Trimethylpentanes

To illustrate, predictions were first made for a ternary system of type II, using binary data only. Figure 14 compares calculated and experimental phase behavior for the system 2,2,4-trimethylpentane-furfural-cyclohexane. UNIQUAC parameters are given in Table 4. As expected for a type II system, agreement is good. 

Type C requires the most complex data analysis. To illustrate, we have reduced the data of Henty (1964) for the system furfural-benzene-cyclohexane-2,2,4-trimethylpentane. VLB data were used in conjunction with one ternary tie line for each ternary to determine optimum binary parameters for each of the two type-I ternaries cyclohexane-furfural-benzene and 2,2,4-... 

Calculated and Experimental Liquid-Liquid Equilibria for a Quarternary System at 25 C 2,2,4-trimethylpentane(1)-furfural(2)-cyclohexane(3)-benzene(4)... 

The motor fuel under test is compared to two pure hydrocarbons chosen as references. The first is 2, 2, 4-trimethylpentane or isooctane which is very resistant to auto-ignition and to which is arbitrarily given the number 100 /... 

Fig. Ill-16. Surface tension lowering of water at 15°C due to adsorption of hydrocarbons. , n-pentane A, 2,2,4-trimethylpentane O, n-hexane x, n-heptane A, n-octane. (From Ref. 133.)...

Using these group values, predict isooctane (2,2,3-trimethylpentane) and... 

Photochemical chlorination of 2 2 4 trimethylpentane gives four isomenc monochlorides... 

The two dimers of 2 methylpropene shown in the equation can be converted to 2 2 4 trimethylpentane (known by its common name isooctane) for use as a gasoline additive Can you suggest a method for this conversion ... 

Octane rating (Section 2 16) The capacity of a sample of gasoline to resist knocking expressed as a number equal to the percentage of 2 2 4 trimethylpentane ( isooctane ) in an isooctane-heptane mixture that has the same knocking characteristics... 

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