Uranium-thorium series isotopes radium

Tracers serve as a dye with which to follow the circulation of ocean waters. There are conventional ocean tracers such as temperature, salinity, oxygen, and nutrients. There are stable isotope tracers such as oxygen-18, carbon-13, and there are radioactive tracers both naturally occurring (such as the uranium/thorium series, and radium), and those produced both naturally and by the bomb tests (such as tritium and carbon-14). The bomb contributions from the latter two are called transient tracers, as are the CFCs, because they have been in the atmosphere for a short time. This implies an anthropogenic source and a nonsteady input function. 

In this chapter we discuss improvements documented in the literature over the past decade in these areas and others. Chemical procedures, decay-counting spectroscopy, and mass spectrometric techniques published prior to 1992 were previously discussed by Lally (1992), Ivanovich and Murray (1992), and Chen et al. (1992). Because ICPMS methods were not discussed in preceding reviews and have become more commonly used in the past decade, we also include some theoretical discussion of ICPMS techniques and their variants. We also primarily focus our discussion of analytical developments on the longer-lived isotopes of uranium, thorium, protactinium, and radium in the uranium and thorium decay series, as these have been more widely applied in geochemistry and geochronology. 

Cochran JK, Masque P (2003) Short-lived U/Th-series radionuclides in the ocean tracers for scavenging rates, export fluxes and particle dynamics. Rev Mineral Geochem 52 461-492 Cohen AS, O Nions RK (1991) Precise determination of femtogram quantities of radium by thermal ionization mass spectrometry. Anal Chem 63 2705-2708 Cohen AS, Belshaw NS, O Nions RK (1992) High precision uranium, thorium, and radium isotope ratio measurements by high dynamic range thermal ionization mass spectrometry. Inti J Mass Spectrom Ion Processes 116 71-81... 

The main source of terrestrial radiation is long-living isotopes of the uranium-radium series the thorium series ( Th) and the actinium series... 

Radon-222 is a direct decay product of radium-226, which is part of the decay series that begins with uranium-238 (see Chapter 3, Figure 3-1). Thorium-230 and thorium-234 are also part of this decay series. Uranium, thorium, and radium are the subjectof other ATSDR Toxicological Profiles. Other isotopes of radon, such as radon-219 and radon-220, are formed in other radioactive decay series. Flowever, radon-219 usually is not considered in the evaluation of radon-induced health effects because it is not abundant in the environment (Radon-219 is part of the decay chain of uranium-235, a relatively rare isotope) and has an extremely short half-life (4 seconds). Radon-220 is also usually not considered when evaluating radon-related health effects. While the average rate of production of radon-220 is about the same as radon-222, the amount of radon-220 entering the environment is much less than that of radon-222 because of the short half-life of radon-220 (56 seconds). All discussions of radon in the text refer to radon-222. 

Subsequently, a wide array of developments in TIMS methods for uranium-series measurement occurred during the past decade including initiation of methods for measurement of long-lived radium (Volpe et al. 1991 Cohen and O Nions 1991) and protactinium isotopes (Pickett et al. 1994 Bourdon et al. 1999), development of improved sources or ionization methods for TIMS analysis, and introduction of commercially available multi-collector TIMS instruments designed specifically for uranium and thorium isotopic measurement. 

Various radium isotopes are derived through a series of radioactive decay processes. For example, Ra-223 is derived from the decay of actinium. Ra-228 and Ra-224 are the result of the series of thorium decays, and Ra-226 is a result of the decay of the uranium series. 

Uranium-238 emits an alpha particle to become an isotope of thorium. This unstable element emits a beta particle to become the element now known as Protactinium (Pa), which then emits another beta particle to become an isotope of uranium. This chain proceeds through another isotope of thorium, through radium, radon, polonium, bismuth, thallium and lead. The final product is lead-206. The series that starts with thorium-232 ends with lead-208. Soddy was able to isolate the different lead isotopes in high enough purity to demonstrate using chemical techniques that the atomic weights of two samples of lead with identical chemical and spectroscopic properties had different atomic weights. The final picture of these elements reveals that there are several isotopes for each of them. 

I he atomic wcighi varies because of natural variations in the isotopic composition of the element, caused by the various isotopes having different origins - I h is the end product of the thorium decay scries, while Ph and " Pb arise Irom uranium as end products of the actinium and radium series respectively. Lead-204 has no existing natural radioactive precursors. Electronic configuration l.v 2s lfc22/j"3v 3//,3i/l"4v- 4/, 4l/" 4/ IJ5v- 5/ "5t/l"bv />-. Ionic radius Pb I.IX A. Pb 1 0.7(1 A. Metallic radius 1.7502 A. Covalent radius (ip i 1.44 A. First ionization potential 7.415 cV second. 14.17 eV. Oxidation... 

Table 3-2 lists important physical properties of radium and selected radium compounds. Radioactive properties of the four naturally-occurring radium isotopes are listed in Table 3-3. In addition to the naturally occurring isotopes, there are 12 other known isotopes of radium. The principal decay schemes of the uranium and thorium decay series that produce the naturally-occurring radium isotopes are presented in Figure 3-1.

FIGURE 3-1. Uranium and Thorium Isotope Decay Series Showing the Sources and Decay Products of the Four Naturally-Occurring Radium Isotopes... 

Whether in the environment or in the human body, uranium will undergo radioactive decay to form a series of radioactive nuclides that end in a stable isotope of lead (see Chapter 3). Examples of these include radioactive isotopes of the elements thorium, radium, radon, polonium, and lead. Analytical methods with the required sensitivity and accuracy are also available for quantification of these elements in the environment where large sample are normally available (EPA 1980,1984), but not necessarily for the levels from the decay of uranium in the body. More sensitive analytical methods are needed for accurately measuring very low levels of these radionuclides. 

The great variety of radionuclides present in thorium and uranium ores are listed in Tables 4.1, 4.2 and 4.3. Whereas thorium has only one isotope with a very long half-life (- Th), uranium has two and giving ri.se to one decay scries for Th and two for U. In order to distinguish the two decay series of U, they were named after long-lived members of practical importance the uranium-radium series and the actinium series. The uranium-radium series includes the most important radium isotope ( Ra) and the actinium scries the most important actinium isotope ( Ac),... 

Radium is element number 88, in which all of its isotopes are radioactive hence, what little radium is found on Earth is mostly as a trace element in uranium ores. The most common isotope has a mass number of 226 with a half-life of 1,604 years. The second longest-lived isotope is radium 228, with a half-life of 5.77 years. The other isotopes have much shorter half-lives ranging from microseconds to days. Radium is constantly being formed as part of the radioactive decay series of uranium and thorium. Because it decays so quickly, however, only minute quantities of radium ever exist at any one time. 

When an element has more than one radioisotope, determinations and data analysis are generally more complex because the isotopes may differ in half-life, especially when a series is involved, e.g., radium, thorium, polonium, radon, actinium, protactinium, and uranium. One possibility is to make measurements after the decay of the short-lived radionuclides, but this may require long waiting times. In favorable cases, it is more convenient to measure the activity of decay products (e.g., radon, thoron ( Rn), actinon ( Rn)), or correct the measurements of the short-lived radioisotopes after determination of the isotopic composition. 

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