solid objects.2 Water is also the most abundant volatile molecule in comets. On the earth, the oceans alone contain about 1.4 x 1021 kilograms or 320,000,000 cubic miles of water. Another 0.8 x 1021 kilogram is held within the rocks of the earth s crust, existing in the form of water of hydration. The human... 

Water can be found, in all three aggregate states, almost everywhere in the universe as ice in the liquid phase on the satellites of the outer solar system, including Saturn s rings and in the gaseous state in the atmospheres of Venus, Mars and Jupiter and in comets (as can be shown, for example, from the IR spectra of Halley s comet). The OH radical has been known for many years as the photodissociation product of water. 

The second important source for the hydrosphere and the oceans are asteroids and comets. Estimating the amount of water which was brought to Earth from outer space is not easy. Until 20 years ago, it was believed that the only source of water for the hydrosphere was gas emission from volcanoes. The amount of water involved was, however, unknown (Rubey, 1964). First estimates of the enormous magnitude of the bombardment to which the Earth and the other planets were subjected caused researchers to look more closely at the comets and asteroids. New hypotheses on the possible sources of water in the hydrosphere now exist the astronomer A. H. Delsemme from the University of Toledo, Ohio, considers it likely that the primeval Earth was formed from material in a dust cloud containing anhydrous silicate. If this is correct, all the water in today s oceans must be of exogenic origin (Delsemme, 1992). 

Fig. 2.7 The distribution of the ratio of the two hydrogen isotopes (D/H) in carbonaceous meteorites compared with that on Earth and in the comets. According to this distribution, most of the water on Earth must have had its origin in meteorites. From Robert (2001)...

The mass of Halley s Comet is about 1014kg, and thus its mean density is only 200 kg/m3. The rate of loss of material has been estimated as 5,000 kg/s. The nucleus is loosely packed and exhibits point craters and chasms from which gas and dust escape. These emissions consist mainly of water vapour (—80% by volume) as well as 6% CO, < 3% C02, -2.5% CH4, -1.2% NH3 and < 6% N2 (Flechtig and Keller, 1987). At the point where Giotto came nearest to the comet, the estimated amount of water being ejected was close to 15,000 kg/s, while that of dust particles was between 6,000 and 10,000 kg/s. Ions derived from water were detected in the... 

The interstellar dust was shown to contain quinone derivatives as well as oxygen-rich condensed aromatic compounds the quinones were present in both hydrated and carboxylated form. Very little nitrogen was present in the compounds detected. The cometary material, however, contained condensed nitrogen heterocycles. Hardly any oxygen was detected in the solid phase of the cometary dust it possibly evaporates from the tail of the comet in the form of water or oxidized carbon compounds. The authors assume that these analytical results could lead to a reconsideration of the current biogenesis models (Kissel et al 2004 Brownlee, 2004). 

However, the origin of the water on Mars is still unknown. Since the Earth and Mars have some common features in their history, the water on Mars could have come both from its interior and from comets and asteroids. The huge size of the Martian shield volcanoes, one class of which resembles the shield volcanoes Kilauea and Mauna Kea on Hawaii, suggests that a large proportion of the water was of volcanic origin. 

A new reservoir of comets may have formed at around 5 AU in a local orbit around Jupiter or at least perturbed by its gravitational attraction. A comet close to Jupiter would simply have been captured, delivering its chemical payload to the ever-increasing gas giant. Some comets would merely have been deflected towards the inner terrestrial planets, delivering a similar payload of water and processed molecules. Cometary impacts such as the spectacular collision of the comet Shoemaker-Levy 9 with Jupiter would have been common in the early formation phase of the solar system but with a much greater collision rate. Calculations of the expected collision rate between the Earth and potential small comets deflected from the snow line may have been sufficient to provide the Earth with its entire... 

Snow line The distance from the Sun at which water is stable on the surface of particles leading to comets. The presence of a large planetary mass such as Jupiter can then direct comets onto Earth, providing a source of cometary molecules to a prebiotic Earth... 

Giant molecular clouds collapse to form stars and solar systems, with planets and debris left over such as comets and meteorites. Are comets and meteorites the delivery vehicles that enable life to start on many planets and move between the planets as the solar system forms, providing water and molecules to seed life The planets have to be hospitable, however, and that seems to mean wet and... 

Throughout the book I have tried to constrain the wonders of imagination inspired by the subject by using simple calculations. Can all of the water on the Earth have been delivered by comets if so, how many comets How do I use molecular spectroscopy to work out what is happening in a giant molecular cloud Calculations form part of the big hard-sell for astrochemistry and they provide a powerful control against myth. I have aimed the book at second-year undergraduates who have had some exposure to quantum mechanics, kinetics, thermodynamics and mathematics but the book could easily be adapted as an introduction to all of these areas for a minor course in chemistry to stand alone. 

Occurrence. Carbon is distributed very widely in nature as calcium carbonate (limestone). Coal, petroleum and natural gas are chiefly hydrocarbons. Carbon is found as carbon dioxide in the atmosphere of the earth and dissolved in all natural waters. The atmosphere of Mars contains 96% C02. It is plentiful in the sun, stars, comets and the atmospheres of most planets. 

Biscardi, D., Monarca, S., De Fusco, R., Senatore, F., Poli, P., Buschini, A., Rossi, C. and Zani, C. (2003). Evaluation of the migration of mutagens/carcinogens from PET bottles into mineral water by 7>a<7eicawtw/micronuclei test. Comet assay on leukocytes and GC/MS, Sci. Total Environ., 302, 101-108. 

J In outer space, frozen water, or ice, has been found on the moon, on planets— particularly Mercury, Mars, Neptune, and Pluto—and in comets and clouds between stars in our galaxy. Recent explorations of Mars indicate that there may be liquid water underground on Mars.This means there could be microorganisms living there ... 

M. Venturi, R. J. Hambly, B. Glinghammar, J. J. Rafter and I. R. Rowland, Genotoxic activity in human faecal water and the role of bile acids a study using the alkaline comet assay. Carcinogenesis, 1997,18(12), 2353. 

Water is a unique substance that plays a major role in geochemistry and cosmochemistry and is a critical component of life. The physical properties of water control the environment on the Earth s surface and have played significant roles in the history of other planets, comets, and asteroids. Most plants and animals are about 60% water by volume, and most biological reactions involve water. It is no exaggeration to say that water is the key to our existence. 

Depending on conditions, frozen substances in comet nuclei can be crystalline ices, amorphous ices, and clathrate hydrates (compounds in which cages in the water-ice lattice can host guest molecules). Compositions of the ices and associated organic materials in comets have been determined from both telescopic and spacecraft observations. Spectral line measurements of gases in a comet s coma allow the identification of molecules and radicals. An inherent difficulty in spectral measurements is that volatiles in the coma are commonly broken... 

Table 12.1 Chemistry of comet Hale-Bopp, based on production rates of molecules, relative to water...

Oxygen isotopic compositions (relative to standard mean ocean water, SMOW) of several mineral grains in three Stardust particles, each grain denoted by a separate symbol. Open circles are from a CAI comet particle. After McKeegan et al. (2006). 

Compositional variations among comets, based on the production rates ("Q") of carbon-chain (C2 and C3) and NH molecules relative to water (OH). Filled symbols are Kuiper belt comets, and open symbols are Oort cloud comets. After A Hearn etal. (1995). 

Gravitational stirring of icy planetesimals by the giant planets could have sent many comets careening into the inner solar system, providing a mechanism for late addition of water to the terrestrial planets. Comets impacting the Earth and the other terrestrial planets would have delivered water as ice (Owen and Bar-Nun, 1995 Delsemme, 1999), whereas the accretion of already altered carbonaceous chondrite asteroids would have delivered water in the form of hydroxl-bearing minerals (Morbidelli el al., 2000 Dauphas et al., 2000). 

Noble gases may provide a constraint on the source of water and other volatiles. The abundance pattern of noble gases in planetary atmospheres resembles that of chondrites, perhaps arguing against comets. However, there are some differences, especially in the abundance of xenon. Relative to solar system abundances, krypton is more depleted than xenon in chondrites, but in the planets, krypton and xenon are present in essentially solar relative abundances (Fig. 10.11). This observation has been used to support comets as the preferred source of volatiles (even though measurements of xenon and krypton in comets are lacking). A counter-argument is that the Ar/H20 ratio in comets (if the few available measurements are accurate and representative) limits the cometary addition of volatiles to the Earth to only about 1%. 

It is also possible that neither of these mechanisms for providing water to the inner planets is correct. Another hypothesis is that absorption of water onto dust particles in the accretion disk might account for the Earth s oceans (Drake, 2005). As already mentioned, the amount of water required to explain Earth s water is not large on a per-gram basis. Regardless of whether comets, asteroids, or nebular particles were the source of our planet s oceans, the water likely came from more distant regions of the nebular disk. 

Ice Solidified gases h2o For future dating of comet, satellite Europa Antarctic ice, snow, frost Frozen rain and river water Environment study... 

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