Storage stress

C. 0. Ondari, V. K. Prasad, V. P. Shah, and C. T. Rhodes, Effects of short-term moderated storage stress on the disintegration and dissolution of four types of compressed tablets, Pharm. Acta Helv. 59, 149-153 (1984). 

It was reahzed quite some decades ago that the amount of information accumulated by chemists can, in the long run, be made accessible to the scientific community only in electronic form in other words, it has to be stored in databases. This new field, which deals with the storage, the manipulation, and the processing of chemical information, was emerging without a proper name. In most cases, the scientists active in the field said they were working in "Chemical Information . However, as this term did not make a distinction between librarianship and the development of computer methods, some scientists said they were working in "Computer Chemistry to stress the importance they attributed to the use of the computer for processing chemical information. However, the latter term could easily be confused with Computational Chemistry, which is perceived by others to be more limited to theoretical quantum mechanical calculations. 

Ammonia is corrosive to akoys of copper and zinc and these materials must not be used in ammonia service. Iron or steel should usuaky be the only metal in ammonia storage tanks, piping, and fittings. It is recommended that ammonia should contain at least 0.2% water to prevent steel stress corrosion. Mercury thermometers should be avoided. 

Rheometric Scientific markets several devices designed for characterizing viscoelastic fluids. These instmments measure the response of a Hquid to sinusoidal oscillatory motion to determine dynamic viscosity as well as storage and loss moduH. The Rheometric Scientific line includes a fluids spectrometer (RFS-II), a dynamic spectrometer (RDS-7700 series II), and a mechanical spectrometer (RMS-800). The fluids spectrometer is designed for fairly low viscosity materials. The dynamic spectrometer can be used to test soHds, melts, and Hquids at frequencies from 10 to 500 rad/s and as a function of strain ampHtude and temperature. It is a stripped down version of the extremely versatile mechanical spectrometer, which is both a dynamic viscometer and a dynamic mechanical testing device. The RMS-800 can carry out measurements under rotational shear, oscillatory shear, torsional motion, and tension compression, as well as normal stress measurements. Step strain, creep, and creep recovery modes are also available. It is used on a wide range of materials, including adhesives, pastes, mbber, and plastics. 

Tank Shell. Another example of where thickness is set by minimums for fabricabihty but not for strength is in small-diameter tanks. For example, a water storage tank built using a steel of an allowable stress of 20,000 psi (138 mPa), 9 ft (3 m) in diameter by 21-ft (7-m) high, requires a shell thickness to resist hoop stress of only 0.023-in. (0.58-mm) thick. However, if built to API Standard 650, the shell would be fabricated at least 0.1875-in. (4.76-mm) thick. The code requires this thickness so that when fabrication, welding, and tolerances are considered, a tank of acceptable quaUty and appearance meeting the requirements of most services in most locations is provided. 

The sympathetic or adrenergic nervous system operates in juxtaposition to the parasympathetic nervous system to maintain homeostasis in response to physical activity and physical or psychological stress. Sympathomimetic neurotransmission is generally mediated by norepinephrine [51-41 -2] (1), CgH NO, released from presynaptic storage granules upon stimulation. A second endogenous sympathomimetic agent, epinephrine [51-43-4] (2),... 

Commercial use of many chlorinated derivatives imposes stress on the stabHity of the solvent. Inhibitors classified as antioxidants (qv), acid acceptors, and metal stabilizers are added to minimize these stresses. AH the chloriaated derivatives hydrolyze at a slow but finite rate when dissolved ia water. Hydrolysis of chloriaated solvents typicaHy Hberates hydrogen chloride that can corrode storage containers and commercial metal-cleaning equipment. The Hberated hydrogen chloride can be neutralized by an appropriate epoxide to form noncorrosive chlorohydrins (qv). 

Alginate impression materials must have a compressive strength of at least 0.34 MPa (49 psi) 8 min after the start of the mix at least 3.5 min of this time interval should be in storage at 37 1°C. They should have a strain in compression of 4—20% between stresses of 9.8—98 kPa (1.42—14.2 psi) per specification method and they should not have a permanent deformation exceeding 3% after a 12% strain is appHed for 30 s. 

A powder s strength increases significantly with increasing previous compaction. The relationship between the unconfined yield stress/, or a powder s strength, and compaction pressure is described by the powder s flow function FE The flow function is the paramount characterization of powder strength and flow properties, and it is calculated from the yield loci determined from shear cell measurements. [Jenike, Storage and Flow of Solids, Univ. of Utah, Eng. Exp. Station Bulletin, no. 123, November (1964). See also Sec. 21 on storage bins, silos, and hoppers.]... 

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