Surface modification aromatic polyamides

In dentistry, silicones are primarily used as dental-impression materials where chemical- and bioinertness are critical, and, thus, thoroughly evaluated.546 The development of a method for the detection of antibodies to silicones has been reviewed,547 as the search for novel silicone biomaterials continues. Thus, aromatic polyamide-silicone resins have been reviewed as a new class of biomaterials.548 In a short review, the comparison of silicones with their major competitor in biomaterials, polyurethanes, has been conducted.549 But silicones are also used in the modification of polyurethanes and other polymers via co-polymerization, formation of IPNs, blending, or functionalization by grafting, affecting both bulk and surface characteristics of the materials, as discussed in the recent reviews.550-552 A number of papers deal specifically with surface modification of silicones for medical applications, as described in a recent reference.555 The role of silicones in biodegradable polyurethane co-polymers,554 and in other hydrolytically degradable co-polymers,555 was recently studied. 

Wu, S., et al. (1997). Plasma modification of aromatic polyamide reverse osmosis composite membrane surface. J. Applied Polymer Science. 64, 10, 1923-1926. 

Chemical modification of a membrane surface can be used in combination with spacers and periodic applications of bioacids [70]. The paper by Redondo, however, is short on specifics (e.g., details of chemical modification of aromatic polyamides membrane surface), and therefore not very useful to those looking for insights into membrane fouling. 

The incorporation of positive charges has decreased the fouling susceptibility of membranes even more effectively. This is the principle of the aromatic polyamide membrane series commercialized by Hydranautics as low fouling composite membranes (LFC). Cationic charge-modified nylon membranes are also commercially available from CUNO 3M, under the trademark Zeta Plus . Pall Corp. sells cationic charge-modified nylon membranes under the trademark Ngg Posidyne. There are different ways to make the membrane positively charged. A patent from Millipore [148] describes the surface modification of hydrophobic membranes by contacting them with a solution of polyamine epichlorohydrin... 

SURFACE MODIFICATION OF AROMATIC POLYAMIDES BY MICROWAVE PLASMA TREATMENT... 

X.Y. Wei, Z. Wang, Z. Zhang, JJC. Wang, S.C. Wang, Surface modification of commercial aromatic polyamide reverse osmosis membranes by graft polymerization of 3-aUyl-5,5-dimethylhydantoin, 7 Afemfr Sci, 351 (2010) 222-233. 

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