Organo-transition-metal complexes

Structural Chemistry of Organo-Transition Metal Complexes, 5, 93... 

The polymerization of olefins and di-olefins is one of the most important targets in polymer science. This review article describes recent progress in this field and deals with organo-transition metal complexes as polymerization catalysts. Recent developments in organometallic chemistry have prompted us to find a precise description of the mechanism of propagation, chain transfer, and termination steps in the homogeneously metal-assisted polymerization of olefins and diolefins. Thus, this development provides an idea for designing any catalyst systems that are of interest in industry. 

Anionic Rearrangement of Organosilicon and Germanium Compounds, 16, I Application of, 3C-NMR Spectroscopy to Organo-Transition Metal Complexes, 19, 257 Applications of """Sn Mdssbauer Spectroscopy to the Study of Oiganotin Compounds, 9, 21... 

Other optical resolutions leading to enantiomeric organo-transition-metal complexes have been discussed in previous reviews (51, 52) and are included in Table I (Section XVII). 

Redistribution Equilibria of Organometallic Compounds, 6, 171 Radiochemistry of Organometallic Compounds, 11, 207 Strengths of Metal-to-Carbon Bonds, 2, 49 Structural Aspects of Organotin Chemistry, 5, 137 Structural Chemistry of Organo-Transition Metal Complexes, 3, Structures of Organolithium Compounds, 3, 365 Transition Metal-Carborane Complexes, 8, 87 Transition Metal-Isocyanide Complexes, 11, 21... 

Three topics in homogeneous catalysis with organo-transition metal complexes will be dealt with in this chapter ... 

Fig. 1. Typical, 3C spin-lattice relaxation times (T, in seconds) for organo-transition metal complexes. (1) Benzene-d, 38°C (18) (2) benzene-d, 38°C (19) (3) benzene-d6, 35°C (4) toluene-d8,0°C (5), (6), and (7) toluene-d8, 35°C. All measurements at 25.2 MHz.

York, 1971. Contains detailed surveys of the use of organo-transition metal complexes as catalysts for a variety of reactions ... 

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