Fracture mechanics stress corrosion cracking

The Institute has many-year experience of investigations and developments in the field of NDT. These are, mainly, developments which allowed creation of a series of eddy current flaw detectors for various applications. The Institute has traditionally studied the physico-mechanical properties of materials, their stressed-strained state, fracture mechanics and developed on this basis the procedures and instruments which measure the properties and predict the behaviour of materials. Quite important are also developments of technologies and equipment for control of thickness and adhesion of thin protective coatings on various bases, corrosion control of underground pipelines by indirect method, acoustic emission control of hydrogen and corrosion cracking in structural materials, etc. 

Fracture Mechanics Methods These have proved very usebd for defining the minimum stress intensity K[scc. t which stress corrosion cracking of high-strength, low-ductihty alloys occurs. They have so far been less successful when apphed to high-ductility alloys, which are extensively used in the chemicm-process industries. 

Bundy, K. J. and Desai, V. H., Studies of Stress-Corrosion Cracking Behaviour of Surgical Implant Materials using a Fracture Mechanics Approach , in Corrosion and Degradation of Implant Materials, second symposium , (Eds) A. C. Fraker and C. D. Griffin, 73-90, ASTM Publication STP 859, Philadelphia (1985)... 

Any test (several such tests are used) in which time to failure of smooth specimens is determined is an overall measure of the incubation period to initiate a crack, the ability to resist the propagation of a stress corrosion crack and the ability to resist final mechanical fracture. Since this test does not indicate the relative merits of an alloy in each individual aspect of the... 

Structural failure may occur when the overall structural cross-section cannot support the applied load or, when the critical flaw size ac is exceeded by preexisting discontinuity or by reaching the critical crack size through fatigue, stress corrosion cracking or creep mechanisms. Using fracture mechanics the stress at a crack tip can be calculated by a stress-intensity parameter K as,... 

Speidel, M.O., Stress Corrosion Cracking and Corrosion Fatigue - Fracture Mechanics, in Corrosion in Power Generating Equipment, M.O. Speidel, A. Atrens (eds.), Plenum Press, NY, pp. 85-132, 1984. 

From studies of service behavior and from extensive laboratory investigations, the well-established terms stress-corrosion cracking (SCC) and corrosion fatigue have been shown to relate to a continuum of failure modes classified as environment-sensitive fracture. In many environments, the addition of stress, with associated strains, introduces a variable that can result in brittle failure in the sense of very limited plastic flow in otherwise ductile materials such as the stainless steels. Environment-sensitive fractures propagate at an advancing crack tip at which, simultaneously, the local stresses can influence the corrosion processes, and the corrosion can influence the crack-opening processes. Since these processes proceed by kinetic mechanisms, they are time and stress dependent with the result that the crack propagation rate can become very sensitive to the stress application rates. Conventional SCC usually has been associated with static stress, but this is seldom realized... 

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