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Thermodynamics and transition state

Kinetic treatment based on the theory of complex reactions introduced the necessity to calculate quite many parameters (pre-exponential factors, activation energies of elementary reactions, etc.). Therefore a need to estimate independently the rates and surface coverage called for the application of theoretical approaches, based on thermodynamics and transition state theory, as well as other tools (ultra-high vacuum studies, spectroscopy) to get necessary data and reduce the number of parameters in statistical data fitting. [Pg.107]

Here the thermodynamics still favor stepwise reaction by way of pentacoordinate intermediate, 25, but the preference is weaker than in the triester case above. A concerted path might be barely possible here but would be expected to be close in structure and transition state energy to the pentacoordinate intermediate. [Pg.37]

While the collision theory of reactions is intuitive, and the calculation of encounter rates is relatively straightforward, the calculation of the cross-sections, especially the steric requirements, from such a dynamic model is difficult. A very different and less detailed approach was begun in the 1930s that sidesteps some of the difficulties. Variously known as absolute rate theory, activated complex theory, and transition state theory (TST), this class of model ignores the rates at which molecules encounter each other, and instead lets thermodynamic/statistical considerations predict how many combinations of reactants are in the transition-state configuration under reaction conditions. [Pg.139]

At temperatures above 450°C ZSM-5 is a very effective catalyst for the disproportionation of toluene. A process has been developed and put into commercial practice (2). The thermodynamic equilibrium composition (11) is listed in Figure 7. The product obtained with ZSM-5 contains less of the highly substituted aromatics, as a result of diffusion and transition-state inhibition, such that the process can be approximated by the equation ... [Pg.282]

We have not carried out calculations starting with secondary cations derived from the title alkanes because at a computational level, these will have ground-states and transition-states similar to heptane itself (previously discussed). This will be true even though the most stable carbocations in these branched alkanes will be the corresponding tertiary ions, which in themselves will not be directly involved in dehydrocyclization processes. However, one has to keep in mind that the thermodynamic ground-states in these real catalytic reactions will be the alkanes themselves, and in this regard secondary cations formed from n-octane or 2- (or 3-) methylheptane will not differ much in absolute energy. As shown earlier, a 1,6-closure of 2-methylheptane leads eventually to m-xylene, while 3-methylheptane has eventual routes to both o- and p-xylene. [Pg.305]

UNI MOLECULAR REACTIONS AND TRANSITION STATE THEORY TRANSITION-STATE THEORY (Thermodynamics)... [Pg.785]

The measurement of exchange rates is important, since it gives us vital information on the transition state between reagents and products. Absolute rate theory states that the rate is given by eq. (1), in which k, h and R are Boltzmann s, Planck s and the gas constants, and T is the absolute temperature. The transmission coefficient, k, is usually taken as 1. The thermodynamic functions AG, AH and AS represent the change between the initial and transition states. [Pg.229]

Chapter 1 introduces Potential Energy Surfaces as the connection between structure and energetics, and shows how molecular equilibrium and transition-state geometry as well as thermodynamic and kinetic information follow from interpretation of potential energy surfaces. Following this, the guide is divided into four sections ... [Pg.804]

In the case of a simple elementary en2yme reaction, fce is identical to kcat. By utilizing the thermodynamic cycle the quotient of the constants of formation of the transition state K /Ku can be equated with the quotient of the dissociation constants for substrate Ks and transition state Kr [Eq. (2.7)]. [Pg.25]

If the reaction is considered on the molar scale, the activated complexes are the molecular species at the hypothetical free energy maximum which separates reactant and product molecules. The distinction between an activated complex (transition structure), which is a real molecular species, though of exceedingly short lifetime, and transition state, which is a hypothetical thermodynamic state on the molar scale, is important though frequently confused [7]. [Pg.50]

Chemical reactivity is influenced by solvation in different ways. As noted before, the solvent modulates the intrinsic characteristics of the reactants, which are related to polarization of its charge distribution. In addition, the interaction between solute and solvent molecules gives rise to a differential stabilization of reactants, products and transition states. The interaction of solvent molecules can affect both the equilibrium and kinetics of a chemical reaction, especially when there are large differences in the polarities of the reactants, transition state, or products. Classical examples that illustrate this solvent effect are the SN2 reaction, in which water molecules induce large changes in the kinetic and thermodynamic characteristics of the reaction, and the nucleophilic attack of an R-CT group on a carbonyl centre, which is very exothermic and occurs without an activation barrier in the gas phase but is clearly endothermic with a notable activation barrier in aqueous solution [76-79]. [Pg.329]

Polanyi s scientific work lay most squarely within a physical chemistry that encompassed thermodynamics, X-ray crystallography, the study of reaction rates, and the application of quantum mechanics to the study of molecular forces and transition states. In two particular areas, the investigation of solid-surface adsorption phenomena and X-ray diffraction studies of the properties of solids, Polanyi helped establish new scientific specialities, at the boundaries of physics and chemistry, for studying the solid state. He also turned his research experiences in these fields into a basis for the formulation of a new philosophy of science centered on scientific practice, rather than scientific ideas. [1] It is these themes that I would like to explore, with remarks in my conclusion on Polanyi s influence in solid-state science. [Pg.246]


See other pages where Thermodynamics and transition state is mentioned: [Pg.828]    [Pg.828]    [Pg.240]    [Pg.396]    [Pg.107]    [Pg.828]    [Pg.828]    [Pg.240]    [Pg.396]    [Pg.107]    [Pg.390]    [Pg.211]    [Pg.396]    [Pg.186]    [Pg.186]    [Pg.103]    [Pg.514]    [Pg.81]    [Pg.545]    [Pg.352]    [Pg.148]    [Pg.43]    [Pg.118]    [Pg.330]    [Pg.685]    [Pg.131]    [Pg.11]    [Pg.942]    [Pg.507]    [Pg.225]    [Pg.101]    [Pg.101]    [Pg.82]    [Pg.36]    [Pg.24]    [Pg.348]    [Pg.230]    [Pg.323]    [Pg.326]    [Pg.17]    [Pg.239]    [Pg.247]   
See also in sourсe #XX -- [ Pg.304 , Pg.307 ]




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