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The third model

Fig. 1.—The arrangement of 45 spheres in icosahedral closest packing. At the left there is shown a single sphere, which constitutes the inner core. Next there is shown the layer of 12 spheres, at the corners of a regular icosahedron. The third model shows the core of 13 spheres with 20 added in the outer layer, each in a triangular pocket corresponding to a face of the icosahedron these 20 spheres lie at the corners of a pentagonal dodecahedron. The third layer is completed, as shown in the model at the right, by adding 12 spheres at corners of a large icosahedron the 32 spheres of the third layer lie at the corners of a rhombic triaconta-hedron. The fourth layer (not shown) contains 72 spheres. Fig. 1.—The arrangement of 45 spheres in icosahedral closest packing. At the left there is shown a single sphere, which constitutes the inner core. Next there is shown the layer of 12 spheres, at the corners of a regular icosahedron. The third model shows the core of 13 spheres with 20 added in the outer layer, each in a triangular pocket corresponding to a face of the icosahedron these 20 spheres lie at the corners of a pentagonal dodecahedron. The third layer is completed, as shown in the model at the right, by adding 12 spheres at corners of a large icosahedron the 32 spheres of the third layer lie at the corners of a rhombic triaconta-hedron. The fourth layer (not shown) contains 72 spheres.
In the third model (Figure 5.1c), the plug-flow model, a steady uniform movement of the reactants is assumed,... [Pg.83]

Scheme 3 illustrates the third model reaction was homogenous, and again we intended to compare conventional heating with microwave heating, as well as study the influence of different solvents on both. The obtained results are shown in Table 4. [Pg.142]

In the third model, solvent molecules act as a bulk medium and significandy modify the solute properties. In this type, solute-solvent interaction is modeled using the continuum approach [8-11]. A variety of models have been proposed in the literature to treat solvent molecules in different situations. [Pg.380]

In the third model (2, right), the colored residues are those that are located on the surface and occur invariably (red) or almost invariably (orange) in all known insulins. It is assumed that amino acid residues that are not replaced by other residues during the course of evolution are essential for the protein s function. In the case of insulin, almost all of these residues are located on one side of the molecule. They are probably involved in the binding of the hormone to its receptor (see p.224). [Pg.76]

In the third model (finite chain with different terminal groups) no reflection symmetry element exists in the Fischer projection. The individual macromolecules are, therefore, chiral and all the tertiary atoms are asymmetric and different. The stereochemical notation for a single chain, depending on the priority order of the end groups, can be R, R2, R. . . R -2, R -i, Rn or R, R2, R3... [Pg.68]

With the third model, also, the single chains are chiral but with negligible optical activity. Even in this case we are in the cryptochirality domain, except possibly with low molecular weight compounds. [Pg.69]

The third model is a shift to higher frequencies and concomitant broadening of the resonance peak, due to increased 6s electron density in the eluster. Here use was made of the expected increase of 6s electron density due to the decrease in cluster volume, as obtained from EXAFS [39,40,41]. But as we have pointed out above, despite the decrease in cluster volume, the I.S. of the core sites indicates a decrease of 6s electron density. The excellent prediction of the I.S. values of the surface sites, given above, utilizing a sizeable increase in d-character of the electrons associated with (in the vicinity of) the surface sites, means that the postulated blue shift and flattening should really be a red shift and concomitant sharpening of the resonance, which should make the resonance more visible, if present. The MES I.S. results thus refute this as a possible explanation. [Pg.25]

The third model is simply that the Second Amendment recognizes the right of individuals to keep and bear arms. This is the view advanced by Emerson and adopted by the district court. None of our sister circuits has subscribed to this model, known by commentators as the individual rights model or the standard model. The individual rights view has enjoyed considerable academic endorsement, especially in the last two decades. [Pg.287]

We have made three new calculations following the cooling of proto-neutron stars until the luminosity fell below an observable level. In the first model a soft equation of state (EOS) was used (gravitational critical mass 1.50 MQ). The proto-neutron star was selected by taking a post bounce calculation of the core of a 25 M0 star and removing all the mass but for the inner 1.64 M0. The second model was made with a stiffer EOS using the same core as the first model. The third model was made by... [Pg.348]

The third model of semantic biology, in conclusion, is the idea that The mind is a trinitary system made of mental genotype, mental specietype and mental phenotype. Another version is the semantic theory of mental development Mental development is a sequence of two distinct processes of reconstruction from incomplete information, each of which increases the complexity of the system in a convergent way. The first process builds the specietypic mind (the universal grammar), while the second leads to the individual mind. ... [Pg.251]

The third model is an application of similar considerations to mental development, especially with respect to language. One kind of organic memory accounts for the acquisition of the capacities that appear early in the ontogeny of language, then a second takes over. Again, codes are absolutely indispensable, and the emergence of new ones has been a key innovation in the history of both life and mind. [Pg.313]

The third model assumes that the concentration fluctuations are long lived but not static. The dotted line in Fig. 12 shows good agreement with the data assuming a lifetime of 5 ps for the concentration fluctuations. A range of lifetimes from 4 to 7 ps is compatible with the data. This model not only agrees with the Raman echo data, it is also matches the FID and Raman line shape and peak position data as well. The lifetime found in the Raman echo implies that the Gaussian component of the line shape (4.25 cm-1) is actually motionally narrowed from the full distribution of frequencies (5.15 cm-1). [Pg.426]

The third model is the 6 Hz psychomotor seizure model, which screens for focal seizures and is used to find new antiepileptic agents with novel mechanisms of action. In these studies, convulsions were inhibited or prevented in mice following intraperitoneal administration of the experimental agent. [Pg.350]

The actual mechanism of self-association of monomeric protein into amyloid is complex and three mechanisms of stmcture conversion have been proposed (32) In templated assembly, a monomeric native state peptide binds to an existing nucleus. Upon binding, there is a change in the secondary stmcture of the monomer as it is added to the growing chain. Monomer directed conversion involves the presence of a misfolded monomer that templates the stmcture conversion of a native monomer, followed by disassociation and chain formation. The third model is nucleated polymerization, which is the most widely accepted model for the fibril growth. [Pg.2098]

The first model implies the rupture of the coordination bonds. This is inconsistent with the inertness of the macrobicyclic complex because its decomposition causes the rupture not only of M-N bonds, but also of C-C and C-H bonds. Therefore, this model predicts a relatively long lifetime of the state for the [Cr(sep)]3+ cation. In fact, the E states for [Cr(en)s] and [Cr(sep)] + cations have very similar lifetimes (of the order of 10 ps) in DMF at 0°C and similar spectral characteristics (both of them show an intense band at 15 151 cm-i and possess a quantitatively similar low-intensity vibronic structure). The macrobicyclic ligand ensures that ligand dissociation will have a large activation barrier, even in metal-centred electronic exited states. Neither the first model nor the second one adequately accounts for the photolytic similarities of [Cr(sep)]3+, [Cr(en)3] + and [Cr(NH3)e] cations. The third model seems the most realistic alternative [159]. [Pg.374]

In order to characterize the distributions of selective values in the second and the third model, we explored the value landscape by a Monte Carlo search. We created three random samples of 38,000 different sequences each (one repeat with 76,000 sequences gave essentially the same results) with predetermined ratios of probabilities for (0/1) digits, Pi = 0.2857, p2 = 0.5, and p3 = 0.7143, which led to mutant distributions centered at the 20-, 35-, and 50-error mutants of the all-zero sequence Iq. Three different parts of the value landscapes determined by Eqs. (IV.9)-(IV.ll) were explored in that way. The results are shown in Figure 22. [Pg.221]


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