Tert-Butyl peroxyacetate

By way of example, tert-butyl peroxyacetate [107-71-1] is more thermally stable than 3-hydroxy-1,1-dimethylbutyl peroxyneoheptanoate [110972-57-1]. Although other factors affect thermal stability, the trends shown can be used to qualitatively predict peroxyester reactivity trends. The order of activity of the R group in peroxyesters is also observed in other / -alkylperoxy-containing compounds. 

SYNS t-BUTYL PERACETATE t-BUTYL PEROXYACETATE tert-BUTYL PEROXYACETATE, >76% in solution (DOT) ETHANEPEROXOIC ACID, 1,1-DMETHYLETHYL ESTER LUPERSOL 70 TRIGONOX F-C50... 

Beilstein Handbook Reference) Aztec t-butyl peracetate-50 OMS, 60 OMS, 75 OMS BRN 1701510 t-Butyl peroxyacetate tert-Butyl peracetate tert-Butyl peroxyacetate EINECS 203-514-5 Ethaneperoxoic acid, 1,1-dimethylethyl ester Lupersol 70 NSC 118417 Peroxyxetic acid, tert-butyl ester Trigonox F-C50. Used as a catalyst and initiator. Catalyst Resowces Inc. 

In many cases, azobis(isobutyronitrile) (AIBN) is employed as radical initiator. The polymerization conditions, in particular solvent, depend mainly on both, solubility of the starting sf monomers and choice of comonomer. To give just a few examples, copolymers of dodecafluoroheptyl methacrylate with methacrylic acid could be synthesized in dioxane due to the solubilizing effect of methacrylic acid [66], copolymers of sfMA-H2F8 and sfMA-H2F4 with styrene could be prepared in toluene [35], and copolymerizations of i/methacrylates with butyl acrylate, hydroxy-butyl acrylate, and styrene were performed using tert-butyl peroxyacetate as initiator in methyl amyl ketone [31]. 

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