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Benzene thermodynamic stability

The orbital phase theory can be applied to the thermodynamic stability of the disubstituted benzene isomers. The cyclic orbital interaction in the benzene substituted with two EDGs is shown in Scheme 21. The orbital phase is continuous in the meta isomer and discontinuous in the ortho and para isomers (Scheme 22, cf. Scheme 4). [Pg.103]

The stabilization of iminoboranes can yield five different tj ies of products cyclodimers (1,3,2,4-diazadiboretidines, Di), cyclotrimers (borazines, Tr), bicyclotrimers (Dewar borazines, Tr ), cyclotetramers (octahydro-l,3,5,7-tetraza-2,4,6,8-tetraborocines, Te), and polymers (polyiminoboranes, Po) these substances are isoelectronic with cyclobutadienes, benzenes, Dewar benzenes, cyclooctatetraenes, and polyalkynes, respectively, which are all known to be products of the thermodynamic stabilization of alkynes. [Pg.141]

Aromatic compounds have a special place in ground-state chemistry because of their enhanced thermodynamic stability, which is associated with the presence of a closed she of (4n + 2) pi-electrons. The thermal chemistry of benzene and related compounds is dominated by substitution reactions, especially electrophilic substitutions, in which the aromatic system is preserved in the overall process. In the photochemistry of aromatic compounds such thermodynamic factors are of secondary importance the electronically excited state is sufficiently energetic, and sufficiently different in electron distribution and electron donor-acceptor properties, ior pathways to be accessible that lead to products which are not characteristic of ground-state processes. Often these products are thermodynamically unstable (though kinetically stable) with respect to the substrates from which they are formed, or they represent an orientational preference different from the one that predominates thermally. [Pg.77]

TABLE 2. Calculated substituent effects on the thermodynamic stability, AE (in kcalmol-1), of (pso-substituted silabenzenes and of substituted benzenes (HF/3-21G)"... [Pg.15]

Using the appropriate bond-separation reactions, the UF/3-21G aromatic stabilization energies are calculated to be 47.2, 36.4 and 22.5 kcal mol-1 for 22,11 and 21, respectively, compared to 59.0 kcal mol-1 for benzene503 thus the meta-, para- and ortho-isomers have 80, 62 and 38% of the aromaticity of benzene. The different orders of the thermodynamic stability of the three isomeric disilabenzene and of their aromatic stabilization energies... [Pg.18]

Tritylation of some compounds of low thermal stability increases neither the kinetic nor thermodynamic stability, measured decomposition enthalpies per gram remaining high. Possibly the energy theoretically represented by the three benzene rings in the trityl group makes itself apparent. [Pg.2611]

The authors suggested244 that proton loss [Eq. (185)] is controlled by stereo-electronic considerations and not by the thermodynamic stability of the product. In the preferred conformation, the tertiary hydrogen on the isopropyl group of the p-cymene radical cation is located in the nodal plane of the benzene ring where its interaction with the n system in the transition state is minimized. The methyl group, on the other hand, rotates rather freely, and the loss of any one of the hydrogens is, therefore, not conformationally restricted. [Pg.313]

On the basis of solubilities in benzene, Horn and Honigman (1974) estimated the relative thermodynamic stability of the five most commonly recognized polymorphs Sisa = y<8enthalpy difference between the two commercially most significant a and forms as 10.75 kJmoP which is consistent with the results of the solvent-mediated a ft... [Pg.267]

Another system for which thermodynamic data have been obtained in some detail is the Tp Rh(CNneopentyl)(R)H system studied by Jones. Here, the relative thermodynamic stabilities of a number of adducts were obtained by measuring both the competitive kinetic selectivity for two types of C-H bond (AAGt in Fig. 2) as well as the barrier for reductive elimination of free alkane from each adduct (AG and AG in Fig. 2). The free energies for the latter were obtained from kinetic studies of the reductive elimination of hydrocarbon in benzene. A summary of the AG° values, calculated equilibrium constants, and relative metal-carbon bond strengths are given in Table 4 [26]. For DC H for benzene, see ref. [Pg.17]


See other pages where Benzene thermodynamic stability is mentioned: [Pg.516]    [Pg.731]    [Pg.625]    [Pg.62]    [Pg.15]    [Pg.9]    [Pg.425]    [Pg.74]    [Pg.37]    [Pg.7]    [Pg.15]    [Pg.37]    [Pg.222]    [Pg.562]    [Pg.225]    [Pg.629]    [Pg.4]    [Pg.20]    [Pg.54]    [Pg.351]    [Pg.71]    [Pg.33]    [Pg.142]    [Pg.590]    [Pg.177]    [Pg.103]    [Pg.18]    [Pg.3569]    [Pg.47]    [Pg.37]    [Pg.629]    [Pg.369]    [Pg.743]    [Pg.1096]    [Pg.37]    [Pg.130]    [Pg.31]   
See also in sourсe #XX -- [ Pg.15 ]

See also in sourсe #XX -- [ Pg.15 ]

See also in sourсe #XX -- [ Pg.15 ]

See also in sourсe #XX -- [ Pg.15 ]




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