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The Concept of Class

We can find the mirror A universe equivalents to all the symmetry operations in the group in a similar way. Thus, [Pg.435]

There is no need to stop here. We can imagine other parallel universes corresponding to reflections B and C and rotations D and F. (The F universe is the one we inhabit.) We can use the same sort of technique to accumulate corresponding operations for all these universes. The results are given in Table 13-3. [Pg.435]

If we examine this table, we note certain patterns. The operation E in our universe corresponds to E in all the universes. The reflections (A, B, and C) always correspond to reflections, and the rotations D and F) always correspond to rotations. This makes physical sense. If we do nothing ( ) in our universe, we expect the people in the other universes to do nothing also. If we rotate by 120°, we expect the people to perform [Pg.435]

EXAMPLE 13-2 BH3, like ammonia, has three planes of reflection symmetry that contain the three-fold rotational axis. However, BH3, being planar, also has a reflection operation through the molecular plane. Is this reflection operation in the [Pg.436]

We shall see that classes are important subdivisions of groups. Note, however, that a class need not be a subgroup. For instance, D and F constitute a class, but, as the class does not include E, it is not a subgroup. [Pg.436]


In Section 2.4 the concept of classes of elements within a group was introduced. This concept is utilized in dealing with symmetry groups. As we shall see in Chapter 4, it is convenient and customary in writing what is called the character table of a group to consider all the elements of a given class together,... [Pg.50]

In order to prove (10) it is necessary to employ the concept of class multiplication. The class product, QjQf, is defined as the collection of products of all possible pairs of group operations, where one member of the pair belongs to the class e and the other to the class 6/. Such a product is itself a collection of complete classes and may be described symbolically by the equation... [Pg.163]

In discussing the concept of class, it is unnecessary to postulate parallel universes, and the reader should not be disturbed by this pedagogical device. The people in the other universes are merely working with ammonia models that have been reflected or rotated with respect to the model orientation that we chose in Fig. 13-3. Operations in the same class are simply operations that become interchanged if our coordinate system is subjected to one of the symmetry operations of the group. [Pg.436]

Goldfarb, L. On the Concept of Class and Its Role in the Future of Machine Learning. In Goldfarb, L. (ed.) What Is a Structural Representation (in preparation) http //www.cs.unb.ca/ goldfarb/ETSbook/Class.pdf... [Pg.90]

The concepts of classes, methods and attributes give rise to a set of characteristics that give OOP its power. These characteristics have already been mentioned above, but they are more explicitly discussed in this section. [Pg.1950]

The PasquiU and Gifford approach described later, removes the need to concentrate on determining and Oy (refer to Figure 1) directly from weather data. In order to do this, Pasquill introduced the concept of the atmospheric stabihty class. [Pg.341]

More recently, D. Emin [24] developed an alternative analysis of activated hopping by introducing the concept of coincidence. The tunneling of an electron from one site to the next occurs when the energy state of the second site coincides with that of the first one. Such a coincidence is insured by the thermal deformations of the lattice. By comparing the lifetime of such a coincidence and the electron transit time, one can identify two classes of hopping processes. If the coincidence lime is much laigcr than the transit lime, the jump is adiabatic the electron has lime to follow the lattice deformations. In the reverse case, the jump is non-adia-batic. [Pg.566]

In proceeding to a consideration of the chemical ionization mass spectra of more highly branched paraffins, it will be most convenient to consider separately the several different classes of alkyl ions found in the spectra—i.e., MW — 1+, MW — 15+, MW — 29 +, etc. We can see from Table II that a considerable amount of variation in the relative intensity of the MW — 1 ions (always the highest mass ion for which an intensity is given in the table) occurs. However, we shall show that the observed MW — 1 intensities can be approximately accounted for in terms of the concept of localized electrophilic attack by the reactant ion. First, however, we must consider the energetics of two processes which may be important in generating the spectra of branched paraffins. One of these is the abstraction of a primary hydrogen by the reactant ion. As a typical example we may write... [Pg.186]

In summary, we found that the students received lower scores on items that were at different pressures than on items with the same amount of pressure. Also, we found that although the students learned the concept of diffusion in their seventh grade biology class, they did not generate the conception of diffusion in a submicro-scopic maimer. Instead, they tended to conceptualize the diffusion of the particles in a more intuitive way (the heavier object sinking to the bottom of the container) than in a scientific model that was designed to delineate the random nature of the particle motion. [Pg.270]

A final example is the concept of QM state. It is often stated that the wave function must be square integrable because the modulus square of the wave function is a probability distribution. States in QM are rays in Hilbert space, which are equivalence classes of wave functions. The equivalence relation between two wave functions is that one wave function is equal to the other multiplied by a complex number. The space of QM states is then a projective space, which by an infinite stereographic projection is isomorphic to a sphere in Hilbert space with any radius, conventionally chosen as one. Hence states can be identified with normalized wave functions as representatives from each equivalence class. This fact is important for the probability interpretation, but it is not a consequence of the probability interpretation. [Pg.26]

Hence polysaccharides have been viewed as a potential renewable source of nanosized reinforcement. Being naturally found in a semicrystalline state, aqueous acids can be employed to hydrolyze the amorphous sections of the polymer. As a result the crystalline sections of these polysaccharides are released, resulting in individual monocrystalline nanoparticles [13]. The concept of reinforced polymer materials with polysaccharide nanofillers has known rapid advances leading to development of a new class of materials called Bionanocomposites, which successfully integrates the two concepts of biocomposites and nanometer sized materials. The first part of the chapter deals with the synthesis of polysaccharide nanoparticles and their performance as reinforcing agents in bionanocomposites. [Pg.120]

Based on the concept of mixed-framework lattices, we have reported a novel class of hybrid solids that were discovered via salt-inclusion synthesis [4—7]. These new compounds exhibit composite frameworks of covalent and ionic lattices made of transition-metal oxides and alkali and alkaline-earth metal halides, respectively [4]. It has been demonstrated that the covalent frameworks can be tailored by changing the size and concentration of the incorporated salt. The interaction at the interface of these two chemically dissimilar lattices varies depending upon the relative strength of covalent vs. ionic interaction of the corresponding components. In some cases, the weak interaction facilitates an easy... [Pg.239]

Section III introduces the concept of nonmonotonic planning and outlines its basic features. It is shown that the tractability of nonmonotonic planning is directly related to the form of the operators employed simple propositional operators lead to polynomial-time algorithms, whereas conditional and functional operators lead to NP-hard formulations. In addition, three specific subsections establish the theoretical foundation for the conversion of operational constraints on the plans into temporal orderings of primitive operations. The three classes of constraints considered are (1) temporal ordering of abstract operations, (2) avoidable mixtures of chemical species, and (3) quantitative bounding constraints on the state of processing systems. [Pg.45]

The starting point for much of the work described in this article is the idea that quinone methides (QMs) are the electrophilic species that are generated from ortho-hydro-xybenzyl halides during the relatively selective modification of tryptophan residues in proteins. Therefore, a series of suicide substrates (a subtype of mechanism-based inhibitors) that produce quinone or quinonimine methides (QIMs) have been designed to inhibit enzymes. The concept of mechanism-based inhibitors was very appealing and has been widely applied. The present review will be focused on the inhibition of mammalian serine proteases and bacterial serine (3-lactamases by suicide inhibitors. These very different classes of enzymes have however an analogous step in their catalytic mechanism, the formation of an acyl-enzyme intermediate. Several studies have examined the possible use of quinone or quinonimine methides as the latent... [Pg.357]


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