Starch acetate potato, solubility

In general, starch triacetates are soluble in acetic acid and, except perhaps for potato starch triacetate, are soluble in chloroform, 1,1,2-tri-chloroethane, tetrachloroethane, and other halogenated hydrocarbons. High grade starch triacetates do not appear to be soluble in ethyl acetate or alcohol, while some controversy exists as to the extent of their solubility in pyridine and acetone. Waxy com starch triacetate, perhaps due to its smaller molecular weight, is readily soluble in a wide variety of organic solvents. 

Staudinger and Husemann determined the osmotic pressure of solutions of a potato starch acetate which had been fractionated into four parts by precipitation of its chloroform solution with ether. The molecular weights of the fractions ranged from 45,000 to 275,000. All of the fractions were soluble in chloroform, but fractions of low molecular weight were also soluble in acetone. For various concentrations of solute in either chloroform or acetone, the osmotic pressure did not increase in direct proportion to the solute concentration, but the deviation from van t Hoff s law was the smallest in the case of the acetone solutions. Osmotic pressure measurements on amylose and amylopectin tri-acetates dissolved in tetrachloroethane have been made by Meyer and co-workers, who have deduced molecular weights for these substances of approximately 78,000 and 300,000, respectively (see above discussion of the purity of these fractions). 

Not all modified starches are suitable for removal by aqueous dissolution alone. Such modifications of natural starches are carried out to reduce solution viscosity, to improve adhesion and ostensibly to enhance aqueous solubility. Commercial brands vary [169], however, from readily soluble types to those of limited solubility. Indeed, some may be as difficult to dissolve as potato starch if they have been overdried. It is thus very important to be sure of the properties of any modified starch present. If there are any doubts about aqueous dissolution, desizing should be carried out by enzymatic or oxidative treatment. Even if the size polymer is sufficiently soluble, it is important to ensure that the washing-off range is adequate. Whilst the above comments relate to modified starches, other size polymers such as poly(vinyl acetate/alcohol) and acrylic acid copolymers vary from brand to brand with regard to ease of dissolution. 

Sealing tape has 35 to 90 pounds per ream of kraft paper as a substrate, whereas, reinforced sealing tape is based on a bonded laminate of kraft paper, reinforcing fibers, and kraft paper. The adhesives applied to these substrates may be thin-boiling, waxy starches alone, or blended with a soluble dextrin (5). More recently, blends of a soluble dextrin with oxidized potato or a hydrox-ypropyl ether of an oxidized potato starch are being used (9). Also, the acetate or succinate of an oxidized waxy starch may be used (15) as well as specially produced waxy starch acrylamide graft copolymer products (16). 

Potato starch A clear solution of starch (4,0 ml, 5mg/ml) was mixed with 80.0 ml of Reagent I, centrifuged (2,416 g) and the clear solution of starch-iodine-complex was loaded on the column under gravity. The same procedure was followed as in the case of soluble starch, except that the amylose-iodine-complex was desorbed with acetate buffer (pH 4,8, 0.1 M) containing iirea (8 M) (Figure 2). 

T. ikp cellulose, starch is a polyglucose, but its subunits are connected by a-acetal linkages. It functions as a food reserve in plants and (like cellulose) is readily cleaved by aqueous acid into glucose. Major sources of starch are com, potatoes, wheat, and rice. Hot water swells granular starch and allows the separation of the two major components amylose (—20%) and amylopectin (—80%). Both are soluble in hot water, but amylose is less soluble in cold water. Amylose contains a few hundred glucose units per molecule... 

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