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Surface functionalization characterization

The carbon black surface function characterization consists of suspending a given amount of carbon black in solutions of known normality of basis of different strength NaHCOs, Na2C03, NaOH in water, and EtONa in ethanol [72]. Then carbon black is filtered and the number of reacted acidic groups obtained by titrating the remaining basis in filtrate (Fig. 2). [Pg.378]

The elemental composition, oxidation state, and coordination environment of species on surfaces can be determined by X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES) techniques. Both techniques have a penetration depth of 5-20 atomic layers. Especially XPS is commonly used in characterization of electrocatalysts. One common example is the identification and quantification of surface functional groups such as nitrogen species found on carbon-based catalysts.26-29 Secondary Ion Mass spectrometry (SIMS) and Ion Scattering Spectroscopy are alternatives which are more surface sensitive. They can provide information about the surface composition as well as the chemical bonding information from molecular clusters and have been used in characterization of cathode electrodes.30,31 They can also be used for depth profiling purposes. The quantification of the information, however, is rather difficult.32... [Pg.339]

Soil particles were found to have a capacity for ligand binding of 2 1(H mol g-1 these surface functional groups are characterized by an apparent "mono-protic" acidity constant... [Pg.41]

Although we have used for exemplification largely the surfaces of hydrous oxides, the concepts given apply to all surfaces. As has been pointed out, most hydrous surfaces are characterized by functional groups that acquire charge by chemical interaction with H+, OH, metal ions and by ligands. (For the moment we ignore redox reactions.)... [Pg.56]

Suitable characterization techniques for surface functional groups are temperature-programmed desorption (TPD), acid/base titration [29], infrared spectroscopy, or X-ray photoemission spectroscopy, whereas structural properties are typically monitored by nitrogen physisorption, electron microscopy, or Raman spectroscopy. The application of these methods in the field of nanocarbon research is reviewed elsewhere [5,32]. [Pg.400]

Tseng YY, Dupree C, Chen ZJ et al (2009) SpKtPocket identification of protein functional surfaces and characterization of their spatial patterns. Nucleic Acids Res 37 W384-W389... [Pg.162]

Perrone et al. (2001) modelled Ni(II) adsorp-tion to synthetic carbonate fluoroapatite (CaI0 ((P04)5(C03))(0H,F). The solid phase had a pHIEP of 6.3 and a ZPC of 6.4 with an SSA of 8.8m2/g, an estimated sorption site density of 3.1 sites/nm2. They conducted 8-day isotherms in closed vessels at Ni concentrations of 5 x 10-10 to 1 x 10 8 M, constant I (0.05, 0.1 or 0.5 M), constant solid phase concentrations of 10 g/dm3 at pH values of 4 to 12. As Ni sorption occurred, no significant release of Ca was seen. Sorption was reversible. Rather than precisely characterize surface functional groups, they elected to describe their sorbent surfaces using acid-base reactions for the average behaviour of all sites involved in protonation and deprotonation. Potentiametric titration data were used to estimate the constants with the FTTEQL computer code ... [Pg.444]

There are conceivable a priori different functions determining the fraction of the total number of surface sites characterized by definite adsorption energy of a given substance, various combinations of these functions at simultaneous adsorption of two or more substances and, finally, various combinations of adsorption energy with kinetic characteristics of surface sites with respect to adsorption and elementary reactions. [Pg.208]


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See also in sourсe #XX -- [ Pg.17 ]




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