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The BMN-170 and the RBEC-M are designed for operation in a multi-component energy system with optimized nuclide flows (such system is described in Section XXIII-1.5 of Annex XIII). [Pg.33]

Since the original proof of concept, and a later demonstration of its practical use in semiconductor manufacturing (40), appHcations and extensions of this concept have proliferated. In the following sections these systems are described in greater detail with emphasis on the resist formulation at a components level (41). [Pg.123]

This type of chromatographic development will only be briefly described as it is rarely used and probably is of academic interest only. This method of development can only be effectively employed in a column distribution system. The sample is fed continuously onto the column, usually as a dilute solution in the mobile phase. This is in contrast to displacement development and elution development, where discrete samples are placed on the system and the separation is subsequently processed. Frontal analysis only separates part of the first compound in a relatively pure state, each subsequent component being mixed with those previously eluted. Consider a three component mixture, containing solutes (A), (B) and (C) as a dilute solution in the mobile phase that is fed continuously onto a column. The first component to elute, (A), will be that solute held least strongly in the stationary phase. Then the... [Pg.8]

The engineering of novel deviees requires, in many eases, materials with finely seleeted and preestablished properties. In partieular, one of the most promising lines of synthetic materials research consists in the development of nanostructured systems (nanocomposites). This term describes materials with structures on typical length scale of 1-100 nm. Nanometric pieces of materials are in an intermediate position between the atom and the solid, displaying electronic, chemical and structural properties that are distinct from the bulk. The use of nanoparticles as a material component widens enormously the available attributes that can be realised in practice, which otherwise would be limited to bulk solid properties. [Pg.128]

Opening segments of the IP2 PRA data analysis section describe the definitions of terms and concepts employed, the assumptions made, and limitations recognized during the data base construction. A set of 39 plant-specific component failure mode summaries established the basis for component service hour determinations, the number of failures, and the test data source for each failure mode given for each component. Generic data from WASH-1400, IEEE Std 500, and the LER data summaries on valves, pumps, and diesels were combined with plant-specific failure data to produce "updated" failure information. All the IP2 specialized component hardware failure data, both generic and updated, are contained in Table 1.5.1-4 (IP3 1.6.1-4). This table contains (by system, component, and failure mode) plant-specific data on the number of failures and service hours or demands. For some components, it was determined that specifications of the system was warranted because of its impact on the data values. [Pg.119]

A complicated analyser system such as that described above can only be maintained if all of the valve-switching events are scheduled in the correct positions in the chromatogram. Mismatch of one of the events will cause (parts of) components to be directed to the wrong columns and thus possible misidentifications. Therefore, accurate determination and maintenance of the cutting windows are essential. This can only be accomplished in a fully automated system with accurate flow and temperature controls. Once these prerequisites are fulfilled, the system will operate unattended and produce results of high quality. The repeatabilities generally achieved are of the order of 1 % rel. [Pg.385]

Mutual diffusion is usually described by Pick s first law, written here for a system with two components and one-dimensional diffusion in the z-direction ... [Pg.162]

In a system with two components, one finds experimentally the same values for and D, because is not independent from J,. It follows that the system can be described with only one mutual diffusion coefficient D = Dj = D2. [Pg.163]

Many technological applications of liquid crystals, as in electro-optic display devices, are based on multicomponent mixtures. Such systems offer a route to the desired material properties which cannot be achieved simultaneously for single component systems. Mixtures also tend to exhibit a richer phase behaviour than pure systems with features such as re-entrant nematic phases [3] and nematic-nematic transitions possible. In this section, we describe simulations which have been used to study mixtures of thermotropic calamitic mesogens. [Pg.121]

After Chadwick s discovery, scientists knew the three components of an atom protons and neutrons in the nucleus with electrons hovering outside. The masses and charges of these constituents are shown in Table 3.1. Chemists have developed a system to describe the elements based on their atomic makeup. The atomic number of an atom is the number of protons in the nucleus. This number is usually represented by the letter Z. Thus, for hydrogen Z = 1, for helium Z = 2, and so on. [Pg.34]

The design of simulated moving bed chromatography and its application to the separation of cycloheptanone and cyclopentanone as test substances to validate the system for subsequent chiral chromatography has been described.27 Briefly, eight silica-packed columns were hooked up in series to form a cyclic flow path. On the first pair, preliminary separation of the components was performed, with the less-retained raffinate being directed to waste. Following the second pair of columns, eluent was added. After the... [Pg.133]

Abstract Recent advances in the metal-catalyzed one-electron reduction reactions are described in this chapter. One-electron reduction induced by redox of early transition metals including titanium, vanadium, and lanthanide metals provides a variety of synthetic methods for carbon-carbon bond formation via radical species, as observed in the pinacol coupling, dehalogenation, and related radical-like reactions. The reversible catalytic cycle is achieved by a multi-component catalytic system in combination with a co-reductant and additives, which serve for the recycling, activation, and liberation of the real catalyst and the facilitation of the reaction steps. In the catalytic reductive transformations, the high stereoselectivity is attained by the design of the multi-component catalytic system. This article focuses mostly on the pinacol coupling reaction. [Pg.63]

Note that in the component mass balance the kinetic rate laws relating reaction rate to species concentrations become important and must be specified. As with the total mass balance, the specific form of each term will vary from one mass transfer problem to the next. A complete description of the behavior of a system with n components includes a total mass balance and n - 1 component mass balances, since the total mass balance is the sum of the individual component mass balances. The solution of this set of equations provides relationships between the dependent variables (usually masses or concentrations) and the independent variables (usually time and/or spatial position) in the particular problem. Further manipulation of the results may also be necessary, since the natural dependent variable in the problem is not always of the greatest interest. For example, in describing drug diffusion in polymer membranes, the concentration of the drug within the membrane is the natural dependent variable, while the cumulative mass transported across the membrane is often of greater interest and can be derived from the concentration. [Pg.21]

At the antipodes of the latter description, there is a continuous need for better low-resolution models that involve, for instance, coarse graining of molecules, or implicit solvation. This need is motivated by the expectation that the free energy of a large system can be calculated with sufficient accuracy without requiring that all its components be described at the atomic level. In many cases, this is equivalent to the assumption that a mean-field approximation works, or that many fast degrees of freedom can be removed from the system, yet without any appreciable loss of... [Pg.510]

This assumption is implicitly present not only in the traditional theory of the free-radical copolymerization [41,43,44], but in its subsequent extensions based on more complicated models than the ideal one. The best known are two types of such models. To the first of them the models belong wherein the reactivity of the active center of a macroradical is controlled not only by the type of its ultimate unit but also by the types of penultimate [45] and even penpenultimate [46] monomeric units. The kinetic models of the second type describe systems in which the formation of complexes occurs between the components of a reaction system that results in the alteration of their reactivity [47-50]. Essentially, all the refinements of the theory of radical copolymerization connected with the models mentioned above are used to reduce exclusively to a more sophisticated account of the kinetics and mechanism of a macroradical propagation, leaving out of consideration accompanying physical factors. The most important among them is the phenomenon of preferential sorption of monomers to the active center of a growing polymer chain. A quantitative theory taking into consideration this physical factor was advanced in paper [51]. [Pg.170]

As a second example, we choose quartz (or any silica polymorph) as a component for a system containing an aqueous fluid and quartz. Now the mole number for the quartz component includes not only the silica in the quartz mineral, the real quartz, but the silica in solution in species such as SiC>2(aq) and IGSiO. Again, the mole numbers of component quartz and real quartz are not the same. A common mistake in geochemical modeling is confusing the components used to describe the composition of a system with the species and phases that are actually present. [Pg.32]

Choosing the basis in this manner sometimes leads to some initial confusion, because we select species present in the system to serve as components. There is a risk of confusing the amount of a component, which describes bulk composition but not the actual state of the system, with the amount of a species or mineral that exists in reality. [Pg.38]

TA are used to model and analyze dynamic systems with discrete and timed behavior. One of their strengths is the easy modeling in a decomposed fashion as a set of often small and individually acting automata. Time in TA is modeled in a very natural way by a set of clocks that simply measure the time between events. This is a major difference to MIP techniques, where time and dynamic components are described in a rather artificial way by providing variables and inequalities for every point of time within a discretized time horizon. In addition to the advantages in modeling, TA serve as a computational model which can be analyzed by techniques for reachability analysis. These techniques are widely used in the context of verification, in which the objective is to detect possible undesired (bad or forbidden) behaviors [9-11]. The success of these techniques was pushed by the availability and increasing performance of tools for TA, e.g., Uppaal [9, 10, 12, 13]. [Pg.220]


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