Tert-Butyl peracetate

Tert-Butyl Peracetate Diethyl-aluminum Chloride... 

Copper-catalyzed687-689 or photochemical690 reaction of alkenes with peroxy-esters, usually with tert-butyl peracetate (or rm-BuOOH in acetic acid), may be used to carry out acyloxylation or the synthesis of the corresponding allylic esters in good yields. In contrast to the oxidation with Se02, preferential formation without rearrangement of the 3-substituted esters takes place from terminal alkenes 691... 

Butyl ether, see Dibutyl ether n-Butyl formate iso-Butyl formate Butyl hydroperoxide in heptane in hexane in pentane Butyl lactate Butyl mercaptan Butyl methacrylate Isobutyl methyl ketone tert-Butyl peracetate tert-Butyl perbenzoate Butyl peroxypivalate (in 75% sol. 

Beilstein Handbook Reference) Aztec t-butyl peracetate-50 OMS, 60 OMS, 75 OMS BRN 1701510 t-Butyl peroxyacetate tert-Butyl peracetate tert-Butyl peroxyacetate EINECS 203-514-5 Ethaneperoxoic acid, 1,1-dimethylethyl ester Lupersol 70 NSC 118417 Peroxyxetic acid, tert-butyl ester Trigonox F-C50. Used as a catalyst and initiator. Catalyst Resowces Inc. 

The polybutadiene used was Intene from I. S. Rubber [77] = 2.1 dl/g in cyclohexane at 30°C. Vinyl chloride and styrene monomers from Montedison were 99.99 and 99.5% pure respectively. Azobis(isobutyronitrile) (AIBN) from Fluka was 99% pure. Di-te/t-butyl peroxide was 95% pure. Tert-butyl peracetate was used at a 50% dilution with dimethyl phthalate. The n-butyl ester of 3,3- (di-te/t-butylperoxy)valerianic acid was 85% pure. Terf-dodecyl mercaptan, a commercial product of the Societe Nationale des Petroles d Aquitaine, was used as a modifier. The solvents used were commercial products purified by fractionation. 

Measurements were made in apparatus depicted in Figure 4. T = 100°C elastomer in the initial styrene solution, 10%. EPDM, type B initiator, tert-butyl peracetate, 0.09% modifier, tert-dodecyl mercaptan, 0.02%. Polybutadiene, lntene initiator, tert -butyl peracetate, 0.02% modifier, tert-... 

EPDM elastomer, type C and elastomer in starting solution, 10%. Initial polymerization T = 100°C styrene conversion, 30% and initiator, tert-butyl peracetate, 0.09%. Suspension polymerization suspending agent, 0.6% ferf-butyl peroxide, 0.4% and water/(rubber -f monomer) = 1.2. Suspension cycle 2 hrs at 120°C, l hr at 140°C, and 2 hrs at 155°C. 

Synonyms tert-butyl peracetate peroxy-acetic acid terr-butyl ester Lupersol 70... 

Pd(OAc)2) were used in combination with an additional oxidant of tert-butyl peracetate (tert-BuOaAc)/ ... 

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