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Sulfinic acid amides esters

Benzenesulfonic acid Sulfinic acid esters from sulfinic acid amides Inversion of configuration... [Pg.35]

S-Aminosulfoxonium salts Sulfinic acid amides Sulfoximines Thionitrous acid esters Thionylimines... [Pg.593]

Arylsulfonyl chlorides are pivotal precursors for the preparation of many diverse functional types including sulfonate esters,8 amides,4 sulfones,9 sulfinic acids,10 and others.11 Furthermore, sulfonyl fluorides are best prepared from sulfonyl chlorides.12 The sulfonyl fluorides have many uses, among which is their utilization as active site probes of chymotrypsin and other esterases.13 The trifluoromethyl group also plays valuable roles in medicinal chemistry.14... [Pg.138]

On the pages which follow, general methods are illustrated for the synthesis of a wide variety of classes of organic compounds including acyl isocyanates (from amides and oxalyl chloride p. 16), epoxides (from reductive coupling of aromatic aldehydes by hexamethylphosphorous triamide p. 31), a-fluoro acids (from 1-alkenes p. 37), 0-lactams (from olefins and chlorosulfonyl isocyanate p. 51), 1 y3,5-triketones (from dianions of 1,3-diketones and esters p. 57), sulfinate esters (from disulfides, alcohols, and lead tetraacetate p. 62), carboxylic acids (from carbonylation of alcohols or olefins via carbonium-ion intermediates p. 72), sulfoxides (from sulfides and sodium periodate p. 78), carbazoles... [Pg.150]

As indirect evidence for the formation of sulfuranes, the following reactions have been reported by Okuyama and co-workers [34]. They undertook the hydrolysis of sulfinic esters and sulfine amides 5 under acidic conditions using an 180-tracer. On the basis of 180 exchange and kinetic studies for the hydrolysis, they found that 180 exchange takes place in the reactions, and proposed that the mechanism for the hydrolysis involves the initial formation of sulfurane 6 as an intermediate as shown in Scheme 3. [Pg.95]

Other methods, among which thermolysis or photolysis of tetrazene [59], photolysis of nitrosoamines in acidic solution [60], photolysis of nitrosoamides in neutral medium [61], anodic oxidation of lithium amides [62], tributylstannane-mediated homolysis of O-benzoyl hydroxamic derivatives [63, 64], and spontaneous homolysis of a transient hydroxamic acid sulfinate ester [65] could have specific advantages. The redox reaction of hydroxylamine with titanium trichloride in aqueous acidic solution results in the formation of the simplest protonated aminyl radical [66] similarly, oxaziridines react with various metals, notably iron and copper, to generate a nitrogen-centered radical/oxygen-centered anion pair [67, 68]. The development of thiocarbazone derivatives by Zard [5, 69] has provided complementary useful method able to sustain, under favorable conditions, a chain reaction where stannyl radicals act simply as initiators and allow transfer of a sulfur-containing... [Pg.918]


See other pages where Sulfinic acid amides esters is mentioned: [Pg.250]    [Pg.277]    [Pg.261]    [Pg.280]    [Pg.290]    [Pg.95]    [Pg.95]    [Pg.2373]    [Pg.319]    [Pg.244]    [Pg.359]    [Pg.837]    [Pg.836]    [Pg.255]    [Pg.419]   
See also in sourсe #XX -- [ Pg.17 , Pg.585 ]




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Amidation, esters

Esters amides

Esters, sulfinate

Sulfinate

Sulfinates

Sulfine

Sulfines

Sulfinic acid amides sulfines

Sulfinic acid esters

Sulfinic acids

Sulfinic esters

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