Temperature Kelvin definition

The thermodynamic temperature. Hie definition of thermodynamic temperature in kelvins (Eq. 6-8) also follows from Eq. 6-6. See textbooks of thermodynamics for further treatment. 

The most important modem system of units is the SI system, which is based around seven primary units time (second, abbreviated s), length (meter, m), temperature (Kelvin, K), mass (kilogram, kg), amount of substance (mole, mol), current (Amperes, A) and luminous intensity (candela, cd). The candela is mainly important for characterizing radiation sources such as light bulbs. Physical artifacts such as the platinum-iridium bar mentioned above no longer define most of the primary units. Instead, most of the definitions rely on fundamental physical properties, which are more readily reproduced. For example, the second is defined in terms of the frequency of microwave radiation that causes atoms of the isotope cesium-133 to absorb energy. This frequency is defined to be 9,192,631,770 cycles per second (Hertz) —in other words, an instrument which counts 9,192,631,770 cycles of this wave will have measured exactly one second. Commercially available cesium clocks use this principle, and are accurate to a few parts in 1014. 

Converting between Celsius (°C) and Kelvin (K) temperature scales Converting between Celsius (°C) and Fahrenheit (°F) temperature scales Definition of density... 

A first perspective on this enormous discrepancy can be found by considering the problems in measuring another physical base quantity, temperature. The definition of the kelvin, the unit of thermodynamic temperature (Table 1.1), is the fraction (1/273.16) of the... 

Unit for temperature The SI unit system defines a base unit for temperature kelvin with the dimension ( ). The physical origin of this definition is the thermodynamic temperature scale where the temperature unit is defined as being proportional to the kinetic mean energy of the molecules in a system of matter. Therefore, for dimensional analysis it is admissible to use the same unit for temperature quantities as for energy, if this is expedient. In this case, the dimension for temperature is (L MT ). 

The new international temperature scale, known as ITS-90, was adopted in September 1989. However, neither the definition of thermodynamic temperature nor the definition of the kelvin or the Celsius temperature scales has changed it is the way in which we are to realize these definitions that has changed. The changes concern the recommended thermometers to be used in different regions of the temperature scale and the list of secondary standard fixed points. The changes in temperature determined using ITS-90 from the previous IPTS-68 are always less than 0.4 K, and almost always less than 0.2 K, over the range 0-1300 K. 

The ultimate definition of thermodynamic temperature is in terms of pV (pressure X volume) in a gas thermometer extrapolated to low pressure. The kelvin (K), the unit of thermodynamic temperature, is defined by specifying the temperature of one fixed point on the scale—the triple point... 

Celsius temperature degree Celsius °c equal to kelvin and used in place of kelvin for expressing Celsius temperature, t, defined by equation t = T — where T is the thermodynamic temperature and Tq = 273.15 K by definition... 

The volume of a gas would theoretically be zero at a temperature of approximately -273°C or -460°F. Tliis temperature, wliich lias become known as absolute zero, is tlie basis for tlie definition of two absolute temperature scales, tlie Kelvin (K) and Rankine (°R) scales. The former is defined by shifting tlie Celsius scale by 273-Celsius degrees so that 0 K is equal to -273°C. Equation (4.2.3) shows tliis relation. 

The exact form of the function < > (T2, T being to some extent arbitrary, we might give several definitions of absolute temperature, all drawn up, however, in terms of the efficiency of the reversible engine. Lord Kelvin, in 1854, adopted the following form ... 

Temperature Scales A quantitative description of temperature requires the definition of a temperature scale. The two most commonly encountered in thermodynamics are the absolute or ideal gas (°A) scale and the thermodynamic or Kelvin (K) scale."... 

The second law of thermodynamics says that in a Carnot cycle Q/T = constant. This law allows for the definition of a temperature scale if we arbitrarily assign the value of a reference temperature. If we give the value T3 = 273.16K to the triple point (see Gibbs law, Section 8.2) of water, the temperature in kelvin units [K] can be expressed as ... 

Consultative Committee for Thermometry creation of a mise en pratique of die definition of the kelvin The Consultative Committee for Thermometry, considering that the ITS-90 and the PLTS-2000 are internationally accepted practical temperature scales defining temperatures T90 and T2qqq that are good approximations to thermodynamic temperature T... 

Taking up a 2005 recommendation of the Consultative Committee for Thermometry (CCT) [25], the Comite International des Poids et Mesures (CIPM) created a mise en practique of the definition of the kelvin containing clarifications and recommendations of the CCT concerning the realization of the definition of the kelvin and the implementation of practical temperature scales. 

The ideal scale, as defined by (2.7a, b), also has an entirely different (and quite surprising ) theoretical basis, related to the maximum efficiency of machines and the second law of thermodynamics. This alternative definition of T(suggested by Kelvin) will be discussed in Section 4.5. However, we can recognize at this point that such a dual connection to fundamental thermodynamic principles of great universality gives (2.7a, b) a double-justification to be considered the true temperature scale. We henceforth adopt this definition of T throughout this book. 

According to Kelvin s definition, absolute Kelvin temperature TK can be consistently assigned in terms of the efficiency of the reversible engine operating between the two reservoir temperatures as... 

Heat and temperature were poorly understood prior to Carnot s analysis of heat engines in 1824. The Carnot cycle became the conceptual foundation for the definition of temperature. This led to the somewhat later work of Lord Kelvin, who proposed the Kelvin scale based upon a consideration of the second law of thermodynamics. This leads to a temperature at which all the thermal motion of the atoms stops, By using this as the zero point or absolute zero and another reference point to determine the size of the degrees, a scale can be defined. The Comit e Consultative of the International Committee of Weights and Measures selected 273.16 K as the value lor the triple point for water. This set the ice-point at 273.15 K. 

All thermometers, regardless of fluid, read the same at zero and 100 if they are calibrated by the method described, but at other points the readings do not usually correspond, because fluids vary in their expansion characteristics. An arbitrary choice could be made, and for many purposes this would be entirely satisfactory. However, as will be shown, the temperature scale of the SI system, with its kelvin unit, symbol K, is based on the ideal gas as thermometric fluid. Since the definition of this scale depends on the properties of gases, detailed discussion of it is delayed until Chap. 3. We note, however, that this is an absolute scale, and depends on the concept of a lower limit of temperature. 

A) The SI (Systeme International) units use kilograms, meters, seconds, amperes, kelvin, mole (6.022 x 1023 molecules per gram-mole, and not per kg-mole), and candela for [M], [L], [T], current, absolute temperature, mole, and luminous intensity, respectively. It started from an MKS (m-kg-s) system and included an electrical unit as part of the definition, as first suggested by Giorgi44 in 1904. There is a very slight modification of SI, used in nonlinear optics, confusingly dubbed MKS by its users, but called SI here. 

It is clear that with the definition of the Ampere also the other electrical quantities are defined. Thermodynamics required the introduction of the base quantities temperature and amount of substance, with the Kelvin and the mol as units. The unit of energy is the Joule, so that no conversion factor is involved here either. 

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