Surface-initiated controlled radical polymerization

Tab. 9.3 Specific surface modifications and SAM systems of particles or planar substrates for the surface-initiated controlled radical polymerization (CRSIP) of vinyl monomers. 

Barbey R, Lavanant L, Paripovic D et al (2009) Polymer brushes via surface-initiated controlled radical polymerization synthesis, characterization, properties, and applications. Chem Rev 109 5437-5527... 

Degradable polymer brushes prepared via surface-initiated controlled radical polymerization. Macromolecules,... 

For a review of polymer brush syntheses via surface-initiated controlled radical polymerization, see Barbey, R. Lavanant, L. Paripovic, D. Schuwer, N. Sugnaux, C. Tugulu, S. Klok, H. -A. Chem. Rev. 2009,109, 5437. 

Synthetic strategies for the preparation of polymer brushes (A) physisorption, (B) grafting-to approach via reaction of appropriately end-functionalized polymers with complementary functional groups on the substrate surface, (C) grafting-from approach via surface-initiated polymerization. (Reprinted with permission from Barbey et al. 2009. Polymer Brushes via Surface-Initiated Controlled Radical Polymerization Synthesis, Characterization, Properties, and Applications. Chemical Reviews 109 (ll) 5437-5527 copyright (2009) American Chemical Society.)... 

Chakkalakal GL, Alexandre M, Abetz C, Boschetti-de-Fierro A, Abetz V (2012) Surface-initiated controlled radical polymerization from silica nanoparticles with high initiator density. Macromol Chem Phys 213(5) 513-528... 

Turgman-Cohen S, Genzer J (2011) Simultaneous bulk- and surface-initiated controlled radical polymerization from planar substrates. J Am Chem Soc 133(44) 17567-17569... 

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