Transition metal nanoparticles self-assembly

It should be mentioned here that Finke s group has added a whole plethora of significant contributions to the field of metal nanoclusters [295-299] including a recent study on the mechanism for the self-assembly of transition metal nanoparticles [294]. 

Self-assembly of transition metal nanoparticles using marine sources ... 

For transition and precious metals, thiols have been successfully employed as the stabilizing reagent (capping reagent) of metal nanoparticles [6]. In such cases, various functionalities can be added to the particles and the obtained nanoparticles may be very unique. It is well known that thiols provide good self-assembled monolayers (SAM) on various metal surfaces. When this SAM technique is applied to the nanoparticle preparation, nanoparticles can be covered constantly by functionalized moieties, which are connected to the terminal of thiol compounds. 

Biomimetic Synthesis of Nanoparticles Carbonyl Complexes of the Transition Metals Metallic Materials Deposition Metal-organic Precursors Polynuclear Organometallic Cluster Complexes Porous Inorganic Materials Self-assembled Inorganic Architectures Semiconductor Nanocrystal Quantum Dots Sol-Gel Encapsulation of Metal and Semiconductor Nanocrystals. 

Beverly et al. [93] studied the temperature-dependent DC transport measurements on monolayers of self-assembled dodecanethiol-coated 7 nm silver nanoparticles as a function of particle size distribution-induced disorder. The superlattices disorder was adjusted by a stepwise variation of the particle size distribution. In the electrical transport measurements, six different monolayers of 7 nm silver nanoparticles, in which the size distribution was varied from 6.6% to 13.8%, were investigated at 300-10 K. Above 200 K, all films exhibited metallic conductivity, and below 200 K activated transport. However, between 30 and 100 K a second transition (Tcross) was observed that was based on the crossover from the simply activated transport to a... 

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