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The Selective Removal of Protecting Groups in Carbohydrate Chemistry

THE SELECTIVE REMOVAL OF PROTECTING GROUPS IN CARBOHYDRATE CHEMISTRY... [Pg.13]

A. H. Haines, The selective removal of protecting groups in carbohydrate chemistry, Adv. Carbokydr. Chan. Biochem. 39 13 (1981). [Pg.30]

The great chemical stability and lack of reactivity under mild conditions for deprotection has greatly hampered the widespread application of amides in protecting group chemistry. However, recent developments in this area may suggest that proteases and amidohydrolases of broad substrate specificity can serve to overcome these drawbacks. Thus, 3-phenylpropionamides and iV-benzoylphenylalanine amides are attacked by chymotrypsin (pH 7, 37 °C). The application of penicillin acylase for the selective removal of the phenylacetamido residue from peptides (23 equation 7) and carbohydrates is also promising. [Pg.643]

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Carbohydrate groups

Carbohydrates groups, removal

Carbohydrates in chemistry

Carbohydrates protecting groups

Carbohydrates removal

Carbohydrates selective protection

Chemistry of carbohydrates

Chemistry protecting groups

Group selectivity

Protected carbohydrate group

Protected carbohydrates

Protecting groups carbohydrate chemistry

Protecting groups, removal

Protection chemistry

Protective groups selection

Protective groups selective

Protective groups, removal

Protective groups, removal selective

Protective removal, selective

Removal of protecting groups

Selection group

Selective Protection of Carbohydrates

Selective protection

Selective removal of protecting groups

Selectivity in removal of protecting groups

The Chemistry of Carbohydrates

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