Tear strength tests

TDI isomers, 210 Tear strength tests, 242-243 TEDA. See Triethylene diamine (TEDA) Telechelic oligomers, 456, 457 copolymerization of, 453-454 Telechelics, from polybutadiene, 456-459 TEM technique, 163-164 Temperature, polyamide shear modulus and, 138. See also /3-transition temperature (7)>) Brill temperature Deblocking temperatures //-transition temperature (Ty) Glass transition temperature (7) ) Heat deflection temperature (HDT) Heat distortion temperature (HDT) High-temperature entries Low-temperature entries Melting temperature (Fm) Modulu s - temperature relationship Thermal entries Tensile strength, 3, 242 TEOS. See Tetraethoxysilane (TEOS)... 

In tensile strength determinations, the material has to completely break through the cross-section, whereas the tear strength test indicates the resistance to the propagation of a defect, such as a nick, in the polyurethane. The way that elastomers tear under different conditions has led to a number of different tests. 

Tests such as the tensile strength and tear strength tests evaluate polyurethanes to destruction. When polyurethanes are used in a practical situation, the aim is for them to have as long a life as needed in the application. Stress, strain, and shear are applied to the polyurethane at various frequencies and at different temperatures. There may also be dynamic variations on top of a static load, for example, vibrations on a loaded isolation pad. 

PU formulations were performed but they could not be tested because the tear strength test was not efficient since it behaved finally for these samples as a tensile test. The angular specimens were elongated till the limit value of the tensile device and the maximum force for rupture could not be determined. In order to get tear strength results, other standard tests using trapezoidal specimens are under study and results are pending. 

Tables 4—6 Ust ASTM methods used for the characterization of PB and PMP. A number of specialized methods were developed for testing particular articles manufactured from polyolefins several of these determine the performance of PB and PMP film, including the measurement of the film s dart impact strength and tear strength. Dart impact strength is measured by dropping a heavy dart with a round tip on a stretched film. Tear resistance, which reflects the film s resistance to tear propagation, is measured with the Ehnendorf tear tester. Two values for the tear strength are usually reported, one in the machine dkection of the film and the other in the transverse dkection. Pipes manufactured from PB are tested by pressurizing them internally with water the time-to-burst failure is determined at various temperatures (46). The standard test method for haze and luminous transmittance (ASTM D1003) is used for the measurement of PMP optical characteristics.

Although a variety of test methods, eg, Dk, modulus, and tear strength, exist to determine key properties of potential contact lens materials, a number of properties, eg, wettabihty and deposition, have no predictive methodology short of actual clinical experience. 

Characterization of Hydrogel Films. Mechanical testing was conducted in buffered saline on an Instron instrument, according to the modified ASTM D-1708 (tensile) and D-1938 (tear) and were reported in g/mm2 for modulus and g/mm for tear strength. The water contents and the amount of extractables were measured gravimetr ica1ly. 

Tear strength is only applicable to flexible materials and is very little used to monitor ageing simply because tensile strength will serve perfectly well. There are circumstances where compression stress-strain properties would be relevant but the relatively bulky test pieces will be subject to the limitation of oxygen diffusion in any accelerated tests and changes can probably be estimated from tensile measurements. Similarly, shear stress-strain is very rarely used for monitoring ageing. 

ISO 34-1 2004 Rubber, vulcanized or thermoplastic - Determination of tear strength -Part 1 Trouser, angle and crescent test pieces... 

The short-term tear strength retention at 100°C can vary from 28% up to 54% according to the tested grades. 

Neoprene is the generic name for polychloroprene rubber. It has been produced commercially since 1931 and had rapid and wide acceptance because it is much superior to natural rubber for heat and oil resistance. Heat resistance is far better than NR, BR or SBR. but less than EPDM. When heated in the absence of air, neoprene withstands degradation better than other elastomers which are normally considered more heat resistant, and retains its properties fifteen times longer than in the presence of air. Compression set at higher temperature is better than natural rubber and 100°C is typically the test temperature rather than 70°C. Abrasion resistance is not as good as natural rubber but generally better than most heat resistant and oil resistant rubbers. This is also true for tear strength and flex resistance. 

It is not surprising that, given the importance of tearing and the different levels of result obtained from different geometries, a considerable number of tear tests have been devised which, in part, reflect the different stress concentrations found in various products. The arbitrary nature of the geometries means that, in general, the measured tear strength is not an intrinsic property of the material and it is difficult to directly correlate the results of laboratory tests with the performance of products in service. 

As mentioned above, a large number of different geometries have been used for tear strength measurements. Often they have been chosen with more thought for the convenience of testing than the significance of the results. 

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