Stiffnesses symmetry

If there is an infinite numtser of planes of material property symmetry, then the foregoing relations simplify to the isotropic material relations with only two independent constants in the stiffness matrix ... 

Thus, the Tsai-Wu tensor failure criterion is obviously of more general character than the Tsai-Hill or Hoffman failure criteria. Specific advantages of the Tsai-Wu failure criterion include (1) invariance under rotation or redefinition of coordinates (2) transformation via known tensor-transformation laws (so data interpretation is eased) and (3) symmetry properties similar to those of the stiffnesses and compliances. Accordingly, the mathematical operations with this tensor failure criterion are well-known and relatively straightforward. 

Stiffnesses for single-layered configurations are treated first to provide a baseline for subsequent discussion. Such stiffnesses should be recognizable in terms of concepts previously encountered by the reader in his study of plates and shells. Next, laminates that are symmetric about their middle surface are discussed and classified. Then, laminates with laminae that are antisymmetrically arranged about their middle surface are described. Finally, laminates with complete lack of middle-surface symmetry, i.e., unsymmetric laminates, are discussed. For all laminates, the question of laminae thicknesses arises. Regular laminates have equal-thickness laminae, and irregular laminates have non-equal-thickness laminae. 

For laminates that are symmetric in both geometry and material properties about the middle surface, the general stiffness equations. Equation (4.24), simplify considerably. That symmetry has the form such that for each pair of equal-thickness laminae (1) both laminae are of the same material properties and principal material direction orientations, i.e., both laminae have the same (Qjjlk and (2) if one lamina is a certain distance above the middle surface, then the other lamina is the same distance below the middle surface. A single layer that straddles the middle surface can be considered a pair of half-thickness laminae that satisfies the symmetry requirement (note that such a lamina is inherently symmetric about the middle surface). ... 

Because of the analytical complications involving the stiffnesses Ai6, A26, D g, and D26, a laminate is sometimes desired that does not have these stiffnesses. Laminates can be made with orthotropic layers that have principal material directions aligned with the laminate axes. If the thicknesses, locations, and material properties of the laminae are symmetric about the middle surface of the laminate, there is no coupling between bending and extension. A general example is shown in Table 4-2. Note that the material property symmetry requires equal [Q j], of the two layers that are placed at the same distance above and below the middle surface. Thus, both the orthotropic material properties, [Qjjlk. of the layers and the angle of the principal material directions to the laminate axes (i.e., the orientation of each layer) must be identical. 

The general case of a laminate with multiple anisotropic layers symmetrically disposed about the middle surface does not have any stiffness simplifications other than the elimination of the Bjj by virtue of symmetry. The Aig, A2g, Dig, and D2g stiffnesses all exist and do not necessarily go to zero as the number of layers is increased. That is, the Aig stiffness, for example, is derived from the Q matrix in Equation (2.84) for an anisotropic lamina which, of course, has more independent... 

The stiffnesses of an antisymmetric laminate of anisotropic laminae do not simplify from those presented in Equations (4.22) and (4.23). However, as a consequence of antisymmetry of material properties of generally orthotropic laminae, but symmetry of their thicknesses, the shear-extension coupling stiffness A.,6,... 

Symmetric angle-ply laminates were described in Section 4.3.2 and found to be characterized by a full matrix of extensional stiffnesses as well as bending stiffnesses (but of course no bending-extension coupling stiffnesses because of middle-surface symmetry). The new facet of this type of laminate as opposed to specially orthotropic laminates is the appearance of the bend-twist coupling stiffnesses D. g and D2g (the shear-extension coupling stiffnesses A. g and A2g do not affect the transverse deflection w when the laminate is symmetric). The governing differential equation of equilibrium is... 

Equation (8.22) for a(0) is also special because, due to symmetry, there is only one adjacent point, a(l). The overall set may be solved by any desired method. Euler s method is discussed below and is illustrated in Example 8.5. There are a great variety of commercial and freeware packages available for solving simultaneous ODEs. Most of them even work. Packages designed for stiff equations are best. The stiffness arises from the fact that VJJ) becomes very small near the tube waU. There are also software packages that will handle the discretization automatically. 

The Ni octahedra derive their stability from the interactions of s, p, and d electron orbitals to form octahedral sp3d2 hybrids. When these are sheared by dislocation motion this strong bonding is destroyed, and the octahedral symmetry is lost. Therefore, the overall (0°K) energy barrier to dislocation motion is about COCi/47r where = octahedral shear stiffness = [3C44 (Cu - Ci2)]/ [4C44 + (Cu - C12)] = 50.8 GPa (Prikhodko et al., 1998), and the barrier = 4.04 GPa. The octahedral shear stiffness is small compared with the primary stiffnesses C44 = 118 GPa, and (Cn - C12)/2 = 79 GPa. Thus elastic as well as plastic shear is easier on this plane than on either the (100), or the (110) planes. 

The Group IV elements also show a linear correlation of their octahedral shear moduli, C44(lll) with chemical hardness density (Eg/2Vm).This modulus is for for shear strains on the (111) planes. It is a measure of the shear stiffnesses of the covalent bonds. The (111) planes lie normal to the bonds that connect the atoms in the diamond (or zinc blende) structure. In terms of the three standard moduli for cubic symmetry (Cn, Q2, and C44), the octahedral shear modulus is given by C44(lll) = 3CV1 + [4C44/(Cn - Ci2)]. Since the (111) planes have three-fold symmetry, they have only one shear modulus. The bonds across the octahedral planes have high resistance to shear which probably results from electron correlation in the bonds (Gilman, 2002). 

Another property that is related to chemical hardness is polarizability (Pearson, 1997). Polarizability, a, has the dimensions of volume polarizability (Brinck, Murray, and Politzer, 1993). It requires that an electron be excited from the valence to the conduction band (i.e., across the band gap) in order to change the symmetry of the wave function(s) from spherical to uniaxial. An approximate expression for the polarizability is a = p (N/A2) where p is a constant, N is the number of participating electrons, and A is the excitation gap (Atkins, 1983). The constant, p = (qh)/(2n 2m) with q = electron charge, m = electron mass, and h = Planck s constant. Then, if N = 1, (1/a) is proportional to A2, and elastic shear stiffness is proportional to (1/a). 

When we compared the viscosities of solutions of natural rubber and of guttapercha and of other elastomers and later of polyethylene vs.(poly)cis-butadiene, with such bulk properties as moduli, densities, X-ray structures, and adhesiveness, we were greatly helped in understanding these behavioral differences by the studies of Wood (6) on the temperature and stress dependent, melting and freezing,hysteresis of natural rubber, and by the work of Treloar (7) and of Flory (8) on the elasticity and crystallinity of elastomers on stretching. Molecular symmetry and stiffness among closely similar chemical structures, as they affect the enthalpy, the entropy, and phase transitions (perhaps best expressed by AHm and by Clapeyron s... 

Due to the inherent stiffness of 1,4-phenylene based polymers and based on molecular modeUng calculations (see below), the question arises whether the shape of the dendrimer can be predetermined by choosing an appropriate core. This should be important for the use of dendrimers in single molecule appHca-tions, as carriers for dyes for single molecule optical spectroscopy or as building blocks for two- and three-dimensional assemblies. There are two possibiHties variation of the core and variation of the building unit. Therefore, we synthesized dendrimers based on cores with different symmetries presented in Scheme 4. 

In many cases considerable simplification is possible, because of the constraints imposed on the number of independent elastic constants. For cubic symmetry, for which the elastic stiffness tensor has only three independent constants as given in (6.29), the elements of T, are given in Table 11.1(b), and for hexagonal symmetry the elements are given in Table 11.1(c). If c12 = Cn - 2c44 were to be substituted in Table 11.1(b) the isotropic elements would... 

Polyoxybenzoate is a stiff chain, lyotropic liquid crystalline material, as was discussed on the basis of its copolymers with ethylene terephthalate (see Sect. 5.1.4). The crystal structure of the homopolymer polyoxybenzoate was shown by Lieser 157) to have a high temperature phase III, described as liquid crystalline. X-ray and electron diffraction data on single crystals suggested that reversible conformational disorder is introduced, i.e. a condis crystal exists. Phase III, which is stable above about 560 K, has hexagonal symmetry and shows an 11 % lower density than the low temperature phases I and II. It is also possible to find sometimes the rotational disorder at low temperature in crystals grown during polymerization (CD-glass). 

Since there are only 6 independent components of stress and strain there are 36 components to S, the compliance tensor and C, the stiffness tensor. These 36 components may be further reduced using thermodynamic arguments so that there are 21 independent constants for triclinic symmetry, 13 for monodinic, 7 for tetragonal, 5 for hexagonal, 3 for cubic and 2 for isotropic materials. It is consequently more convenient to use die simplified notation of Voigt where ... 

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