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Total analysis system mass transport

Transient techniques including an EPS voltammetry are often more sensitive than the steady-state measurements. To extend the scale of information on the system, an analysis of EPS voltammetric maxima is desirable. Unfortunately, analytical expressions for EPS voltammograms are not available for circumstances discussed in Chapter 4. Nevertheless, it is of interest to use for this purpose some relationships derived for simple redox systems replacing the concentration of the oxidant by the total concentration of metal. Certain grounds for such operation follow from the regularities of mass transport of labile complexes (Section 3.2). [Pg.142]


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See also in sourсe #XX -- [ Pg.61 , Pg.63 ]




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