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Kernel symmetry

Lithium has been alloyed with gaUium and small amounts of valence-electron poorer elements Cu, Ag, Zn and Cd. like the early p-block elements (especially group 13), these elements are icosogen, a term which was coined by King for elements that can form icosahedron-based clusters [24]. In these combinations, the valence electron concentrations are reduced to such a degree that low-coordinated Ga atoms are no longer present, and icosahedral clustering prevails [25]. Periodic 3-D networks are formed from an icosahedron kernel and the icosahedral symmetry is extended within the boundary of a few shells. [Pg.143]

Clearly, the above procedure can be continued (in principle) as many times as required. Thus, if the wave function includes n = —4 3 paths, we have simply to dehne the function I 4((t)) = —+ 8ti), and then map onto the (j) = 0 16ti cover space, which will unwind the function completely. In general, if there are h homotopy classes of Feynman paths that contribute to the Kernel, then one can unwind ihG by computing the unsymmetrised wave function ih in the 0 2hn cover space. The symmetry group of the latter will be a direct product of the symmetry group in the single space and the group... [Pg.35]

Since ky does not depend on i or j, it can be absorbed, together with the symmetry factor a (equal to 4 for RA2 or 2 for ARB), into time units and the Smolu-chowski coagulation equation would assume its simplest form with the kernel equal to one ... [Pg.140]

The point group of a JT distorted molecule is a subgroup of the point group G of the parent molecule without JT distortion. In the JT active configuration space v, there exists a minimal subgroup which consists of such symmetry operations g in G that leave all allowed distortions invariant. Such a subgroup will be referred to as a kernel of v in G, K(G, v) ... [Pg.242]

We may see that all A2" characters of D h which are in the E, C3 and CTv headed columns (the corresponding operations constitute the C v group) are equal to -1-1. It means that these symmetry operations are conserved during any nuclear displacement (such as vibrations) described by IR A2" of Dsh group. The subgroup formed in this way is called kernel or kernel subgroup K(G, A) where G is the parent group and A denotes the IR of this displacement [11], In our case this relation is described by the formula... [Pg.54]

A degenerate (multidimensional) representation describes the symmetry of a set of coordinates (such as vibrations). The elements of this set are called the components of the representation and span a multidimensional distortion space [10]. Because the degeneracy leaves the direction of the distortion unspecified, one has to scan all directions of the distortion space. A minimal subgroup of symmetry elements, which must be conserved in any case, consists of those symmetry operations that leave all distortions invariant and is said to form the kernel K(G, A) of the degenerate representation A. The kernel of the degenerate mode may be obtained from the character tables by collecting all symmetry operations with the same characters as the identity operation [11]. In the case of group for E type IR with all characters equal to -1-2 we obtain... [Pg.54]

It has been mentioned [25-27] that the optimized structure of the monoanionic state of coronene does not have (epikernel) D2h symmetry expected from the epikernel principle but has (kernel) C2h symmetry. Hence the JT distortion of coronene monoanion is an exception for the epikernel principle. This is because the epikernel... [Pg.68]

If it is neither primal nor dual, then by symmetry the kernel contains a factor of [1, l]/2, but the space is still that of linear combinations of schemes which have this factor as well as a varying number of (1 — za)/( 1 — z) factors. [Pg.142]

Fig. 2.3. Scheme showing that the sum of two equal deformations along different C3, co-kernel directions is a deformation with C2v co-kernel symmetry... [Pg.35]

If the reaction can not be modeled by an impulsive collision event, as for atomic recombination or some isomerization reactions, then is zero by time reversal symmetry as discussed earlier. Nevertheless, the structure of the rate kernel has the same qualitative structure as described above. To... [Pg.104]

The reason why double-kernelled peaches and apricots are harmful to people is that the flowers of these trees are properly speaking five-petalled yet if they develop with sixfold (symmetry), twinning will occur. Plants and trees all have the fivefold pattern only the yellow-berry and snowflake crystals are hexagonal. This is one of the principles of Yin and Yang. So if double-kernelled peaches and apricots with an (aberrant) sixfold (symmetry) are harmful, it is because these trees have lost their standard rule. [Pg.49]

The nonlocal term in Eq. (37) is transformed after differentiating with respect to h using the symmetry of the interaction kernel Q z), and, after shifting the variable back, integrated by parts with the help of Eq. (38). The result is... [Pg.180]

The last term in Eq.(2.9) describes molecular motor-mediated interaction of rods. We assume that after the interaction, the two rods share the same orientation and the same spatial location in the middle of their original locations. The interaction kernel W is localized in space, but in general does not have to be isotropic. On the symmetry grounds we assume the following form (we assume 2D geometry and neglect higher-order anisotropic corrections) ... [Pg.289]


See other pages where Kernel symmetry is mentioned: [Pg.233]    [Pg.144]    [Pg.208]    [Pg.549]    [Pg.370]    [Pg.164]    [Pg.152]    [Pg.102]    [Pg.9]    [Pg.242]    [Pg.24]    [Pg.202]    [Pg.33]    [Pg.225]    [Pg.238]    [Pg.47]    [Pg.55]    [Pg.59]    [Pg.332]    [Pg.376]    [Pg.377]    [Pg.413]    [Pg.204]    [Pg.13]    [Pg.15]    [Pg.31]    [Pg.32]    [Pg.34]    [Pg.35]    [Pg.36]    [Pg.38]    [Pg.39]    [Pg.45]    [Pg.2003]    [Pg.190]   
See also in sourсe #XX -- [ Pg.33 ]




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