Structural Chemistry of Organo-Transition Metal Complexes

Structural Chemistry of Organo-Transition Metal Complexes, 5, 93... 

Redistribution Equilibria of Organometallic Compounds, 6, 171 Radiochemistry of Organometallic Compounds, 11, 207 Strengths of Metal-to-Carbon Bonds, 2, 49 Structural Aspects of Organotin Chemistry, 5, 137 Structural Chemistry of Organo-Transition Metal Complexes, 3, Structures of Organolithium Compounds, 3, 365 Transition Metal-Carborane Complexes, 8, 87 Transition Metal-Isocyanide Complexes, 11, 21... 

Structural chemistry of organo-transition metal complexes... 

Structural information on the 10 bonding in some organo-transi- (25) tion metal complexes The structural chemistry of organo- 43 transition metal complexes some (159) recent developments Structure of 7r-olefinic and 77- 33 acetylenic complexes of transi- (114) tion metals... 

The structural chemistry of some metal dithiocarbamates, i.e. systematics, coordination modes, crystal packing, and supramolecular self-assembly patterns of nickel, zinc, cadmium, mercury,363 organotin,364 and tellurium,365 366 complexes has been thoroughly analyzed and discussed in detail. Supramolecular self-assembly frequently occurs in non-transition heavier soft metal dithiocarbamates. Thus, lead(II),367 bismuth(III)368 zinc,369 cadmium,370 and (organo)mercury371 dithiocarbamates are associated through M- S secondary bonds, to form either dimeric supermolecules or chain-like supramolecular arrays. The arsenic(III)372 and antimony(III)373 dithiocarbamates are... 

My first incursion into organo-transition metal chemistry occurred because of my interest in chemical bonding. How did olefins with no lone pair of electrons form coordinate bonds to metal atoms The position in 1941 can be read in Keller s review on olefin complexes 54). During the war years I was able to assemble a card index of all references to olefin complexes and I convinced myself that they should be formulated as chelate complexes of, for example, structure (VII) for Zeise s ion if chlorine could bridge metal atoms why should it not bridge carbon to a metal Nature rejected my letter on this topic as being... 

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