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Thiols chlorides

Of the crystalline derivatives of thiols, those formed with 3 5-dinitro-benzoyl chloride are not very satisfactory since they have, in general lower melting points than those of the corresponding alcohols (compare Section 111,27,7) and do not diflfer widely from ethyl to n-heptyl. The best results are obtained with 2 4-dinitrochlorobenzene. [Pg.500]

Ethylene oxide Acids and bases, alcohols, air, 1,3-nitroaniline, aluminum chloride, aluminum oxide, ammonia, copper, iron chlorides and oxides, magnesium perchlorate, mercaptans, potassium, tin chlorides, alkane thiols... [Pg.1208]

Tetrachloropyridine-4-thiol [10357-06-1] (41) reacts with chlorine in carbon tetrachloride to give a sulfenyl chloride (42), which is fairly stable. The sulfenyl chloride may be converted into a number of derivatives (39). [Pg.329]

General Reaction Chemistry of Sulfonic Acids. Sulfonic acids may be used to produce sulfonic acid esters, which are derived from epoxides, olefins, alkynes, aHenes, and ketenes, as shown in Figure 1 (10). Sulfonic acids may be converted to sulfonamides via reaction with an amine in the presence of phosphoms oxychloride [10025-87-3] POCl (H)- Because sulfonic acids are generally not converted directiy to sulfonamides, the reaction most likely involves a sulfonyl chloride intermediate. Phosphoms pentachlotide [10026-13-8] and phosphoms pentabromide [7789-69-7] can be used to convert sulfonic acids to the corresponding sulfonyl haUdes (12,13). The conversion may also be accompHshed by continuous electrolysis of thiols or disulfides in the presence of aqueous HCl [7647-01-0] (14) or by direct sulfonation with chlorosulfuric acid. Sulfonyl fluorides are typically prepared by direct sulfonation with fluorosulfutic acid [7789-21-17, or by reaction of the sulfonic acid or sulfonate with fluorosulfutic acid. Halogenation of sulfonic acids, which avoids production of a sulfonyl haUde, can be achieved under oxidative halogenation conditions (15). [Pg.95]

Vinyl chloride reacts with sulfides, thiols, alcohols, and oximes in basic media. Reaction with hydrated sodium sulfide [1313-82-2] in a mixture of dimethyl sulfoxide [67-68-5] (DMSO) and potassium hydroxide [1310-58-3], KOH, yields divinyl sulfide [627-51-0] and sulfur-containing heterocycles (27). Various vinyl sulfides can be obtained by reacting vinyl chloride with thiols in the presence of base (28). Vinyl ethers are produced in similar fashion, from the reaction of vinyl chloride with alcohols in the presence of a strong base (29,30). A variety of pyrroles and indoles have also been prepared by reacting vinyl chloride with different ketoximes or oximes in a mixture of DMSO and KOH (31). [Pg.414]

Thiol esters are obtained in 91% yield by the addition of aioyl chloride to a slurry of an alkaline salt xanthate in acetone without cooling (54) ... [Pg.364]

Aliphatic Alcohols and Thiols. Ahphatic alcohols on reaction with chloroformates give carbonates and hydrogen chloride. Frequendy, the reaction proceeds at room temperature without a catalyst or hydrogen chloride acceptor. However, faster reactions and better yields are obtained in the presence of alkaU metals or their hydroxides, or tertiary amines. Reactions of chloroformates with thiols yield monothiolocarbonates (14). [Pg.38]

Pyrimidine-2-sulfonyl chloride, 4,6-dimethyl-reactions, 3, 97 Pyrimidinesulfonyl halides reactions, 3, 97 Pyrimidinethiols S-acylation, 3, 95 S-alkylation, 3, 94 oxidation, 3, 94 synthesis, 3, 135 Pyrimidine-5-thiols oxidation, 3, 94 synthesis, 3, 136... [Pg.808]

Non-Bonding (NB) Paraffins Nonactive H chlorides Nonactive H fluorides Sulfides Nonactive H iodides Disulfides Nonactive H bromides Thiols... [Pg.1318]

The dibenzosuberyl ether is prepared from an alcohol and the suberyl chloride in the presence of triethylamine (CH2CI2, 20°, 3 h, 75% yield). It is cleaved by acidic hydrolysis (1 N HCl/dioxane, 20°, 6 h, 80% yield). This group has also been used to protect amines, thiols, and carboxylic acids. The alcohol derivative can be cleaved in the presence of a dibenzosuberylamine. ... [Pg.60]

Triphenylmethyl thioethers have been formed by reaction of the thiol with tri-phenylmethyl alcohol/anhydrous CF3COOH (85-90% yield) or with triphenyl-methyl chloride (75% yield). [Pg.287]

NO2C6H4SCI NaBH4- Treatment of the thioether with the sulfenyl chloride initially produces a disulfide which is then reduced to afford the free thiol. [Pg.289]

These sulfides are prepared from other sulfur protective groups by reaction with the sulfenyl chloride. The Npys group can also be introduced directly by treatment of the thiol with NpysCl. ... [Pg.304]

Alkyldithio carbamates are prepared from the acid chloride (Et N, EtOAc, 0°) and amino acid, either free or as the O-silyl derivatives (70-88% yield). The N- i-propyldithio) carbamate has been used in the protection of proline during peptide synthesis. Alkyldithio carbamates can be cleaved with thiols, NaOH, Ph P/TsOH. They are stable to acid. Cleavage rates are a function of the size of the alkyl group as illustrated in the table below. [Pg.334]

The utility of methanesulfinyl chloride lies in its great chemical reactivity. Through its ready hydrolysis, it serves as a convenient source of methanesulfinic acid. It reacts at low temperature with aromatic amines to form sulfinamides, and with alcohols to form sulfinate esters. When it is hydrolyzed in the presence of an equimolar quantity of sulfenyl chloride, a thiol-sulfonate ester is produced. [Pg.65]

Thioketals are readily prepared by reaction of saturated 3-ketones with thiols or dithiols in the presence of boron trifluoride or hydrogen chloride catalysts. Selective protection of the 3-ketone in the presence of a 6-ketone is possible by carrying out the reaction in diluted medium. Similarly, 3-ketones react selectively with monothiols " " or with bulky dithiols in the presence of 6-, 7-, 11- and 12-ketones. [Pg.389]

The free-radical chemistry of fluoroalkanesulfenyl chlorides with hydrocarbons was also investigated [S, 9], Depending upon the structures of the sulfenyl chloride and the hydrocarbon, these reactions yield as major products up to three of the following four types of organic compounds thiols, disulfides, sulfides, and chlorohydrocarbons (equation 6), Perfluoroisobutanesulfenyl chloride is unique m that the only major products detected are the thiol and chlorohydrocarbon [ ] (equation 6) (Table 3). [Pg.555]


See other pages where Thiols chlorides is mentioned: [Pg.134]    [Pg.273]    [Pg.134]    [Pg.273]    [Pg.254]    [Pg.318]    [Pg.126]    [Pg.109]    [Pg.169]    [Pg.69]    [Pg.551]    [Pg.381]    [Pg.70]    [Pg.108]    [Pg.542]    [Pg.1]    [Pg.414]    [Pg.25]    [Pg.137]    [Pg.88]    [Pg.157]    [Pg.162]    [Pg.170]    [Pg.218]    [Pg.72]    [Pg.279]    [Pg.366]    [Pg.626]    [Pg.1069]   
See also in sourсe #XX -- [ Pg.462 , Pg.658 ]




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Chlorides, from thiols

Methanesulfonyl chloride, trichloroalkane chlorination thiols

Olefins and Functional Derivatives in the Presence of Carboxylic Acids, Thiols, Amines or Hydrogen Chloride

Sulfenyl chlorides from thiols

Sulfonyl chlorides thiols

Thiols Thionyl chloride

Thiols to sulfonyl chlorides

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