Structure and mechanism of formation

Structure and Mechanism of Formation. Thermal dimerization of unsaturated fatty acids has been explaiaed both by a Diels-Alder mechanism and by a free-radical route involving hydrogen transfer. The Diels-Alder reaction appears to apply to starting materials high ia linoleic acid content satisfactorily, but oleic acid oligomerization seems better rationalized by a free-radical reaction (8—10). 

III. Structure and Mechanism of Formation of Derivatives of the Heterocyclic Pseudobasic Carbinolamines... 

Uzun O, Xu H, Jeoung E, Thibault RJ, Rotello VM. Recognition-induced polymersomes structure and mechanism of formation. Chem Eur J 2005 11 6916-6920. 

F. Tessier, M. Obrenovich, and V. M. Monnier, Structure and mechanism of formation of human lens fluorophore LM-1, J. Biol. Chem., 1999, 274, 20796-20804. 

Structure and mechanism of formation of ozonides (1,2,3- and 1,2,4-trioxolanes) 92CSR79. 

Bottero J. Y., Manceau A.,Villieras, F. and Tchouba, D. (1994) Structure and mechanisms of formation of FeOOH(Cl) polymers. Langmuir 10 316-319. 

Kennedy G, Slaich PK, Golding BT, et al. 1996. Structure and mechanism of formation of a new adduct from formaldehyde and guanosine. Chem Biol Interact 102 93-100. 

Many attempts have been made to rationalize the structures and mechanisms of formation of polymetallates. Lipscomb observed that no individual MOg octahedral unit ever has more than two unshared, i.e. terminal oxygens (exceptions appear to be stable only in the solid state) and this has been explained on the basis of r-bonding between the metal and terminal oxygen atoms more than two of these... 

Marks, F., and Hecker, E., Metabolism and mechanism of action of oestrogens XII. Structure and mechanism of formation of water-soluble and protein bound metabolites of oestrone in rat-liver microsomes in vitro and in vivo. Biochim. Biophy.s. Acta 187, 250-265 (1969). Masukawa, T., and Iwata, H., Possible regulation mechanism of microsomal glutathione S-transferase activity in rat liver. Biochem. Pharmacol. 35, 435-438 (1986). 

The classic description of the structure and mechanisms of formation of silica sols by the hydrolysis and condensation of silicates in aqueous media was given by Iler in 1979 (I). According to Iler, polymerization may occur in essentially three stages (1) the polymerization of monomers to oligomers and then to primary particles, (2) growth of particles, and (3) particle aggregation to form networks that eventually give rise to a gel... 

Bonneviot L, Clause O, Che M, Manceau A, Dexpert H (1989b) EXAFS characterization of the adsorption sites of nickel ammine and ethyldiamine complexes on a silica surface. Catalysis Today 6 39-46 Bomebusch H, Clausen BS, Steffensen G, Liitzenkirchen-Hecht D, Frahm R (1999) A new approach for QEXAFS data acquisition. J Synchrotron Rad 6 209-211 Bostick BC, Fendorf S, Barnett MO, Jardine PM, Brooks SC (2002) Uranyl surface complexes formed on subsurface media from DOE facilities. Soil Sci Soc Am J (2002) 66 99-108 Bottero JY, Manceau A, Villieras F, Tchoubar D (1994) Structure and mechanisms of formation of iron oxide hydroxide (chloride) polymers. Langmuir 10 316-319 Bourg ACM, Joss S, Schindler PW, (1979) Ternary surface complexes 2. Complex formation in the system silica-Cu(II)-2,2 bipyridyl . Chimia 33 19-21... 

Elliott, C. M., Baldy, C. J., Nuwaysir, L. M., and Wilkins, C. L., "Electrochemical Pol3mieiization of 4-Methyl-4 -vinyl-2,2 -bipyridine-Containing Metal Complexes Polymer Structure and Mechanism of Formation," Inorg. Chem., 29, 389-392, 1990. 

Cullis CF, Yates JG, The structure and mechanism of formation of pyrolytic carbon from cyanogen, Acta CrystallograpMca, 17(11), 1433-1436, Nov 1964. 

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