Surface-Initiated Living Radical Polymerization

Tsujii, Y, Ohno, K., Yamamoto, S., Goto, A. and Fukuda, T. (2006) Structure and properties of high-density polymer brushes prepared by surface-initiated living radical polymerization. Adv. Polym. Sci., 197, 1-45. [Pg.69]

Structure and Properties of High-Density Polymer Brushes Prepared by Surface-Initiated Living Radical Polymerization... [Pg.213]

A dense polymer brush is obtained using the grafting from techniques. Surface-initiated polymerization in conjunction with a living polymerization technique is one of the most useful synthetic routes for the precise design and functionalization of the surfaces of various solid materials with well-defined polymers and copolymers. Above all, surface-initiated living radical polymerization (LRP) is particularly promising due to its simplicity and versatility and it has been applied for the synthesis of Au NPs. [Pg.149]

Surface-initiated living radical polymerization is also applied for spherical surfaces such as silica nanoparticles and beads. [Pg.507]

Yu WH, Kang ET, Neoh KG. Controlled grafting of comb copolymer brushes on poly-(tetrafluoroethylene) films by surface-initiated living radical polymerizations. Langmuir 2005 21(l) 450-6. [Pg.9]

Size-Exclusion Effect and Protein Repellency of Concentrated Polymer Brushes Prepared by Surface-Initiated Living Radical Polymerization Chiaki Yoshikawa, Atsushi Goto, Norio Ishizuka, Kazuki Nakanishi, Akio Kishida, Yoshinobu Tsujii, Takeshi Fukuda ... [Pg.9]

Surface-initiated living radical polymerization (LRP) has been explored to yield... [Pg.200]

Y. Tsujii, T. Fukuda, Synthesis of gold nanoparticles coated with well-definecl, high-density polymer brushes by surface-initiated living radical polymerization, Macromalecules 2002, 35, 8989 8993 ... [Pg.150]

Grafting of a poly(MPC) chain on a PU surface by a surface-initiated living radical polymerization technique was reported and the surface platelet adhesion resistance postgrafting was confirmed [97]. Because the procedure for obtaining a blood-compatible PU surface is very complicated, it is not applicable for preparing bloodcontacting medical devices. [Pg.332]

To overcome these problems, a surface-initialed living radical polymerization technique is used for preparing polymer brush surfaces, where precisely controlled polymer chains are densely tethered. The technique also can be used to construct block copolymer on the surfaces by sequentially grafting another polymer via the active polymer-end groups of a first-grafted polymer brush. As a typical surface-initiated Uving radical polymerization, atom transfer radical polymerization (ATRP) and reversible addition-fragmentafion chain transfer radical (RAFT) polymerization are... [Pg.212]

Ohno, K., Kayama, Y, Ladmiral, V., Fukuda, T., Tsujii, Y. 2010. A versatile method of initiator fixation for surface-initiated living radical polymerization on polymeric substrates. MagvnwlecuJ 43 5569-5574. [Pg.114]

The use of SAMs and polymer brushes for biological applications is well reviewed in the literature. Hence, this chapter focuses mainly on a "concentrated" polymer brush prepared by surface-initiated living radical polymerization (Sl-LRP) [7]. [Pg.257]

Ohno, K Koh, K Tsuji, Y. Fukuda, T. (2002). Synthesis of Gold Nanoparticles Coated with WeU-defined High-density Polymer Brushes by Surface-initiated Living Radical Polymerization. Macromolecules, 35,8989-8993... [Pg.194]

Surface-Initiated Living Radical Polymerizations Using Iodine, Organotellurium, and Organic Cataiysts. 107... [Pg.1]

Ohno K, Akashi T, Huang Y, Tsujii Y (2010) Surface-initiated living radical polymerization from narrowly size-distributed silica nanoparticles of diameters less than 100 nm. Macromolecules 43(21) 8805-8812... [Pg.71]

Ohno K, Tabata H, Tsujii Y (2013) Surface-initiated living radical polymerization from silica particles functionalized with poly(ethylene glycol)-carrymg initiator. Colloid Polym Sci 291(1) 127-135... [Pg.71]

Surface-Initiated Living Radical Polymerizations Using Iodine.. [Pg.109]

Idota N, Nagase K, Tanaka K, Okano T, Annaka M. Stereoregulation of thermores-ponsive polymer brushes by surface-initiated living radical polymerization and the effect of tacticity on surface wettability. Langmuir. 2010 26 17781-17784. [Pg.254]

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