Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Space entanglement

Our discussion of reptation has been limited to completely dense systems—e.g., a dry network with closely spaced entanglement points or a polymer melt of very long chains, incorporating one extra test chain. To... [Pg.227]

FIQ. 1 Sketch of the BFM of polymer chains on the three-dimensional simple cubic lattice. Each repeat unit or effective monomer occupies eight lattice points. Elementary motions consist of random moves of the repeat unit by one lattice spacing in one lattice direction. These moves are accepted only if they satisfy the constraints that no lattice site is occupied more than once (excluded volume interaction) and that the bonds belong to a prescribed set of bonds. This set is chosen such that the model cannot lead to any moves where bonds should intersect, and thus it automatically satisfies entanglement constraints [51],... [Pg.516]

The presented scheme offers several extensions. For example, the model gives a clear route for an additional inclusion of entanglement constraints and packing effects [15]. Again, this can be realized with the successful mean field models based on the conformational tube picture [7,9] where the chains do not have free access to the total space between the cross-links but are trapped in a cage due to the additional topological restrictions, as visualized in the cartoon. [Pg.612]

This section presents results of the space-time analysis of the above-mentioned motional processes as obtained by the neutron spin echo technique. First, the entropically determined relaxation processes, as described by the Rouse model, will be discussed. We will then examine how topological restrictions are noticed if the chain length is increased. Subsequently, we address the dynamics of highly entangled systems and, finally, we consider the origin of the entanglements. [Pg.12]

A one-dimensional SOM is less effective at filling the space defined by input data that cover a two-dimensional space (Figure 3.22) and is rather vulnerable to entanglement, where the ribbon of nodes crosses itself. It does, however, make a reasonable attempt to cover the sample dataset. [Pg.76]

The positive electrode should have a porous structure to support the transport of 02 to the electrolyte/electrode interface as much as possible through the gas phase rather than by the slower diffusion in the electrolyte. CNT materials with mesopores and space between the entangled CNTs have been tested as electrode materials for Li-... [Pg.308]

Lack of steady flow of a liquid-bearing colloidal solution requires the existence of a space-filling, three-dimensional structure. As we might select a perfect crystal as a csuionical solid, or liquid argon as a prototypical liquid, we csui choose the covalently crosslinked network, without any entanglements, to represent the ideal gel state. Then an appropriate time scale for reversible gels would be the lifetime of a typical crosslink bond if subjected to conditions that would cause flow in a pure... [Pg.4]

Zero shear viscosities have been determined in solution over a wide range of concentrations with a cone-plate Rheometrics Stress Rheometer. For linear macromolecules, the viscosity is proportional to c below the so called "entanglement concentration", c above c, is proportional to c. However, the viscosity will rise steeply at some concentration below c in the case where particular interconnections are formed at the concentration at which the molecules come into contact with one another. Ideally this will be the overlap threshold c. Below c, the molecules may associate partially but cannot form a network continuous over the entire sample space. Above c, plastic flow will require separation and... [Pg.103]

Many electron systems such as molecules and quantum dots show the complex phenomena of electron correlation caused by Coulomb interactions. These phenomena can be described to some extent by the Hubbard model [76]. This is a simple model that captures the main physics of the problem and admits an exact solution in some special cases [77]. To calculate the entanglement for electrons described by this model, we will use Zanardi s measure, which is given in Fock space as the von Neumann entropy [78]. [Pg.512]

In the Hubbard model, the electron occupation of each site has four possibilities there are four possible local states at each site, v). = 0)y, t) -, i) -, Ti)y The dimensions of the Hilbert space of an L-site system is 4 and IV] V2 Vf,) = vj)j can be used as basis vectors for the system. The entanglement of the jth site with the other sites is given in the previous section by Eq. (65). [Pg.518]

In this chapter, we will focus on the entanglement behavior in QPT for the two-dimensional array of quantum dots, which provide a suitable arena for implementation of quantum computation [88, 89, 103]. For this purpose, the real-space renormalization group technique [91] will be utilized and developed for the finite-size analysis of entanglement. The model that we will be using is the Hubbard model [83],... [Pg.519]


See other pages where Space entanglement is mentioned: [Pg.48]    [Pg.516]    [Pg.517]    [Pg.518]    [Pg.78]    [Pg.48]    [Pg.516]    [Pg.517]    [Pg.518]    [Pg.78]    [Pg.415]    [Pg.497]    [Pg.133]    [Pg.117]    [Pg.117]    [Pg.121]    [Pg.478]    [Pg.60]    [Pg.75]    [Pg.116]    [Pg.460]    [Pg.127]    [Pg.36]    [Pg.42]    [Pg.53]    [Pg.189]    [Pg.100]    [Pg.185]    [Pg.252]    [Pg.397]    [Pg.225]    [Pg.227]    [Pg.13]    [Pg.305]    [Pg.616]    [Pg.7]    [Pg.50]    [Pg.498]    [Pg.594]    [Pg.40]    [Pg.129]   
See also in sourсe #XX -- [ Pg.516 ]




SEARCH



Entanglement spacings

Entanglements

Estimations of Entanglement Spacings

© 2024 chempedia.info